Registration Dossier

Administrative data

First-aid measures

Description of first aid measures

Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. Drench the affected skin with running water for 10 minutes or longer if substance is still on skin. Transfer to hospital if there are burns or symptoms of poisoning.

Eye contact: Bathe the eye with running water for 15 minutes. Transfer to hospital for specialist examination.

Ingestion: Wash out mouth with water. Do not induce vomiting. Give 1 cup of water to drink every 10 minutes. If unconscious, check for breathing and apply artificial respiration if necessary. If unconscious and breathing is OK, place in the recovery position. Transfer to hospital as soon as possible.

Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. If unconscious and breathing is OK, place in the recovery position. If conscious, ensure the casualty sits or lies down. If breathing becomes bubbly, have the casualty sit and provide oxygen if available. Transfer to hospital as soon as possible.


Most important symptoms and effects, both acute and delayed

Skin contact: Blistering may occur. Progressive ulceration will occur if treatment is not immediate. Eye contact: Corneal burns may occur. May cause permanent damage.

Ingestion: Corrosive burns may appear around the lips. Blood may be vomited. There may be bleeding from the mouth or nose.

Inhalation: There may be shortness of breath with a burning sensation in the throat. Exposure may cause coughing or wheezing.

Delayed / immediate effects: Immediate effects can be expected after short-term exposure.


Indication of any immediate medical attention and special treatment needed

Immediate / special treatment: Eye bathing equipment should be available on the premises.

Fire-fighting measures

Extinguishing media

Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Carbon dioxide. Dry chemical powder. Use water spray to cool containers.


Special hazards arising from the substance or mixture

Exposure hazards: Corrosive. In combustion emits toxic fumes.


Advice for fire-fighters
Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.

Accidental release measures

Personal precautions, protective equipment and emergency procedures

Personal precautions: Notify the police and fire brigade immediately. If outside keep bystanders upwind and away from danger point. Mark out the contaminated area with signs and prevent access to unauthorised personnel. Do not attempt to take action without suitable protective clothing - see section 8 of SDS. Do not create dust.

Environmental precautions

Environmental precautions: Do not discharge into drains or rivers.


Methods and material for containment and cleaning up

Clean-up procedures: Clean-up should be dealt with only by qualified personnel familiar with the specific substance. Transfer to a closable, labelled salvage container for disposal by an appropriate method.


Reference to other sections

Reference to other sections: Refer to section 8 of SDS (Exposure controls/personal protection).

Handling and storage

Precautions for safe handling

Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area. Do not handle in a confined space. Avoid the formation or spread of dust in the air.

Conditions for safe storage, including any incompatibilities

Storage conditions: Store in cool, well ventilated area. Keep container tightly closed. Suitable packaging: Must only be kept in original packaging.

Transport information

Land transport (ADR/RID)

UN number:
UN3261
Proper shipping name and description:
CORROSIVE SOLID, ACIDIC ORGANIC, N.O.S
Chemical name:
(2-{5-[(DICHLOROPHOSPHORYL)AMINO]-1 ,2,4-THIADIAZOL-3-YL}-(Z)-2-(ETHOXYIMIN O) ACETYL CHLORIDE)
Language:
English
Class:
8
Packaging group:
III
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Marine transport (IMDG)

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Exposure controls / personal protection

Control parameters

Workplace exposure limits: Not applicable.

Exposure controls

Engineering measures: Ensure there is sufficient ventilation of the area.

Respiratory protection: Self-contained breathing apparatus must be available in case of emergency. Respiratory protective device with particle filter.

Hand protection: Protective gloves.

Eye protection: Tightly fitting safety goggles. Ensure eye bath is to hand.

Skin protection: Protective clothing.

Stability and reactivity

Reactivity

Reactivity: Stable under recommended transport or storage conditions.

Chemical stability

Chemical stability: Stable under normal conditions.

Possibility of hazardous reactions

Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions. Decomposition may occur on exposure to conditions or materials listed below.

Conditions to avoid

Conditions to avoid: Heat. Moist air.

Incompatible materials

Materials to avoid: Strong oxidising agents. Strong acids.

Hazardous decomposition products

Haz. decomp. products: In combustion emits toxic fumes. In combustion emits toxic fumes of hydrogen chloride. In combustion emits toxic fumes of nitrogen oxides. In combustion emits toxic fumes of hydrogen cyanide.

Disposal considerations

Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company.

Disposal of packaging: Burn in a chemical incinerator equipped with afterburners and scrubbers. NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal.