Registration Dossier
Registration Dossier
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EC number: 428-320-1 | CAS number: 71308-16-2
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures:
Pay attention to self-protection.
Remove victims from hazardous area.
Immediately remove soiled or soaked clothing and remove it to a safe distance.
Keep victim warm, in a stabilized position and covered.
Do not leave victims unattended.
If the casualty is unconscious: Place the victim in the recovery position.
Inhalation:
Potential for exposure by inhalation if dusts or smoke are generated.
Move victims into fresh air.
With labored breathing: Provide with oxygen.
Consult a doctor.
If the casualty is not breathing: Perform mouth-to-mouth resuscitation, notify emergency physician immediately.
Skin contact:
Wash off affected area immediately with plenty of water.
Continue decontamination with polyethylene glycol 400 after initial rinsing with water and then wash with water and soap.
If symptoms persist, consult a physician for treatment.
Eye contact:
With eye held open, thoroughly rinse immediately with plenty of water for at least 10 minutes.
Consult an ophthalmologist immediately if the symptoms persist.
Ingestion:
Rinse out mouth. Immediately give large quantities of water to drink.
Consult a physician immediately.
Most important symptoms and effects, both acute and delayed:
Indication of any immediate medical attention and special treatment needed:
After accidental absorption in the body, the pathology and clinical findings are dependent on the kinetics of the noxious substance (quantity of absorbed substance, the absorption time, and the effectiveness of early elimination measures (first aid)/ excretion - metabolism).
Continue with first aid measures.
Depending on the pathology and clinical findings, patient monitoring and symptomatic treatment are necessary.
Pay attention to self-protection.
Remove victims from hazardous area.
Immediately remove soiled or soaked clothing and remove it to a safe distance.
Keep victim warm, in a stabilized position and covered.
Do not leave victims unattended.
If the casualty is unconscious: Place the victim in the recovery position.
Inhalation:
Potential for exposure by inhalation if dusts or smoke are generated.
Move victims into fresh air.
With labored breathing: Provide with oxygen.
Consult a doctor.
If the casualty is not breathing: Perform mouth-to-mouth resuscitation, notify emergency physician immediately.
Skin contact:
Wash off affected area immediately with plenty of water.
Continue decontamination with polyethylene glycol 400 after initial rinsing with water and then wash with water and soap.
If symptoms persist, consult a physician for treatment.
Eye contact:
With eye held open, thoroughly rinse immediately with plenty of water for at least 10 minutes.
Consult an ophthalmologist immediately if the symptoms persist.
Ingestion:
Rinse out mouth. Immediately give large quantities of water to drink.
Consult a physician immediately.
Most important symptoms and effects, both acute and delayed:
Indication of any immediate medical attention and special treatment needed:
After accidental absorption in the body, the pathology and clinical findings are dependent on the kinetics of the noxious substance (quantity of absorbed substance, the absorption time, and the effectiveness of early elimination measures (first aid)/ excretion - metabolism).
Continue with first aid measures.
Depending on the pathology and clinical findings, patient monitoring and symptomatic treatment are necessary.
Fire-fighting measures
Suitable extinguishing media:
All extinguishing substances suitable.
Water, quenching powder, foam, carbon dioxide (CO2).
Unsuitable extinguishing media:
Do not use a solid water stream as it may scatter and spread fire.
Special hazards arising from the substance or mixture:
None known.
Special protective equipment for fire-fighters:
In the event of fire, wear self-contained breathing apparatus.
Full protective suit.
Advice for firefighters:
Contaminated extinguishing water must be treated at a suitable disposal plant in accordance with waste management laws.
Water used to extinguish fire should not enter drainage systems, soil or stretches of water.
Ensure there are sufficient retaining facilities for water used to extinguish fire.
In case of fire, remove the endangered containers and bring to a safe place, if this can be done safely.
Contaminated fire-extinguishing water must be disposed of in accordance with the regulations issued by the appropriate local authorities.
