Registration Dossier
Registration Dossier
Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
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EC number: 203-904-5 | CAS number: 111-75-1
Guidance on Safe Use
Administrative data
First-aid measures
- General advice: Show this safety data sheet to the doctor in attendance. Call a physician immediately.
- If inhaled: Move to fresh air. Get medical advice/ attention.
- In case of skin contact: Wash off with soap and water. Get medical attention.
- In case of eye contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical advice/ attention.
- If swallowed: Do NOT induce vomiting. Drink plenty of water.
Most important symptoms and effects, both acute and delayed Symptoms: Irritating to eyes, respiratory system and skin.
Indication of any immediate medical attention and special treatment needed Treatment: Treat symptomatically.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media: Water spray; Carbon dioxide (CO2); Dry chemical; Foam
Unsuitable extinguishing media: Do NOT use water jet.
Special hazards arising from the substance or mixture
Hazardous combustion products: Nitrogen oxides (NOx); Carbon oxides
Advice for firefighters
Special protective equipment for firefighters: Wear an approved positive pressure self-contained breathing apparatus in addition to standard fire fighting gear.
Further information: Do not allow run-off from fire fighting to enter drains or water courses.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Personal precautions: Use personal protective equipment. Evacuate personnel to safe areas. Avoid contact with skin, eyes and clothing. Local authorities should be advised if significant spillages cannot be contained.
Environmental precautions
Environmental precautions: Avoid release to the environment. Prevent product from entering drains. Collect spillage.
Methods and material for containment and cleaning up
Methods for cleaning up: Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations.
Handling and storage
Precautions for safe handling
Advice on safe handling: Do not get in eyes. Avoid contact with skin. Use only with adequate ventilation. Wash thoroughly after handling.
Advice on protection against fire and explosion: Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours).
Hygiene measures Handle in accordance with good industrial hygiene and safety practice.
Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers: Keep container tightly closed.
Specific end use(s)
Specific use(s): Chemical intermediate
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Engineering measures
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level.
Personal protective equipment
Eye protection: Safety glasses with side-shields
Hand protection
Remarks: Rubber gloves Neoprene gloves The data about break through time/strength of material are standard values! The exact break through time/strength of material has to be ob-tained from the producer of the protective glove.
Skin and body protection: Complete suit protecting against chemicals
Respiratory protection: Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines.
Filter type: Filter type K
Protective measures: Ensure that eye flushing systems and safety showers are located close to the working place.
Stability and reactivity
Reactivity
Stable under recommended storage conditions.
Chemical stability
Stable under normal conditions.
Possibility of hazardous reactions
Hazardous reactions: Hazardous decomposition products formed under fire condi-tions.
Conditions to avoid
Conditions to avoid: Do not expose to temperatures above: 50 °C. Heat, flames and sparks.
Incompatible materials
Materials to avoid: Strong oxidizing agents; Peroxides
Hazardous decomposition products
- Carbon dioxide (CO2)
- Carbon monoxide
- Nitrogen oxides (NOx)
- Ammonia Hydrogen
- cyanide (hydrocyanic acid)
Disposal considerations
Waste treatment methods
Product: Dispose of in accordance with local regulations.
Contaminated packaging: Empty containers should be taken to an approved waste han-dling site for recycling or disposal.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
