Registration Dossier

Identification

Chemical structure
Display Name:
nickel, 5,5'-azobis-2,4,6(1H,3H,5H)-pyrimidinetrione complexes and melamine
EC Number:
939-379-0
Molecular formula:
C8H4N6O6Ni
IUPAC Name:
nickel, 5,5'-azobis-2,4,6(1H,3H,5H)-pyrimidinetrione complexes and melamine

Type of substance

Composition:
multi-constituent substance
Origin:
organic

Total tonnage band

Total range:
100 - 1 000 tonnes per annum

REACH

Registered as:
FULL
Submitted:
Joint Submission

Publication dates

First published:
05-Sep-2013
Last modified:
19-Sep-2020

Chemical safety assessment

Performed for this substance:
YES

Compositions open all close all

Type:
boundary composition of the substance
State Form:
solid: nanoform


Constituent 1
Chemical structure
Reference substance name:
Nickel, 5,5'-azobis-2,4,6(1H,3H,5H)-pyrimidinetrione complexes
EC Number:
270-944-8
EC Name:
Nickel, 5,5'-azobis-2,4,6(1H,3H,5H)-pyrimidinetrione complexes
CAS Number:
68511-62-6
Molecular formula:
C8H6N6O6Ni
IUPAC Name:
Nickel, 5,5'-azobis-2,4,6(1H,3H,5H)-pyrimidinetrione complexes
Constituent 2
Chemical structure
Reference substance name:
Melamine
EC Number:
203-615-4
EC Name:
Melamine
CAS Number:
108-78-1
Molecular formula:
C3H6N6
IUPAC Name:
1,3,5-triazine-2,4,6-triamine
Type:
legal entity composition of the substance
State Form:
solid: nanoform


Constituent 1
Chemical structure
Reference substance name:
Melamine
EC Number:
203-615-4
EC Name:
Melamine
CAS Number:
108-78-1
Molecular formula:
C3H6N6
IUPAC Name:
1,3,5-triazine-2,4,6-triamine
Constituent 2
Chemical structure
Reference substance name:
Nickel, 5,5'-azobis-2,4,6(1H,3H,5H)-pyrimidinetrione complexes
EC Number:
270-944-8
EC Name:
Nickel, 5,5'-azobis-2,4,6(1H,3H,5H)-pyrimidinetrione complexes
CAS Number:
68511-62-6
Molecular formula:
C8H6N6O6Ni
IUPAC Name:
Nickel, 5,5'-azobis-2,4,6(1H,3H,5H)-pyrimidinetrione complexes
Constituent 3
Chemical structure
Reference substance name:
zinc, 5,5’-azobis-2,4,6(1H,3H,5H)-pyrimidinetrione dihydrate complexes
Molecular formula:
C8H4N6O6Zn x 2H2O
IUPAC Name:
zinc, 5,5’-azobis-2,4,6(1H,3H,5H)-pyrimidinetrione dihydrate complexes
Type:
legal entity composition of the substance
State Form:
solid: particulate/powder


Constituent 1
Chemical structure
Reference substance name:
Nickel, 5,5'-azobis-2,4,6(1H,3H,5H)-pyrimidinetrione complexes
EC Number:
270-944-8
EC Name:
Nickel, 5,5'-azobis-2,4,6(1H,3H,5H)-pyrimidinetrione complexes
CAS Number:
68511-62-6
Molecular formula:
C8H6N6O6Ni
IUPAC Name:
Nickel, 5,5'-azobis-2,4,6(1H,3H,5H)-pyrimidinetrione complexes
Constituent 2
Chemical structure
Reference substance name:
Melamine
EC Number:
203-615-4
EC Name:
Melamine
CAS Number:
108-78-1
Molecular formula:
C3H6N6
IUPAC Name:
1,3,5-triazine-2,4,6-triamine
Type:
legal entity composition of the substance
State Form:
solid: nanoform


