Registration Dossier

Administrative data

First-aid measures

Emergency measure - Inhalation: See SDS

Symptoms and effects Irritating to eyes and skin.

Inhalation Move to fresh air, rest, half upright position,
loosen clothing. Oxygen or artificial respiration if there
is difficulty in breathing. Seek medical advice after
significant exposure.
Emergency measure - Eyes: Symptoms and effects Irritating to eyes and skin.

Eye Rinse immediately and as long as possible with plenty of
water. Eyelids should be held away from the eyeball to
ensure thorough rinsing. Seek medical advice if irritation
persists.
Emergency measure - Skin: See SDS

Symptoms and effects Irritating to eyes and skin.

Skin Remove all contaminated clothing immediately. Wash off
with plenty of soap and water. Seek medical advice if
irritation develops. Launder clothes before reuse.
Emergency measure - Ingestion: See SDS

Symptoms and effects Irritating to eyes and skin.

Ingestion DO NOT induce vomiting because of risk of
aspiration. Seek medical advice.

Advice to physician Symptomatic treatment is advised.

Fire-fighting measures

Recommended extinguishing agent: See SDS

Extinguishing media Carbon dioxide, dry chemical powder,
water, foam.

Unsuitable extinguishing media halones.

Special exposure hazards Decomposition under effect of
heating. If involved in a fire, it will support combustion.
In case of fire and/or explosion do not breathe fumes.

Product arising from burning: normal hydrocarbon combustion products, strongly dependent
on conditions

Hazardous decomposition/

combustion products

Acetone, Propane, Isopropanol, Acetic acid, 3-Methyl-2-
butanon, Isopropyl acetate, Mixture of aliphatic and
aromatic hydrocarbon solvents and other, normal
decomposition and oxidation products of hydrocarbons

Product determined by test: N

Protective equipment: See SDS

Protective equipment Wear suitable protective clothing. Wear
self contained breathing apparatus.

Accidental release measures

Emergency measures in case of spillage: See SDS

Personal precautions Do not breathe fumes/vapour. Avoid
contact with skin and eyes.

Environmental precautions Do not allow to enter drains or
water courses.

Methods for cleaning up Collect as much as possible in a
clean container for (preferable) reuse or disposal. Cover
the remainder with inert absorbent (e.g. vermiculite) for
disposal. The waste should NOT be confined.

Handling and storage

Handling: See SDS, ch

Handling Do not eat, drink or smoke in application area.
Never weigh out in the storage room. Do not breathe
fumes/vapour. Do not pipet by mouth. Handle in well
ventilated areas. Avoid contact with skin and eyes.
Confinement must be avoided. Never bring peroxide into
direct contact with accelerator during processing. Weigh
ut
and add peroxide and accelerator separately.

Fire and explosion prevention: Use explosion protected
equipment. Avoid shock and friction. Take precautionary

measures against static discharges. Keep away from sources
of ignition - No smoking.

Other information Wash thoroughly after handling. Keep
working clothing separately and do not take them

home.

Storage: See SDS

Storage requirements Store in accordance with
ocal/national
regulations. Keep away from food, drink and animal
feedingstuffs. Keep container tightly closed in a cool
place. Store in a dry, well ventilated place away from
sources of heat and direct sunlight. Keep container upright
to prevent leakage. Keep away from reducing agents (e.g.
amines), acids, alkalies and heavy metal compounds (e.g.
accelerators, driers, metal soaps) Do not mix with

peroxide accelerators. Do not mix with reducing agents.
Avoid temperatures above 10 CC.

Packaging of the substance and or preparation: 35 KG PE or PP containers

Transport information

Shippingopen allclose all
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all

Marine transport (IMDG)

Remarksopen allclose all

Air transport ICAO/IATA

Remarks
Transport code: See above
Transport: See SDS, ch 14:

Land transport (ADR/ RID)

ADR class 5.2 ADR item number 3b

RID class 5.2 RID item number 3b

Hazard Identification No. 539 Substance Identification No.

TREM-Card CEFIC TEC(R)- 52G01B UN number 3103

Proper Shipping Name Organic peroxide type c, liquid,
sample; ( methyl isopropyl ketone peroxide )

Other information Every shipment should be accompanied with
a copy of the notification.

Sea transport (IMDG-code/ IMO)

IMO/IMDG code Class 5.2

Packing group II UN number 3103

EMS 5.2-01 MFAG

Marine pollutant no

Proper Shipping Name Organic peroxide type c, liquid,
sample; ( methyl isopropyl ketone peroxide )

Other information Every shipment should be accompanied with
a copy of the notification.

Air transport (ICAO-TI/ IATA-DGR)

ICAO-TI/IATA-DGR UN number 3103

Class 5.2 Packing group II
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Stability and reactivity

Danger other than fire: if stored at temperatures above 10 deg C, substance may
spontaneously decompose and cause fire or explosion

Chemical reaction with water: Dangerous reactions with water are not expected. See Notox
statement on the flammability (contact with water) of

Trigonox R-946

Dust explosion: Not applicable

Disposal considerations

Industry - Possibility of recovery/recycling: Trigonox R-938 cannot be recycled or recovered after use

Industry - Possibility of neutralisation: Should not be attempted because of the potential for
dangerous reactions

Industry - Possibility of destruction: controlled discharge: Controlled discharge if allowed by local authorities but not
recommended.

Industry - Possibility of destruction - incineration: Controlled incineration in incinerator for industrial waste.
No special treatment of wast gases required.

Industry - Possibility of destruction - water purification: no method known

Public at large - Possibility of recovery/recycling: Not applicable.Substance will not be made available to the
public at large

Public at large - Possibility of neutralisation: Not applicable.Substance will not be made available to the
public at large

Public at large - Possibility of destruction: controlled discharge: Not applicable.Substance will not be made available to the
public at large

Public at large - Possibility of destruction - incineration: Not applicable.Substance will not be made available to the
public at large

Public at large - Possibility of destruction - water purification: Not applicable.Substance will not be made available to the
public at large

Public at large - Possibility of destruction - others: Not applicable.Substance will not be made available to the
public at large