Registration Dossier

Administrative data

First-aid measures

Emergency measure - Inhalation: Remove to fresh air. If not breathing, give artificial
respiration, preferably mouth to mouth. If breathing is
difficult, give oxygen. Get medical attention.
Emergency measure - Eyes: Immediately flush eyes with plenty of water for at least 15
minutes. Get medical attention.
Emergency measure - Skin: Immediately flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Get
medical attention.
Emergency measure - Ingestion: Give two glasses of water. Do not induce vomiting. Get
medical attention.

Fire-fighting measures

Recommended extinguishing agent: Dry chemical, water spray (fog), foam or carbon dioxide

Product arising from burning: Hafnium compounds and oxides of carbon and silicon

Product determined by test: N

Protective equipment: Standard fireman equipment is recommended

Accidental release measures

Emergency measures in case of spillage: Sweep or shovel spills into appropriate container for
disposal.

Handling and storage

Handling: Eye protection : wear chemical goggles or face shield.

Protective clothing : Tyvek suits, nitrile gloves (sol-vex

nitrile) or Omni Flock Lines.

Respirators : Dust respirators such as half-face respirator
(Model 474-476-1 by MSA)

Storage: Store in a cool dry place and under inert atmosphere

Packaging of the substance and or preparation: Package in 3/16 inch steel container. Volume is 4.3 liter.

Transport information

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Marine transport (IMDG)

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Air transport ICAO/IATA

Remarks
Transport code: UN 3134
Transport: Transport code :

UN 3134


Further notes on transport :

Description : water reactive solid, toxic, N.O.S.

Hazard classification : 4.3

ID number : UN 3134

Packing Group : PGI
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Exposure controls / personal protection

Stability and reactivity

Danger other than fire: None expected

Chemical reaction with water: Reacts with water/moisture and undergoes hydrolysis

Dust explosion: Not expected, however, no test has been conducted.

Dust explosion determined by test: N

Disposal considerations

Industry - Possibility of recovery/recycling: The substance is consumed in the polymerization process. No
recycling/recovery is needed. In the event of spills, the
substance will be decomposed due to hydrolysis by moisture
in air, recovery will not be possible.

Industry - Possibility of neutralisation: Exposure of substance to air will result in decomposition.

Industry - Possibility of destruction: controlled discharge: No discharge will occur due to incorporation of the
deactivated substance being incorporated into the polymer.


The substance is easily destructed in the presence of oxygen
and/or water resulting in hydrolysis of the molecule or
formation of oxodimers.

Industry - Possibility of destruction - incineration: No incineration treatment will be needed due to the
deactivated substance being incorporated into the polymer.

Public at large - Possibility of destruction: controlled discharge: No discharge is made.

Public at large - Possibility of destruction - incineration: No inceneration is needed.

Public at large - Possibility of destruction - water purification: Not needed because no waste is discharged into water system.

Public at large - Possibility of destruction - others: None