Registration Dossier

Administrative data

First-aid measures

General information:
Take persons to a safe place. Observe self-protection for first aid. Always seek medical advice in the event of contact with this
substance.

After inhalation
Keep the patient calm. If unconscious place in stable sideways position. Protect against loss of body heat. If breathing stops,
administer artificial respiration. Seek medical advice immediately and clearly identify substance.

After contact with the skin
Remove contaminated clothes at once. Wash off with plenty of water or water and soap immediately for 10-15 minutes. In serious
cases, use emergency shower immediately. Seek medical advice immediately and clearly identify substance.

After contact with the eyes
Rinse immediately with plenty of water for 10-15 minutes. Keep eyelids well open to rinse the whole eye surface and eyelids with
water. Seek medical advice and clearly identify substance.

After swallowing
If conscious, give several small portions of water to drink. Do not induce vomiting. Seek medical advice immediately and clearly
identify substance.
4.6 Advice for the physician
Symptoms of poisoning may not become apparent until after many hours - medical monitoring is therefore required for at least 48
hours after any accident.

Fire-fighting measures

Suitable extinguishing media
water mist , extinguishing powder , alcohol-resistant foam , carbon dioxide , sand .

Extinguishing media which must not be used for safety reasons
water spray , water jet .

Special exposure hazards arising from the substance or preparation itself, combustion products, resulting gases
Hazardous decomposition products: alcohols . Do not allow extinguishing water to enter sewerage, the soil or inshore waters.

Special protective equipment for fire fighting
Use respiratory protection independent of recirculated air.

Accidental release measures

Personal precautions
Wear personal protection equipment (see section 8). Keep unprotected persons away. Avoid contact with eyes and skin. Avoid
inhaling mists and vapours. If material is released indicate risk of slipping.

Environmental precautions
Prevent material from entering surface waters, drains or sewers and soil. Contain any fluid that runs out using suitable material
(e.g. earth). Retain contaminated water/extinguishing water. Dispose of in prescribed marked containers.

Methods for cleaning up
Do not flush away with water. For small amounts: Absorb with a liquid binding material such as diatomaceous earth and dispose
of according to local/state/federal regulations. Contain larger amounts and pump up into suitable containers. Clean any slippery
coating that remains using a detergent / soap solution or another biodegradable cleaner. Exhaust vapours.

Further information:
Eliminate all sources of ignition.

Handling and storage

Handling
Precautions for safe handling:
Ensure adequate ventilation. Keep away from incompatible substances in accordance with section 10.2. Spilled substance
increases risk of slipping.
Precautions against fire and explosion:
Flammable vapors may accumulate and form explosive mixtures with air in containers, process vessels, including partial, empty
and uncleaned containers and vessels, or other enclosed spaces. Keep away from sources of ignition and do not smoke. Take
precautionary measures against electrostatic charging. Cool endangered containers with water.

Storage
Conditions for storage rooms and vessels:
none known
Advice for storage of incompatible materials:
not applicable
Further information for storage:
Protect against moisture. Keep container tightly closed and store in a cool, well ventilated place.

Transport information

Land transport (ADR/RID)

UN number:
1992
Proper shipping name and description:
Entzündbarer flüssiger Stoff, giftig, n.a.g.
Chemical name:
enthält Ethanol und Bis(triethoxysilyl)ethan
Language:
German
Class:
3
Classification code:
FT1
Packaging group:
III
Labels:
3+6.1; flammable liquid + toxic substance
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
1192
Proper shipping name and description:
Entzündbarer flüssiger Stoff, giftig, n.a.g.
Chemical name:
enthält Ethanol und Bis(triethoxysilyl)ethan
Language:
German
Class:
3
Classification code:
FT1
Packaging group:
III
Labels:
3+6.1; flammable liquid + toxic substance
Remarksopen allclose all

Marine transport (IMDG)

UN number:
1992
Proper shipping name and description:
Flammable liquid, toxic, n.o.s.
Chemical name:
contains ethanol and bis(triethoxysilyl)ethane
Class:
3
Packaging group:
III
EmS code:
F-E, S-D
Labels:
3+6.1; flammable liquid + toxic substance
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
1992
Proper shipping name and description:
Flammable liquid, toxic, n.o.s.
Chemical name:
contains ethanol and bis(triethoxysilyl)ethane
Class:
3
Packaging group:
III
Labels:
3+6.1; flammable liquid + toxic substance
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Exposure limits
-
Exposure limited and controlled
Exposure in the work place limited and controlled
General protection and hygiene measures:
Avoid contact with eyes and skin. Do not inhale gases/vapours/aerosols. Do not eat, drink or smoke when handling.
Personal protection equipment
Respiratory protection
In case of long or strong exposure: gas mask filter ABEK .
Hand protection
Protective gloves made of butyl rubber . Gloves suitable for up to 60 minutes' use.
Eye protection
tight fitting protective goggles .
Skin protection
protective clothing .

Exposure to the environment limited and controlled
Prevent material from entering surface waters and soil.

Further information for system design and engineering measures
Observe information in section handling and storage.

Stability and reactivity

General information:
If stored and handled in accordance with standard industrial practices no hazardous reactions are known.

Conditions to avoid
moisture . Heat, open flames, and other sources of ignition.

Materials to avoid
Reacts with water in the presence of: basic substances or acids . Reaction causes the formation of: ethanol .

Hazardous decomposition products
ethanol .

Disposal considerations

Material
Recommendation:
Dispose of according to regulations by incineration in a special waste incinerator. Observe local/state/federal regulations.

Uncleaned packaging
Recommendation:
Completely discharge containers (no tear drops, no powder rest, scraped carefully). Containers may be recycled or re-used.
Observe local/state/federal regulations.