Registration Dossier

Administrative data

First-aid measures

General advice: Take off immediately all contaminated clothing.

Dust inhalation: Blow nose. Move to fresh air. Oxygen or artificial respiration if needed. Hospitalize immediately.

Skin contact: Wash immediately, abundantly and thoroughly with soap and water. Consult a doctor quickly. In case of extensive burns: Hospitalize immediately.

Eye contact: Wash open eyes immediately, abundantly and thoroughly for at least 15 minutes. Consult an ophthalmologist immediately.

Ingestion: Do not induce vomiting, rinse mouth and lips with plenty of water if the subject is conscious, then hospitalize.

Protection of first-aiders: In case of insufficient ventilation, wear suitable respiratory equipment. Protective suit

Fire-fighting measures

Suitable extinguishing media: Foam, Carbon dioxide (CO2), Water spray
Unsuitable extinguishing media: High volume water jet

Special hazards arising from the substance or mixture:
Thermal decomposition giving toxic and corrosive products, Carbon oxides, Tin oxides, Hydrogen chloride gas

Advice for firefighters:
Specific methods: In case of fire nearby, remove exposed containers. Use water spray to cool unopened containers

Special protective actions for fire-fighters: Wear self-contained breathing apparatus and protective suit.

Accidental release measures

Personal precautions, protective equipment and emergency procedures:
Evacuate non-essential staff and those not equipped with individual protection apparatus. Do not smoke. Prohibit contact with skin and eyes and inhalation of dusts. Wear respiratory protection. Use personal protective equipment.

Environmental precautions: Do not release into the environment. Do not let product enter drains.

Methods and materials for containment and cleaning up:
Recovery:
Shovel or sweep up. After cleaning, flush away traces with water. Recover product from waste water by decanting. Recover waste water for
processing later.

Elimination:
Destroy the product by incineration (in accordance with local and national regulations). Dispose of rinse water in accordance with local and
national regulations.

Handling and storage

Precautions for safe handling: Technical measures/Precautions:
Storage and handling precautions applicable to products: Solid. VERY TOXIC. Corrosive. Provide appropriate
exhaust ventilation at machinery and at places where dust can be generated. Provide showers, eye-baths. Provide self-contained breathing
apparatus nearby. Provide electrical earthing of equipment.


Safe handling advice:
Strictly limit the quantities of product in the work area to those which are absolutely necessary for the work in hand. Great cleanliness in work
areas is a necessary and important factor for safety. Take maximum precautions when handling. Handle and open container with care. Keep
container closed when not in use. Follow the safety instructions. Do not permit any leak. Use only with adequate ventilation. In case of
insufficient ventilation, wear wear self contained breathing apparatus.

Hygiene measures:
Prohibit contact with skin and eyes and inhalation of dust (or vapours). Follow general hygiene guidelines. When using do not eat, drink or
smoke. Wash hands after handling. Remove contaminated clothing and protective equipment before entering eating areas.


Conditions for safe storage, including any incompatibilities:
Store in original container. Keep container tightly closed and in a well-ventilated place. Store protected from moisture and heat. Do not permit any leak. Provide
impermeable floor. Take all necessary measures to prevent accidental spillages of the product from entering into drains and water courses in
the event of failure of containers or transfer systems. Provide earthing and safe electrical equipment.

Incompatible products: Strong acids, Reducing agents, Bases

Packaging material:
Recommended: Stainless steel, High density polyethylene (HDPE)

Transport information

Land transport (ADR/RID)

UN number:
2928
Proper shipping name and description:
TOXIC SOLID, CORROSIVE, ORGANIC,
N.O.S.(DIMETHYLTIN DICHLORIDE, METHYLTIN
TRICHLORIDE)
Chemical name:
(DIMETHYLTIN DICHLORIDE, METHYLTIN TRICHLORIDE)
Language:
English
Class:
6.1
Packaging group:
II
Labels:
6.1 + 8
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
2928
Proper shipping name and description:
TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S.
(DIMETHYLTIN DICHLORIDE, METHYLTIN
TRICHLORIDE)
Chemical name:
(DIMETHYLTIN DICHLORIDE, METHYLTIN
TRICHLORIDE)
Language:
English
Class:
6.1
Packaging group:
II
Labels:
6.1 + 8
Remarksopen allclose all

Marine transport (IMDG)

UN number:
2928
Proper shipping name and description:
CORROSIVE SOLID, TOXIC,
N.O.S.(DIMETHYLTIN DICHLORIDE, METHYLTIN
TRICHLORIDE)
Chemical name:
(DIMETHYLTIN DICHLORIDE, METHYLTIN TRICHLORIDE)
Class:
6.1
Packaging group:
II
EmS code:
EmS Number: F-A, S-B
Mark: MP
Labels:
6.1 + 8
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
2928
Proper shipping name and description:
Toxic solid, corrosive, organic, n.o.s. (Dimethyltin
dichloride, Methyltintrichloride)
Chemical name:
(Dimethyltin dichloride, Methyltintrichloride)
Class:
6.1
Packaging group:
II
Labels:
6.1 + 8
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

CONTROL PARAMETERS:
Exposure Limit Values
Organotin compounds
Source Date Value type Value (ppm) Value (mg/m3) Remarks
ACGIH (US) 2008 TWA – 0,1 as Sn
ACGIH (US) 2008 STEL – 0,2 as Sn
ACGIH (US) 2008 SKIN – – Can be absorbed through the skin.

EXPOSURE CONTROLS:
General protective measures: Ensure sufficient air exchange and/or exhaust in work areas
Personal protective equipment:
Respiratory protection: Dust mask recommended. Recommended Filter type: P2
Respiratory protection complying with EN 143., In the case of hazardous fumes, wear self contained breathing apparatus.

Hand protection: Gloves (PVC, neoprene, nitrile rubber)

Eye/face protection: Safety glasses with side-shields

Skin and body protection: Protective clothing (remove and wash contaminated clothing before re-use)

Stability and reactivity

Reactivity & Chemical stability: The product is stable at normal handling and storage temperatures.

Possibility of hazardous reactions:
In presence of moisture : Hydrolyses (formation of : Hydrochloric acid)

Conditions to avoid: Heat, flames and sparks. Exposure to sunlight. Exposure to light. Exposure to moisture..

Incompatible materials to avoid: Strong acids, Reducing agents, Bases

Hazardous decomposition products: Thermal decomposition: Decomposition temperature: > 200 °C
Thermal decomposition giving toxic and corrosive products :, Carbon oxides, Tin oxides, Hydrogen chloride gas

Disposal considerations

Disposal of product: Destroy the product by incineration (in accordance with local and national regulations).


Disposal of packaging: Clean container with water and recover this water. Destroy packaging by incineration at an approved
waste disposal site. Can be disposed of as waste water, when in compliance with local regulations.