Fire residues should be disposed of in accordance with the regulations.
Keep out unprotected persons.
All extinguishing substances suitable.
Water, quenching powder, foam, carbon dioxide (CO2).
Unsuitable extinguishing media:
Do not use a solid water stream as it may scatter and spread fire.
Special hazards arising from the substance or mixture:
None known.
Special protective equipment for fire-fighters:
In the event of fire, wear self-contained breathing apparatus.
Full protective suit.
Advice for firefighters:
Contaminated extinguishing water must be treated at a suitable disposal plant in accordance with waste management laws.
Water used to extinguish fire should not enter drainage systems, soil or stretches of water.
Ensure there are sufficient retaining facilities for water used to extinguish fire.
In case of fire, remove the endangered containers and bring to a safe place, if this can be done safely.
Contaminated fire-extinguishing water must be disposed of in accordance with the regulations issued by the appropriate local authorities.
Fire residues should be disposed of in accordance with the regulations.
Keep out unprotected persons.
Accidental release measures
Personal precautions, protective equipment and emergency procedures:
Wear personal protective equipment.
Handle in accordance with good industrial hygiene and safety practices.
Keep unauthorized persons away.
Environmental precautions:
Observe regulations on prevention of water pollution (collect, dam up, cover up).
Do not allow substance to enter soil, bodies of water or sewage canals.
If the product contaminates rivers and lakes or drains inform respective authorities.
Methods and material for containment and cleaning up:
Pick up mechanically and collect in a suitable container.
Avoid formation of dust.
To absorb spilled substance an approved industrial vacuum cleaner is recommended.
If necessary, the spilled substance should be moistened.
Rinse away any residue with plenty of water.
Waste to be packed like clean product and to be marked.
Identification label on packages not to be removed until recycling.
Dispose of absorbed material in accordance with the regulations.
Additional advice:
Isolate and seal off defective containers immediately.
Observe regulations on prevention of water pollution (collect, dam up, cover up).
Wear personal protective equipment.
Handle in accordance with good industrial hygiene and safety practices.
Keep unauthorized persons away.
Environmental precautions:
Observe regulations on prevention of water pollution (collect, dam up, cover up).
Do not allow substance to enter soil, bodies of water or sewage canals.
If the product contaminates rivers and lakes or drains inform respective authorities.
Methods and material for containment and cleaning up:
Pick up mechanically and collect in a suitable container.
Avoid formation of dust.
To absorb spilled substance an approved industrial vacuum cleaner is recommended.
If necessary, the spilled substance should be moistened.
Rinse away any residue with plenty of water.
Waste to be packed like clean product and to be marked.
Identification label on packages not to be removed until recycling.
Dispose of absorbed material in accordance with the regulations.
Additional advice:
Isolate and seal off defective containers immediately.
Observe regulations on prevention of water pollution (collect, dam up, cover up).
Handling and storage
Handling:
Precautions for safe handling:
Avoid contact with skin and eyes.
Avoid dust formation.
For personal protection.
Avoid residues of the product on the containers.
Handle in accordance with good industrial hygiene and safety practices.
Remove contaminated or saturated clothing.
No eating, drinking, smoking, or snuffing tobacco at work.
Wash face and/or hands before break and end of work.
Advice on protection against fire and explosion:
Take precautionary measures against static discharges.
Keep away from sources of ignition - No smoking.
Dust explosion class:
Not investigated.
Storage:
Conditions for safe storage, including any incompatibilities: Store in the original receptacle, keeping this tightly sealed, under cool and dry conditions, clean, dry, lockable.
Avoid sun rays, heat effect.
Always close container tightly after removal of product.
Avoid residues of the product on the containers.
Secure container from falling down.
Further information:
Protect from sunlight, warmth and heat.
In order to ensure due transportation, make certain that stacks are of the correct height, containers are securely fastened so as not to fall off, and labelled according to the regulations.
Advice on common storage:
No special precautions required.
