Registration Dossier
Registration Dossier
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EC number: 416-810-6 | CAS number: 111969-64-3 GLYOXYLATE DE MENTHYLE HYDRATÉ; MENTHYL GLYOXYLATE HYDRATE
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures:
Pay attention to self-protection.
Remove victims from hazardous area.
Immediately remove soiled or soaked clothing and remove it to a safe distance. Keep victim warm, in a stabilizedposition and covered.
Do not leave victims unattended.
If the casualty is unconscious: Place the victim in the recovery position.
Inhalation:
Potential for exposure by inhalation if dusts or smoke are generated.
Move victims into fresh air.
With labored breathing: Provide with oxygen.
Consult a doctor.
If the casualty is not breathing: Perform mouth-to-mouth resuscitation, notify emergency physician immediately.
Skin contact:
Wash off affected area immediately with plenty of water.
Continue decontamination with polyethylene glycol 400 after initial rinsing with water and then wash with water and soap.
If symptoms persist, consult a physician for treatment.
Eye contact:
With eye held open, thoroughly rinse immediately with plenty of water for at least 10 minutes.
Consult an ophthalmologist immediately if the symptoms persist.
When dealing with caustic substances, notify emergency physician immediately (key words: burns in eye).
Ingestion:
Rinse out mouth.
Immediately give large quantities of water to drink.
Consult a physician immediately.
When dealing with caustic substances, notify emergency physician immediately.
Most important symptoms and effects, both acute and delayed:
Indication of any immediate medical attention and special treatment needed:
The initial focus is only on the local action, possibly characterized by a progressive tissue irritation; caustic substances result in quickly progressing deep tissue damage.
In the eye, caustic dusts or smoke cause, depending on the intensity of exposure, severe irritation, destruction, and ablation of the epithelium of the conjunctiva and cornea,corneal clouding, edema and ulcerations.
Danger! Possible loss of eyesight!
Superficial irritations and damage up to ulcerations and scarring develop on the skin.
After accidental absorption in the body, the pathology and clinical findings are dependent on the kinetics of the substance (quantity of absorbed substance, the absorption time, and the effectiveness of early elimination measures (first aid)/ excretion - metabolism).
A specific action of the substance is unknown.
Pay attention to self-protection.
Remove victims from hazardous area.
Immediately remove soiled or soaked clothing and remove it to a safe distance. Keep victim warm, in a stabilizedposition and covered.
Do not leave victims unattended.
If the casualty is unconscious: Place the victim in the recovery position.
Inhalation:
Potential for exposure by inhalation if dusts or smoke are generated.
Move victims into fresh air.
With labored breathing: Provide with oxygen.
Consult a doctor.
If the casualty is not breathing: Perform mouth-to-mouth resuscitation, notify emergency physician immediately.
Skin contact:
Wash off affected area immediately with plenty of water.
Continue decontamination with polyethylene glycol 400 after initial rinsing with water and then wash with water and soap.
If symptoms persist, consult a physician for treatment.
Eye contact:
With eye held open, thoroughly rinse immediately with plenty of water for at least 10 minutes.
Consult an ophthalmologist immediately if the symptoms persist.
When dealing with caustic substances, notify emergency physician immediately (key words: burns in eye).
Ingestion:
Rinse out mouth.
Immediately give large quantities of water to drink.
Consult a physician immediately.
When dealing with caustic substances, notify emergency physician immediately.
Most important symptoms and effects, both acute and delayed:
Indication of any immediate medical attention and special treatment needed:
The initial focus is only on the local action, possibly characterized by a progressive tissue irritation; caustic substances result in quickly progressing deep tissue damage.
In the eye, caustic dusts or smoke cause, depending on the intensity of exposure, severe irritation, destruction, and ablation of the epithelium of the conjunctiva and cornea,corneal clouding, edema and ulcerations.
Danger! Possible loss of eyesight!
Superficial irritations and damage up to ulcerations and scarring develop on the skin.
After accidental absorption in the body, the pathology and clinical findings are dependent on the kinetics of the substance (quantity of absorbed substance, the absorption time, and the effectiveness of early elimination measures (first aid)/ excretion - metabolism).
A specific action of the substance is unknown.
Fire-fighting measures
Suitable extinguishing media:
Water spray, foam, CO2, dry powder.
Unsuitable extinguishing media:
Do not use a solid water stream as it may scatter and spread fire.
Special hazards arising from the substance or mixture:
In the case of fire, the following hazardous smoke fumes may be produced:
Carbon oxides, Nitrogen oxides (NOx)
Under certain fire conditions, traces of other toxic products may occur.
Special protective equipment for fire-fighters:
In case of fire: wear a self contained respiratory apparatus.
Full protective suit.
Advice for firefighters:
Contaminated extinguishing water must be treated at a suitable disposal plant in accordance with waste management laws.
