Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

General information:
Remove soiled or soaked clothing immediately.

After inhalation:
When inhaled remove to fresh air and seek medical aid.

After contact with skin:
In case of contact with skin wash off immediately with plenty of water.

After contact with eyes:
In case of contact with eyes rinse thoroughly with plenty of water and seek medical advice.

After ingestion:
Summon a doctor immediately.

Most important symptoms and effects, both acute and delayed
Symptoms: No symptoms known currently.

Indication of any immediate medical attention and special treatment needed
Treatment: Treat symptomatically.

Fire-fighting measures

Suitable extinguishing media:
alcohol-resistant foam
dry powder
carbon dioxide
water spray jet
cool containers by spraying with water

Special hazards arising from the substance or mixture:
In case of fires, hazardous combustion gases are formed: Carbon monoxide (CO).

Advice for firefighters:
Special protective equipment for firefighting.
Use self-contained breathing apparatus.

Accidental release measures

Personal precautions, protective equipment and emergency procedures:
Wear suitable personal protective equipment.

Environmental precautions:
Do not allow to enter drains or waterways.

Methods and material for containment and cleaning up:
Pick up with absorbent material (eg sand, kieselgur, acid binder, universal binder, sawdust).

Handling and storage

Precautions for safe handling

Advice on safe handling:
Ensure adequate ventilation.
Open and handle container with care.

Hygiene measures:
Wash hands before breaks and after work.
Use barrier skin cream.
Remove soiled or soaked clothing immediately and clean thoroughly before using again.

Advice on protection against fire and explosion:
Observe the general rules of industrial fire protection.

Conditions for safe storage, including any incompatibilities
Further information on storage conditions:
Do not leave vessels/containers open
Prevent entry of air/oxygen (peroxide formation).

Transport information

Land transport (ADR/RID)

UN number:
not restricted
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Inland waterway transport (ADN(R))

UN number:
not restricted
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Marine transport (IMDG)

UN number:
not restricted
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Air transport ICAO/IATA

UN number:
not restricted
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Exposure controls / personal protection

General protective measures:
Avoid contact with eyes and skin.

Respiratory protection :
Use respiratory protection in case of insufficient exhaust ventilation or prolonged exposure.
Full mask to standard DIN EN 136.
Filter A (organic gases and vapours) to standard DIN EN 141.
The use of filter apparatus presupposes that the environment atmosphere contains at least 17% oxygen by volume, and does not exceed the maximum gas concentration, usually 0.5% by volume. Relevant guidelines to be considered include EN 136/141/143/371/372 as well as other national regulations.

Hand protection :
For long-term exposure:
Butyl rubber gloves.
Minimum breakthrough time / gloves : 480 min
Minimum thickness / gloves 0,7 mm
For short-term exposure (splash protection):
Nitrile rubber gloves.
Minimum breakthrough time / gloves : 10 min
Minimum thickness / gloves 0,4 mm.
These types of protective gloves are offered by various manufacturers. Please note the manufacturers´ detailed statements, especially about the minimum thickness and the minimum breakthrough time. Consider also the particular working conditions under which the gloves are being used.

Eye protection :
safety glasses

Stability and reactivity

Reactivity:
See under "Possibility of hazardous reactions"

Chemical stability:
Under normal conditions the product is stable.

Possibility of hazardous reactions:
Evolution of peroxides.
No hazardous reactions when stored and handled according to prescribed instructions.
Stable.

Conditions to avoid:
Acids, alkalis, strong oxidizing agents.

Incompatible materials:
not known

Hazardous decomposition products:
When handled and stored appropriately, no dangerous decomposition products are known.

Disposal considerations

Waste treatment methods

Product:
In accordance with current regulations may be taken to waste disposal site or incineration plant, after consultation with site operator and/or with the responsible authority.

Uncleaned packaging:
Packaging that cannot be cleaned should be disposed of as product waste.