German storage class:
Combustible / non-combustible liquids and solids not assigned to other storage classes.
Precautions for safe handling:
Avoid contact with skin and eyes.
Avoid dust formation.
For personal protection.
Avoid residues of the product on the containers.
Handle in accordance with good industrial hygiene and safety practices.
Remove contaminated or saturated clothing.
No eating, drinking, smoking, or snuffing tobacco at work.
Wash face and/or hands before break and end of work.
Advice on protection against fire and explosion:
Take precautionary measures against static discharges.
Keep away from sources of ignition - No smoking.
Dust explosion class:
Not investigated.
Storage:
Conditions for safe storage, including any incompatibilities: Store in the original receptacle, keeping this tightly sealed, under cool and dry conditions, clean, dry, lockable.
Avoid sun rays, heat effect.
Always close container tightly after removal of product.
Avoid residues of the product on the containers.
Secure container from falling down.
Further information:
Protect from sunlight, warmth and heat.
In order to ensure due transportation, make certain that stacks are of the correct height, containers are securely fastened so as not to fall off, and labelled according to the regulations.
Advice on common storage:
No special precautions required.
German storage class:
Combustible / non-combustible liquids and solids not assigned to other storage classes.
Transport information
Land transport (UN RTDG/ADR/RID)
Shippingopen allclose all
Special provisions / remarks
- Special provisions:
- Close container tightly before transport and secure from falling down.
Avoid residues of the product on the containers. - Remarks:
- Not dangerous according to transport regulations.
Inland waterway transport (UN RTDG/ADN(R))
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Close container tightly before transport and secure from falling down.
Avoid residues of the product on the containers.
Not dangerous according to transport regulations.
Marine transport (UN RTDG/IMDG)
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Close container tightly before transport and secure from falling down.
Avoid residues of the product on the containers.
Not dangerous according to transport regulations.
Air transport (UN RTDG/ICAO/IATA)
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Close container tightly before transport and secure from falling down.
Avoid residues of the product on the containers.
Not dangerous according to transport regulations.
Additional transport information
Additional information
- Special provisions / remarks / other:
- Combination traffic :
Labelling of containers / shipping units following main product run as per sea or air transport regulations.
Exposure controls / personal protection
Control parameters:
Remarks: No substance-specific limiting value being known.
Engineering measures:
Ensure suitable suction/aeration at the work place and with operational machinery.
Avoid dust formation.
Provide for installation of emergency shower and eye bath.
Personal protective equipment:
Respiratory protection:
Wear dust mask in the presence of dust.
When handling for a short time: Dust mask with P2 particle filter in the event of prolonged exposure during handling: wear a self contained respiratory apparatus.
Note time limit for wearing respiratory protective equipment.
Hand protection:
Applies to handling for brief periods or of small amounts:
Glove material: Polychloroprene (PCP), for example: Camapren 720, Kächele-Cama Latex GmbH (KCL), Germany.
Material thickness: 0.65 mm
Break through time: > 480 min
Method: DIN EN 374
Applies to handling for longer periods or of large amounts:
Glove material: Polychloroprene (PCP), for example: Tricopren 723, Kächele-Cama Latex GmbH (KCL), Germany.
Material thickness: 1.3 mm
Break through time: > 480 min
Method: DIN EN 374
Eye protection:
Safety glasses with side-shields conforming to EN166 or when handling larger quantities: basket-shaped glasses.
Skin and body protection:
Wear suitable protective clothing.
Hygiene measures:
Avoid contact with skin and eyes.
Avoid dust formation.
No eating, drinking, smoking, or snuffing tobacco at work.
Wash face and/or hands before break and end of work.
Avoid contaminating clothes with product.
Remove contaminated or saturated clothing.
Preventive skin protection recommended.
Protective measures:
Handle in accordance with good industrial hygiene and safety practices.
Wear suitable protective clothing, gloves and eye/face protection.
The personal protective equipment used must meet the requirements of directive 89/686/EEC and amendments (CE certification).
