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Diss Factsheets

Administrative data

Endpoint:
adsorption / desorption: screening
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2008
Reliability:
1 (reliable without restriction)

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2008
Report date:
2008

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
OECD Guideline 106 (Adsorption - Desorption Using a Batch Equilibrium Method)
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Type of method:
batch equilibrium method
Media:
soil

Test material

Constituent 1
Reference substance name:
A mixture of: ethyl (2R,3R)-3-isopropylbicyclo[2.2.1]hept-5-ene-2-carboxylate; ethyl (2S,3S)-3-isopropylbicyclo[2.2.1]hept-5-ene-2-carboxylate
EC Number:
427-090-8
EC Name:
A mixture of: ethyl (2R,3R)-3-isopropylbicyclo[2.2.1]hept-5-ene-2-carboxylate; ethyl (2S,3S)-3-isopropylbicyclo[2.2.1]hept-5-ene-2-carboxylate
Cas Number:
116044-44-1
IUPAC Name:
bis(ethyl (2R,3R)-3-(propan-2-yl)bicyclo[2.2.1]hept-5-ene-2-carboxylate)
Details on test material:
HERBANATE Lot No. 9000738342; Purity 99.5%
Radiolabelling:
no

Study design

Test temperature:
25°C
Dry mass soil to Volume of aqueous phase (0.01 M CacCl2) ratio :
Soil #2 - 5.8 g to 30 mL
Soil #3 - 5.5 g to 30 mL
Soil # 5 - 6 g to 30 mL
Soil #7 - 4 g to 30 mL

Batch equilibrium or other method

Analytical monitoring:
yes
Duration of adsorption equilibrationopen allclose all
Sample No.:
#3
Duration:
30 min
Initial conc. measured:
1.8 - 4.09 other: mg/L - First figure (1.80 mg/L) is the concn in Soil #3 of Herbanate remaining in 0.01 M CaCl2 after shaking. 4.09 mg/L is the Soil-less Control shaken for 30 minutes with 0.01M CaCl2 fortified with Herbanate - i.e. 55.8% adsorption by Soil #3.
pH:
6.4
Temp.:
25
Sample No.:
#5
Duration:
30 min
Initial conc. measured:
1.75 - 4.09 other: mg/L - First figure (1.75 mg/L) is the concn in Soil #5 of Herbanate remaining in 0.01 M CaCl2 after shaking. 4.09 mg/L is the Soil-less Control shaken for 30 minutes with 0.01M CaCl2 fortified with Herbanate - i.e. 57.2% adsorption by Soil #5.

Results and discussion

Adsorption coefficient
Type:
Kd
Value:
6.71 - 85.4
Temp.:
25 °C
% Org. carbon:
1.29 - 9.6
Remarks on result:
other: See remarks in summary Table (above) for specific data on soil types, relevant Kd's and corresponding Koc's.

Applicant's summary and conclusion

Validity criteria fulfilled:
yes