In case of fire, remove the endangered containers and bring to a safe place, if this can be done safely.
Keep out unprotected persons.
Water spray, foam, CO2, dry powder.
Unsuitable extinguishing media:
Do not use a solid water stream as it may scatter and spread fire.
Special hazards arising from the substance or mixture:
In the case of fire, the following hazardous smoke fumes may be produced:
Carbon oxides, Nitrogen oxides (NOx)
Under certain fire conditions, traces of other toxic products may occur.
Special protective equipment for fire-fighters:
In case of fire: wear a self contained respiratory apparatus.
Full protective suit.
Advice for firefighters:
Contaminated extinguishing water must be treated at a suitable disposal plant in accordance with waste management laws.
In case of fire, remove the endangered containers and bring to a safe place, if this can be done safely.
Keep out unprotected persons.
Accidental release measures
Personal precautions, protective equipment and emergency procedures:
Avoid contact with the skin and the eyes.
Avoid breathing dust.
Wear personal protective equipment.
Keep unauthorized persons away.
Environmental precautions:
Prevent substance from entering soil, natural bodies of water and sewer systems.
If the product contaminates rivers and lakes or drains inform respective authorities.
Methods and material for containment and cleaning up:
Pick up mechanically and collect in a suitable container.
Avoid formation of dust.
To absorb spilled substance an approved industrial vacuum cleaner is recommended.
If necessary, the spilled substance should be moistened.
Waste to be packed like clean product and to be marked.
Identification label on packages not to be removed until recycling.
Keep in suitable, closed containers for disposal.
Disposal according to local authority regulations.
Avoid contact with the skin and the eyes.
Avoid breathing dust.
Wear personal protective equipment.
Keep unauthorized persons away.
Environmental precautions:
Prevent substance from entering soil, natural bodies of water and sewer systems.
If the product contaminates rivers and lakes or drains inform respective authorities.
Methods and material for containment and cleaning up:
Pick up mechanically and collect in a suitable container.
Avoid formation of dust.
To absorb spilled substance an approved industrial vacuum cleaner is recommended.
If necessary, the spilled substance should be moistened.
Waste to be packed like clean product and to be marked.
Identification label on packages not to be removed until recycling.
Keep in suitable, closed containers for disposal.
Disposal according to local authority regulations.
Handling and storage
Handling:
Precautions for safe handling:
Wear personal protective equipment.
Avoid residues of the product on the containers.
Storage:
Conditions for safe storage, including any incompatibilities:
Store in the original receptacle, keeping this tightly sealed, under cool and dry conditions.
Further information:
In the event of internal transportation, already-opened containers are to be kept closed in order to avoid spillage.
Secure container from falling down.
Advice on common storage:
No special precautions required.
German storage class:
Combustible / non-combustible liquids and solids not assigned to other storage classes.
Precautions for safe handling:
Wear personal protective equipment.
Avoid residues of the product on the containers.
Storage:
Conditions for safe storage, including any incompatibilities:
Store in the original receptacle, keeping this tightly sealed, under cool and dry conditions.
Further information:
In the event of internal transportation, already-opened containers are to be kept closed in order to avoid spillage.
Secure container from falling down.
Advice on common storage:
No special precautions required.
German storage class:
Combustible / non-combustible liquids and solids not assigned to other storage classes.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (L-(-)-Menthylglyoxylate)
- Chemical name:
- (L-(-)-Menthylglyoxylate)
- Language:
- English
- Labels:
- 9
Special provisions / remarks
- Remarks:
- Environmentally Hazardous
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (L-(-)-Menthylglyoxylate)
- Chemical name:
- (L-(-)-Menthylglyoxylate)
- Language:
- English
- Labels:
- 9
Special provisions / remarks
- Remarks:
- Environmentally Hazardous
Marine transport (UN RTDG/IMDG)
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (L-(-)-Menthylglyoxylate)
- Chemical name:
- (L-(-)-Menthylglyoxylate)
- Labels:
- 9
- Marine pollutant
Special provisions / remarks
- Remarks:
- Marine pollutant
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- Environmentally hazardous substance, solid, n.o.s. (L-(-)-Menthylglyoxylate)
- Chemical name:
- (L-(-)-Menthylglyoxylate)
- Labels:
- 9
Special provisions / remarks
- Remarks:
- Environmentally Hazardous
IATA_C:
ERG-Code: 9L IATA_P:
ERG-Code: 9L
Additional transport information
Additional information
- Special provisions / remarks / other:
- Combination traffic:
Labelling of containers / shipping units following main product run as per sea or air transport regulations.
Exposure controls / personal protection
Control parameters:
Exposure limit for dust:
Control parameters: 10 mg/m³ AGW: (TRGS 900)
Type of exposure: Inhalable fraction.
General dust limiting value(s):
Suitable measuring processes are: BIA method 7284
Control parameters: 3 mg/m³ AGW:(TRGS 900)
Type of exposure: as alveolar accessible part.