It should be defined in the work place in the form of a risk analysis according to directive 89/686/EEC and amendments.
The work-place related airborne concentrations have to be kept below of the indicated exposure limits.
If workplace exposure limits are exceeded and/or larger amounts are released (leakage, spilling, dust) the indicated respiratory protection should be used.
Remarks: No substance-specific limiting value being known.
Engineering measures:
Ensure suitable suction/aeration at the work place and with operational machinery.
Avoid dust formation.
Provide for installation of emergency shower and eye bath.
Personal protective equipment:
Respiratory protection:
Wear dust mask in the presence of dust.
When handling for a short time: Dust mask with P2 particle filter in the event of prolonged exposure during handling: wear a self contained respiratory apparatus.
Note time limit for wearing respiratory protective equipment.
Hand protection:
Applies to handling for brief periods or of small amounts:
Glove material: Polychloroprene (PCP), for example: Camapren 720, Kächele-Cama Latex GmbH (KCL), Germany.
Material thickness: 0.65 mm
Break through time: > 480 min
Method: DIN EN 374
Applies to handling for longer periods or of large amounts:
Glove material: Polychloroprene (PCP), for example: Tricopren 723, Kächele-Cama Latex GmbH (KCL), Germany.
Material thickness: 1.3 mm
Break through time: > 480 min
Method: DIN EN 374
Eye protection:
Safety glasses with side-shields conforming to EN166 or when handling larger quantities: basket-shaped glasses.
Skin and body protection:
Wear suitable protective clothing.
Hygiene measures:
Avoid contact with skin and eyes.
Avoid dust formation.
No eating, drinking, smoking, or snuffing tobacco at work.
Wash face and/or hands before break and end of work.
Avoid contaminating clothes with product.
Remove contaminated or saturated clothing.
Preventive skin protection recommended.
Protective measures:
Handle in accordance with good industrial hygiene and safety practices.
Wear suitable protective clothing, gloves and eye/face protection.
The personal protective equipment used must meet the requirements of directive 89/686/EEC and amendments (CE certification).
It should be defined in the work place in the form of a risk analysis according to directive 89/686/EEC and amendments.
The work-place related airborne concentrations have to be kept below of the indicated exposure limits.
If workplace exposure limits are exceeded and/or larger amounts are released (leakage, spilling, dust) the indicated respiratory protection should be used.
Stability and reactivity
Stability:
Product is stable.
Conditions to avoid:
Sun rays, heat, heat effect, humidity.
Incompatible materials:
None known.
Hazardous decomposition products:
None known.
Product is stable.
Conditions to avoid:
Sun rays, heat, heat effect, humidity.
Incompatible materials:
None known.
Hazardous decomposition products:
None known.
Disposal considerations
Product:
Waste to be packed like clean product and to be labelled.
Identification label on packages not to be removed until recycling.
Disposal according to local authority regulations.
Recommendation:
Offer surplus and non-recyclable solutions to a licensed disposal company.
Must be subjected to special treatment in accordance with the regulations issued by the appropriate local authorities, e. g. suitable incineration plant.
If necessary contact the relevant authorities.
Uncleaned packaging:
Do not reuse empty containers and dispose of in accordance with the regulations issued by the appropriate local authorities.
Dispose of containers that have not been emptied completely and/or cleaned like of substance.
Waste Key Number:
The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.
Waste to be packed like clean product and to be labelled.
Identification label on packages not to be removed until recycling.
Disposal according to local authority regulations.
Recommendation:
Offer surplus and non-recyclable solutions to a licensed disposal company.
Must be subjected to special treatment in accordance with the regulations issued by the appropriate local authorities, e. g. suitable incineration plant.
If necessary contact the relevant authorities.
Uncleaned packaging:
Do not reuse empty containers and dispose of in accordance with the regulations issued by the appropriate local authorities.
Dispose of containers that have not been emptied completely and/or cleaned like of substance.
Waste Key Number:
The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