Constituent 1
Chemical structure
Reference substance name:
Nickel, 5,5'-azobis-2,4,6(1H,3H,5H)-pyrimidinetrione complexes
EC Number:
270-944-8
EC Name:
Nickel, 5,5'-azobis-2,4,6(1H,3H,5H)-pyrimidinetrione complexes
CAS Number:
68511-62-6
Molecular formula:
C8H6N6O6Ni
IUPAC Name:
Nickel, 5,5'-azobis-2,4,6(1H,3H,5H)-pyrimidinetrione complexes
Constituent 2
Chemical structure
Reference substance name:
Melamine
EC Number:
203-615-4
EC Name:
Melamine
CAS Number:
108-78-1
Molecular formula:
C3H6N6
IUPAC Name:
1,3,5-triazine-2,4,6-triamine

Characterisation of nanoforms

Type of information reported:
single nanoform

Shape

Shape description
Shape category:
platelet
Shape:
plate
Pure shape:
no
Typical composition:
96.7 %
Range:
> 95 - < 100 %

Particle size distribution and range

Particle size distribution and range
Shape category:
platelet
Percentileopen allclose all
Percentile:
D10
Typical value:
17 nm
Range:
> 15 - < 20 nm
Percentile:
D50
Typical value:
27 nm
Range:
> 25 - < 30 nm
Percentile:
D90
Typical value:
45 nm
Range:
> 42 - < 49 nm
Typical lateral dimension 1:
49.4 nm
Range of lateral dimension 1:
> 17.8 - < 166 nm
Typical lateral dimension 2:
29 nm
Range of lateral dimension 2:
> 11.8 - < 54.5 nm
Typical aspect ratio (:1):
1.75 :1
Range of aspect ratio (:1):
>= 1.17 - <= 2.33
Fraction of constituent particles in the size range 1-100 nm:
>= 99 - <= 100 %

Crystallinity

Structures
Structure:
partially-crystalline
Pure structure:
no
Range:
> 70 - < 76 %

Specific surface area

Typical specific surface area:
115.3 m²/g
Range of specific surface area:
>= 63.5 - <= 130.2 m²/g
Typical volume specific surface area:
150.7 m²/cm³
Range of volume specific surface area:
>= 110 - <= 240.6 m²/cm³
Skeletal density:
>= 1.716 - <= 1.864 g/cm³

Surface functionalisation / treatment

Surface treatment applied:
no
Type:
legal entity composition of the substance
State Form:
solid: particulate/powder


Constituent 1
Chemical structure
Reference substance name:
Nickel, 5,5'-azobis-2,4,6(1H,3H,5H)-pyrimidinetrione complexes
EC Number:
270-944-8
EC Name:
Nickel, 5,5'-azobis-2,4,6(1H,3H,5H)-pyrimidinetrione complexes
CAS Number:
68511-62-6
Molecular formula:
C8H6N6O6Ni
IUPAC Name:
Nickel, 5,5'-azobis-2,4,6(1H,3H,5H)-pyrimidinetrione complexes
Constituent 2
Chemical structure
Reference substance name:
Melamine
EC Number:
203-615-4
EC Name:
Melamine
CAS Number:
108-78-1
Molecular formula:
C3H6N6
IUPAC Name:
1,3,5-triazine-2,4,6-triamine
Type:
legal entity composition of the substance


Constituent 1
Chemical structure
Reference substance name:
Nickel, 5,5'-azobis-2,4,6(1H,3H,5H)-pyrimidinetrione complexes
EC Number:
270-944-8
EC Name:
Nickel, 5,5'-azobis-2,4,6(1H,3H,5H)-pyrimidinetrione complexes
CAS Number:
68511-62-6
Molecular formula:
C8H6N6O6Ni
IUPAC Name:
Nickel, 5,5'-azobis-2,4,6(1H,3H,5H)-pyrimidinetrione complexes
Constituent 2
Chemical structure
Reference substance name:
Melamine
EC Number:
203-615-4
EC Name:
Melamine
CAS Number:
108-78-1
Molecular formula:
C3H6N6
IUPAC Name:
1,3,5-triazine-2,4,6-triamine
Type:
legal entity composition of the substance
State Form:
solid: particulate/powder