General dust limiting value(s):
Suitable measuring processes are: BIA method 6068 TRGS 901, Part II, Number 96 DIN EN 481
Engineering measures:
If possible, use material transfer/filling, metering and blending plants that are closed, or provide for local suction devices.
If dust occurs: Ensure suitable suction/aeration at the work place and with operational machinery.
Provide for installation of emergency shower and eye bath.
Personal protective equipment:
Respiratory protection:
Wear dust mask in the presence of dust.
When handling for a short time:
If dust occurs: Respirator with ABEK-P2 combination filter
In the event of prolonged exposure during handling: wear a self contained respiratory apparatus.
Note time limit for wearing respiratory protective equipment.
Hand protection:
Applies to handling for brief periods or of small amounts:
Glove material: Nitrile, for example: Camatril 731, Kächele-Cama Latex GmbH (KCL), Germany.
Material thickness: 0.33 mm
Method: DIN EN 374
Applies to handling for longer periods or of large amounts:
Glove material: Nitrile/Chloroprene, for example, Nitopren 717, Kächele-Cama Latex GmbH (KCL), Germany.
Material thickness: 0.65 mm
Methode: DIN EN 374
Eye protection:
Safety glasses with side-shields conforming to EN166
or
When handling larger quantities: basket-shaped glasses.
Skin and body protection:
Usual lab protective clothing
or
When handling larger quantities: chemical protective suit, disposable protective suit.
Hygiene measures:
Remove and wash contaminated clothing before re-use.
No eating, drinking, smoking, or snuffing tobacco at work.
Wash face and/or hands before break and end of work.
Use suitable skin protective agents before handling product.
Cleanse and apply cream to skin after work. Preventive skin protection recommended.
Implement skin protection measures according to skin protection schedule.
Protective measures:
Handle in accordance with good industrial hygiene and safety practices.
The personal protective equipment used must meet the requirements of directive 89/686/EEC and amendments (CE certification).
Exposure limit for dust:
Control parameters: 10 mg/m³ AGW: (TRGS 900)
Type of exposure: Inhalable fraction.
General dust limiting value(s):
Suitable measuring processes are: BIA method 7284
Control parameters: 3 mg/m³ AGW:(TRGS 900)
Type of exposure: as alveolar accessible part.
General dust limiting value(s):
Suitable measuring processes are: BIA method 6068 TRGS 901, Part II, Number 96 DIN EN 481
Engineering measures:
If possible, use material transfer/filling, metering and blending plants that are closed, or provide for local suction devices.
If dust occurs: Ensure suitable suction/aeration at the work place and with operational machinery.
Provide for installation of emergency shower and eye bath.
Personal protective equipment:
Respiratory protection:
Wear dust mask in the presence of dust.
When handling for a short time:
If dust occurs: Respirator with ABEK-P2 combination filter
In the event of prolonged exposure during handling: wear a self contained respiratory apparatus.
Note time limit for wearing respiratory protective equipment.
Hand protection:
Applies to handling for brief periods or of small amounts:
Glove material: Nitrile, for example: Camatril 731, Kächele-Cama Latex GmbH (KCL), Germany.
Material thickness: 0.33 mm
Method: DIN EN 374
Applies to handling for longer periods or of large amounts:
Glove material: Nitrile/Chloroprene, for example, Nitopren 717, Kächele-Cama Latex GmbH (KCL), Germany.
Material thickness: 0.65 mm
Methode: DIN EN 374
Eye protection:
Safety glasses with side-shields conforming to EN166
or
When handling larger quantities: basket-shaped glasses.
Skin and body protection:
Usual lab protective clothing
or
When handling larger quantities: chemical protective suit, disposable protective suit.
Hygiene measures:
Remove and wash contaminated clothing before re-use.
No eating, drinking, smoking, or snuffing tobacco at work.
Wash face and/or hands before break and end of work.
Use suitable skin protective agents before handling product.
Cleanse and apply cream to skin after work. Preventive skin protection recommended.
Implement skin protection measures according to skin protection schedule.
Protective measures:
Handle in accordance with good industrial hygiene and safety practices.
The personal protective equipment used must meet the requirements of directive 89/686/EEC and amendments (CE certification).
Stability and reactivity
Conditions to avoid:
No dangerous reaction known under conditions of normal use.
No dangerous reaction known under conditions of normal use.
Disposal considerations
Product:
Waste to be packed like clean product and to be marked.
Identification label on packages not to be removed until recycling.
The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.
Uncleaned packaging:
Do not reuse empty containers and dispose of in accordance with the regulations issued by the appropriate local authorities.
Waste to be packed like clean product and to be marked.
Identification label on packages not to be removed until recycling.
The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.
Uncleaned packaging:
Do not reuse empty containers and dispose of in accordance with the regulations issued by the appropriate local authorities.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
