Registration Dossier

Administrative data

First-aid measures

General advice
Move out of dangerous area. Place and transport victim in stable position (lying sideways). Remove contaminated clothing immediately and dispose of safely.

Inhalation
Move to fresh air. Keep patient warm and at rest. Call a physician or poison control center immediately.

Skin contact
Wash off thoroughly with plenty of soap and water, if available with polyethyleneglycol 400, subsequently rinse with water. If symptoms persist, call a physician.

Eye contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Get medical attention if irritation develops and persists.

Ingestion
Rinse mouth. Do NOT induce vomiting. Call a physician or poison control center immediately.

Treatment
Treat symptomatically. In case of ingestion gastric lavage should be considered in cases of significant ingestions only within the first 2 hours. However, the application of activated charcoal and sodium sulphate is always advisable. There is no specific antidote.

Fire-fighting measures

Extinguishing media

Suitable
Water spray, Carbon dioxide (CO2), Foam, Sand

Special hazards arising from the substance or mixture In the event of fire the following may be released:, Hydrogen chloride (HCl), Hydrogen cyanide (hydrocyanic acid), Carbon monoxide (CO), Nitrogen oxides (NOx), Sulphur oxides
Advice for firefighters

Special protective equipment for fire-fighters In the event of fire and/or explosion do not breathe fumes. In the event of fire, wear self-contained breathing apparatus.

Further information Contain the spread of the fire-fighting media. Do not allow run-off from fire fighting to enter drains or water courses.

Accidental release measures

Personal precautions, protective equipment and emergency procedures

Precautions Avoid contact with spilled product or contaminated surfaces. Use personal protective equipment.

Environmental precautions
Do not allow to get into surface water, drains and ground water.
Methods and materials for containment and cleaning up

Methods for cleaning up Use mechanical handling equipment. Clean contaminated floors and objects thoroughly, observing environmental regulations. Keep in suitable, closed containers for disposal.

Reference to other sections Information regarding safe handling, see section 7.
Information regarding personal protective equipment, see section 8.
Information regarding waste disposal, see section 13.

Handling and storage

HANDLING AND STORAGE
Precautions for safe handling

Advice on safe handling Use only in area provided with appropriate exhaust ventilation.

Advice on protection against fire and explosion Keep away from heat and sources of ignition.

Hygiene measures Avoid contact with skin, eyes and clothing. Keep working clothes separately. Wash hands immediately after work, if necessary take a shower. Remove soiled clothing immediately and clean thoroughly before using again. Garments that cannot be cleaned must be destroyed (burnt).
Conditions for safe storage, including any incompatibilities

Requirements for storage areas and containers Store in original container. Keep containers tightly closed in a dry, cool and well-ventilated place. Store in a place accessible by authorized persons only. Keep away from direct sunlight.

Advice on common storage Keep away from food, drink and animal feedingstuffs.

Suitable materials
HDPE (high density polyethylene)


Specific end uses
not applicable

Transport information

Land transport (ADR/RID)

UN number:
not classified as dangerous goods
Shippingopen allclose all
Class:
not classified as dangerous goods
Classification code:
not classified as dangerous goods
Packaging group:
not classified as dangerous goods
Labels:
not classified as dangerous goods
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
not classified as dangerous goods
Shippingopen allclose all
Class:
not classified as dangerous goods
Classification code:
not classified as dangerous goods
Packaging group:
not classified as dangerous goods
Labels:
not classified as dangerous goods
Remarksopen allclose all

Marine transport (IMDG)

UN number:
not classified as dangerous goods
Proper shipping name and description:
not classified as dangerous goods
Chemical name:
not classified as dangerous goods
Class:
not classified as dangerous goods
Packaging group:
not classified as dangerous goods
EmS code:
not classified as dangerous goods
Labels:
not classified as dangerous goods
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
not classified as dangerous goods
Proper shipping name and description:
not classified as dangerous goods
Chemical name:
not classified as dangerous goods
Class:
not classified as dangerous goods
Packaging group:
not classified as dangerous goods
Labels:
not classified as dangerous goods
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters

No control parameters known.

Exposure controls


Respiratory protection If product is handled while not enclosed, and if contact may occur:
Wear respirator with a particle filter mask (protection factor 4) conforming to European norm EN149FFP1 or equivalent.
Respiratory protection should only be used to control residual risk of short duration activities, when all reasonably practicable steps have been taken to reduce exposure at source e.g. containment and/or local extract ventilation. Always follow respirator manufacturer's instructions regarding wearing and maintenance.


Hand protection Wear CE Marked (or equivalent) nitrile rubber gloves (minimum thickness of 0,4 mm). Wash when contaminated and dispose of when contaminated inside, when perforated or when contamination on the outside cannot be removed. Wash hands frequently and always before eating, drinking, smoking or using the toilet.

Eye protection Wear goggles (conforming to EN166, Field of Use = 5 or equivalent).

Skin and body protection Wear standard coveralls and Category 3 Type 4 suit.
If there is a risk of significant exposure, consider a higher protective type suit.
Wear two layers of clothing wherever possible. Polyester/cotton or cotton overalls should be worn under chemical protection suit and should be professionally laundered frequently.
If chemical protection suit is splashed, sprayed or significantly contaminated, decontaminate as far as possible, then carefully remove and dispose of as advised by manufacturer.

General protective measures If product is handled while not enclosed, and if contact may occur:
Complete suit protecting against chemicals

Stability and reactivity

Reactivity

Thermal decomposition
175 - 205 °C, Heating rate: 3 K/min
Endothermic.
Determined in glass.

280 - 355 °C, Heating rate: 3 K/min, Decomposition energy: 355 KJ/kg
Exothermic decomposition.
Determined in glass.

Chemical stability
Stable under recommended storage conditions.


Possibility of hazardous reactions
Incapable of deflagration
No hazardous reactions when stored and handled according to prescribed instructions.


Conditions to avoid
Extremes of temperature and direct sunlight.


Incompatible materials Store only in the original container.


Hazardous decomposition products No decomposition products expected under normal conditions of use.

Disposal considerations

DISPOSAL CONSIDERATIONS
Waste treatment methods

Product
In accordance with current regulations and, if necessary, after consultation with the site operator and/or with the responsible authority, the product may be taken to a waste disposal site or incineration plant.

Contaminated packaging
Not completely emptied packagings should be disposed of as hazardous waste.

Waste key for the unused product
020108 agrochemical waste containing dangerous substances