Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

Description of first aid measures:

If inhaled: Remove to fresh air. If symptoms persist, call a physician.

In case of skin contact: Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water for at least 15 minutes. If symptoms persist, call a physician.

In case of eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If symptoms persist, call a physician.

If swallowed: Give small amounts of water to drink. Do NOT induce vomiting. Rinse mouth, ingest activated charcoal. Never give anything by mouth to an unconscious person. If a person vomits when lying on his back, place him in the recovery position. Keep respiratory tract clear. Get medical attention immediately.

Most important symptoms and effects, both acute and delayed
Symptoms: irritant effects
Risks: irritant effects

Indication of any immediate medical attention and special treatment needed
Treatment: The first aid procedure should be established in consultation with the doctor responsible for industrial medicine.

Fire-fighting measures

Extinguishing media
Suitable extinguishing media: Water mist, Foam, Carbon dioxide (CO2), Dry powder, ABC powder.
Unsuitable extinguishing media: High volume water jet

Special hazards arising from the substance or mixture
Specific hazards during firefighting: No information available.

Advice for firefighters
Special protective equipment for firefighters: Wear a positive-pressure supplied-air respirator with full face-piece. Use personal protective equipment.

Further information: Prevent fire extinguishing water from contaminating surface water or the ground water system.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Personal precautions: Use personal protective equipment. Do not breathe dust. Avoid contact with skin and eyes.

Environmental precautions
Environmental precautions: Should not be released into the environment. Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration.

Methods and material for containment and cleaning up
Methods for cleaning up: Remove all sources of ignition. Pick up and arrange disposal without creating dust.

Handling and storage

Precautions for safe handling
Advice on safe handling: Handle in accordance with good industrial hygiene and safety practice. Avoid dust formation. May form explosive dust-air mixture. Keep away from sources of ignition - No smoking. Use only with adequate ventilation.

Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers: Keep container tightly closed. Keep in a well-ventilated place.

Further information on storage conditions: Incompatible with oxidizing agents. Incompatible with strong acids and bases.

Advice on common storage: Never allow product to get in contact with water during storage.

Other data: Stable under recommended storage conditions.

Specific end use(s)
Specific use(s): Polymer additive

Transport information

Land transport (ADR/RID)

UN number:
3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(3,9-bis(2,4-di-tert-butylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane)
Chemical name:
3,9-bis(2,4-di-tert-butylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane
Language:
English
Class:
9
Classification code:
M7
Packaging group:
III
Labels:
9
Special Provisions:
Tunnel restriction code: full load, tank-container, (E)
Remarks:
Hazard Identification: 90

Inland waterway transport (ADN(R))

UN number:
3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(3,9-bis(2,4-di-tert-butylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane)
Chemical name:
3,9-bis(2,4-di-tert-butylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane
Class:
9
Classification code:
M7
Packaging group:
III
Labels:
9
Remarksopen allclose all

Marine transport (IMDG)

UN number:
3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(3,9-bis(2,4-di-tert-butylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane)
Chemical name:
3,9-bis(2,4-di-tert-butylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane
Class:
9
Packaging group:
III
EmS code:
EmS Number 1: F-A
EmS Number 2: S-F
Labels:
9
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
3077
Proper shipping name and description:
Environmentally hazardous substance, solid, n.o.s.
(3,9-bis(2,4-di-tert-butylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane)
Chemical name:
3,9-bis(2,4-di-tert-butylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane
Class:
9
Packaging group:
III
Labels:
9
Remarks
Packing instruction (cargo aircraft): 956
Packing instruction (passenger aircraft): 956
Packing instruction (passenger aircraft): Y956

Additional transport information

Additional transport information
Not regulated by DOT and TDG if shipped or transported in packaging less than 400KG by road and/or rail.

Exposure controls / personal protection

Control parameters
Contains no substances with occupational exposure limit values.

Exposure controls
Engineering measures: Ensure that eyewash stations and safety showers are close to the workstation location. Effective exhaust ventilation system

Personal protective equipment
Eye protection: Safety glasses with side-shields

Hand protection: Nitrile rubber

Skin and body protection: Impervious clothing

Respiratory protection: In the case of dust or aerosol formation use respirator with an approved filter. Respirator with a dust filter

Stability and reactivity

Reactivity
No dangerous reaction known under conditions of normal use.

Chemical stability
No decomposition if stored normally.

Possibility of hazardous reactions
Hazardous reactions: No dangerous reaction known under conditions of normal use.

Conditions to avoid
Conditions to avoid: Extremes of temperature and direct sunlight.

Incompatible materials
Materials to avoid: Water, Oxidizing agents, Acids and bases.

Hazardous decomposition products
Hazardous decomposition products: Carbon oxides, Hydrocarbons, Oxides of phosphorus, Phosphorus compounds.

Disposal considerations

Waste treatment methods
Product: In accordance with local and national regulations.

Contaminated packaging: Empty remaining contents. Dispose of as unused product.