Constituent 1
Chemical structure
Reference substance name:
Nickel, 5,5'-azobis-2,4,6(1H,3H,5H)-pyrimidinetrione complexes
EC Number:
270-944-8
EC Name:
Nickel, 5,5'-azobis-2,4,6(1H,3H,5H)-pyrimidinetrione complexes
CAS Number:
68511-62-6
Molecular formula:
C8H6N6O6Ni
IUPAC Name:
Nickel, 5,5'-azobis-2,4,6(1H,3H,5H)-pyrimidinetrione complexes
Constituent 2
Chemical structure
Reference substance name:
Melamine
EC Number:
203-615-4
EC Name:
Melamine
CAS Number:
108-78-1
Molecular formula:
C3H6N6
IUPAC Name:
1,3,5-triazine-2,4,6-triamine
Type:
legal entity composition of the substance
State Form:
solid: nanoform


Constituent 1
Chemical structure
Reference substance name:
Nickel, 5,5'-azobis-2,4,6(1H,3H,5H)-pyrimidinetrione complexes
EC Number:
270-944-8
EC Name:
Nickel, 5,5'-azobis-2,4,6(1H,3H,5H)-pyrimidinetrione complexes
CAS Number:
68511-62-6
Molecular formula:
C8H6N6O6Ni
IUPAC Name:
Nickel, 5,5'-azobis-2,4,6(1H,3H,5H)-pyrimidinetrione complexes
Constituent 2
Chemical structure
Reference substance name:
Melamine
EC Number:
203-615-4
EC Name:
Melamine
CAS Number:
108-78-1
Molecular formula:
C3H6N6
IUPAC Name:
1,3,5-triazine-2,4,6-triamine

Characterisation of nanoforms

Type of information reported:
single nanoform

Shape

Shape description
Shape category:
spheroidal
Shape:
spherical
Pure shape:
yes

Particle size distribution and range

Particle size distribution and range
Shape category:
spheroidal
Percentileopen allclose all
Percentile:
D10
Typical value:
ca. 32 nm
Range:
>= 30 - <= 35 nm
Percentile:
D50
Typical value:
ca. 42 nm
Range:
>= 40 - <= 45 nm
Percentile:
D90
Typical value:
ca. 58 nm
Range:
>= 55 - <= 60 nm
Typical length:
ca. 43 nm
Typical aspect ratio (:1):
ca. 1.49 :1
Fraction of constituent particles in the size range 1-100 nm:
>= 95 - <= 100 %

Crystallinity

Structures
Structure:
amorphous
Pure structure:
yes

Specific surface area

Typical specific surface area:
ca. 117 m²/g
Range of specific surface area:
>= 116 - <= 118 m²/g
Typical volume specific surface area:
ca. 212.9 m²/cm³
Skeletal density:
ca. 1.82 g/cm³

Surface functionalisation / treatment

Surface treatment applied:
no

Registrants / Suppliers Details open all close all

Registrant / Supplier Registered Updated
Colorants Solutions Deutschland GmbH Brüningstrasse 50 65929 Frankfurt am Main Germany 2017
Lanxess Deutschland GmbH Kennedyplatz 1 50569 Köln Germany 2013 2016
Only representative (No publishable name) 2017
Sun Chemical B.V. Leeuwenveldseweg 3-t 1382 LV Weesp Netherlands 2017
Synthesia, a.s. Semtín103 53002 Pardubice Czech Republic 2013 2020
TOYO INK EUROPE SPECIALTY CHEMICALS Boulevard Dambourney 76350 Oissel France 2018 2020
Registrant / Supplier Registered Ceased manufacture
Trust Chem Europe B.V. Bergpoortstraat 65 NL-7411 CL Deventer Netherlands 2017 2020

Administrative data open all close all

  • 01-2119970317-33-0000
  • 01-2119970317-33-0001
  • 01-2119970317-33-0002
  • 01-2119970317-33-0003
  • 01-2119970317-33-0004
  • 01-2119970317-33-0006
  • 01-2119970317-33-0007

Contact Persons responsible for the SDS open all close all

  • Trust Chem Europe B.V., Bergpoortstraat 65, NL-7411 CL, Deventer, Netherlands (the)
  • Lanxess Deutschland GmbH, 51369, Leverkusen, Germany