Registration Dossier

Administrative data

First-aid measures

Emergency measure - Inhalation: Move exposed person to fresh air; in case of indisposition
seek medical advice.
Emergency measure - Eyes: Rinse with plenty of water; if irritation occurs, seek
medical advice.
Emergency measure - Skin: Wash with soap and water.
Emergency measure - Ingestion: Symptomatic treatment; in case of indisposition seek medical
advice.

Fire-fighting measures

Recommended extinguishing agent: Water, dry powder, foam.

Product arising from burning: Combustion products may contain carbon, nitrogen and sulfur
oxides as well as sodium.

Product determined by test: N

Protective equipment: Wear self contained breathing apparatus.

Accidental release measures

Emergency measures in case of spillage: Wear protective clothing (dust mask, safety goggles and
impermeable gloves).

Solids: sweep up (wet powders with water) and place in
suitable containers for disposal.

Liquids: absorb using an adequate absorbent (such as
kieselgur, sand, saw dust) collect and place in suitable
containers for disposal.

Dispose of waste material in authorized incineration
facilities.

The containers label in accordance with Technical Rule 201.

Handling and storage

Handling: Observe the usual precautions for handling chemicals. If the
pure substance is handled as powder,

all working methods must always be designed so that exposure
by inhalation of the substance and by skin contact are
minimized and eye contact is excluded. Closed or at least
dustproof equipment should be used during filling, transfer
and metered feeding as well as during sampling. In the case
of handling in open systems, any dust that can form must be
extracted directly at the point of origin. If technical
extraction or ventilation measures are not possible or are
insufficient, respiratory protection (e.g. dust mask with
particle filter) should be worn. To avoid skin contact,
tested protective gloves (e.g. nitrile rubber or PVC) and
suitable protective clothing (e.g. normal working clothes)
should be worn. Safe eye protection (e.g. safety glasses
with side prtection shield) is absolutely essential.
Adequate washing facilities should be available in the
immediate vicinity of the work area and eye douches should
be made available and their location indicated
conspicuously. After skin contact, the affected

parts of the skin shoud be cleaned thoroughly using (water
and soap). Special skin-protection and skin-care measures
are recommended. A skin-protection plan should be drawn up.
If dust can develop, due to the potential dust explosion
risk, potential ignition sources should be removed from

the work area. Static discharges must be avoided,

e.g. thorough the earthing of containers, apparatus and
pumps.

Do not eat, drink or smoke in the working area.

Storage: The substance should be stored in well sealed and secure
containers in adequate rooms at room temperature. Avoid
residue outside the containers.

Packaging of the substance and or preparation: 25 kg Faltkarton mit PE-Inlinern.

Transport information

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Marine transport (IMDG)

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Air transport ICAO/IATA

Remarks
Transport: Transport in well sealed suitable containers. The containers
should be secured against falling down. Label containers in
accordance with pertinent regulations.
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Exposure controls / personal protection

Stability and reactivity

Danger other than fire: Not known.

Chemical reaction with water: No dangerous reaction with water.

Dust explosion: Not to be expected if handled under good industrial hygiene
practices.

Dust explosion determined by test: N

Disposal considerations

Industry - Possibility of recovery/recycling: Normal application results in the consumption of ca. 99 %

by irreversible binding to polyamide fibers; recovery or
recycling of the remaining test substance is not possible.

Industry - Possibility of neutralisation: No suitable method known.

Industry - Possibility of destruction: controlled discharge: Not suitable for deposit in landfill site.

Industry - Possibility of destruction - incineration: Incineration with flue gas scrubbing.

Industry - Possibility of destruction - water purification: Removal by controlled discharge to a waste water treatment
plant. It is estimated that approx. 1 % of the total
quantity used is discharged into internal industrial
effluents as highly diluted solution. A purification of

the waste water in a waste water treatment plant is
recommended. The dyestuff should be used in a well equiped
dyehouse.

If necessary the waste water can be purified prior to the
waste water treatment by membrane filtration or by
floculation with cationic agents or by treatment with ozone.
The most effective method is the membrane filtration: more
than 99 % of the remaining dyestuff can be removed from the
waste water.

Industry - Possibility of destruction - other: None.

Public at large - Possibility of recovery/recycling: Not applicable.