Registration Dossier

Administrative data

First-aid measures

Emergency measure - Inhalation: Keep the patient calm. Protect against loss of body heat.
Seek medical advice and clearly identify substance.


Advice for the physician: Treat as early as possible using
cortisone spray.
Emergency measure - Eyes: Rinse immediately with plenty of water for 10 - 15 minutes.
Keep eyelids open to rinse the whole eye surface and eyelids
with water. Seek medical advice and clearly identify
substance.
Emergency measure - Skin: Remove contaminated or soaked clothing. Wash off with plenty
of water and soap immediately for 10 - 15 minutes. In se-
rious cases, use emergency shower immediately. Seek medical
advice and clearly identify substance.
Emergency measure - Ingestion: If consciuos, give several small portions of water to drink.
Do not induce vomiting. Seek medical advice and clearly
identify the substance.

Fire-fighting measures

Recommended extinguishing agent: Water spray, extinguishing powder, foam, carbon dioxide.
However, water jets should not be used for safety reasons.

Product arising from burning: The substance could burn if exposed to high temperatures
releasing hazardous conbustion products such as carbon
oxides (carbon monoxide and carbon dioxide), hydrogen
chloride and chlorine containing compounds.

Product determined by test: N

Protective equipment: Full protective clothing and self-contained breathing
apparatus must be worn.


Fight the fire from a safe distance or protected location.
Use respiratory protection independent of recirculated air.

Accidental release measures

Emergency measures in case of spillage: Keep un protected persons away. Wear personal protective
equipment and avoid contact with eyes and skin.


Prevent material from entering sewers or surface waters.
Contain any fluid that runs out using suitable material
(e.g. earth). Dispose of in prescribed marked containers.
Observe local/state/federal regulations.


Methods of cleaning up: Do not flush away with water. Absorb
with liquid binding material such as diatomaceuos earth and
dispose of according to lacal/state/federal regulations.

For small amounts: Cover with calcium oxide. Contain larger
amounts and pump up into suitable containers.


Eliminate all sources of ignition.

Handling and storage

Handling: All working methods must always be designed so that skin and
eye contact with the substance are excluded. Inhalation of
the substance must be avoided. Closed equipment should be
used during filling and metered feeding as well as during
sampling. In the case of handling in open systems, any
vapours/aerosols that can form should be extracted directly
at the point of origin. The extracted air should only be
returned to the work area after adequate cleaning using
tested equipment.

Respiratory protection (e.g. a full-face mask with ABEK/ST
filter or a self-contained respirator if long-term or strong
exposure) should be worn in case technical extraction or
ventilation measures are not possible or are insufficient.
Even if skin contact is only possible for short periods,
tested protective gloves (e.g. PVC) and suitable protective
clothing (e.g. full protective clothing) must be worn. Safe
eye protection (e.g. tightly closing safety goggles) is
absolutely essential. Adequate washing facilities should be
available in the immediate vicinity of the work area and eye
douches should be made available and their location indica-
ted conspicuously. After skin contact, the affected parts of
the skin should be cleaned thoroughly using (:::). Contami-
nated clothing must be changed immediately. Special skin-
protection and skin-care measures are recommended. A skin-
protection plan must be drawn up. Ensure adequate ventila-
tion. Must be syphoned off in situ. Keep away from incompa-
tible substances, for example basic substances.


Cool endangered containers with water. Vapours may form in
closed rooms with air mixtures, leading to explosion in the
presence of sources of ignition, even in empty, uncleaned
vessels. Keep away from open flames, heat and sparks. Take
precautionary measures against electrostatic charging.

Storage: Do not store in containers made of aluminum or other light
metals. Do not store in containers coated with zinc.

For the storage the original packaging drums or other
unbreakable and correctly labelled containers are to be
used. Keep containers tightly closed and secure by suitable
measures against falling down. Avoid product residues on the
packing drums.


Keep in the original container in a cool well ventilated
place. Keep container dry and tightly closed.

Packaging of the substance and or preparation: Steel drum with PE inliner, 205 l;

steel jerry with PE inliner, 30 l.

Transport information

Shippingopen allclose all
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all

Marine transport (IMDG)

Remarksopen allclose all

Air transport ICAO/IATA

Remarks
Transport code: UN-Nr. 3334
Transport: Transport only in original containers labelled according to
the regulations. Prevent containers from falling.
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Stability and reactivity

Danger other than fire: None known.

Chemical reaction with water: None which is hazardous.

Dust explosion: Not applicable as the substance is a liquid.

Dust explosion determined by test: N

Disposal considerations

Industry - Possibility of recovery/recycling: Discharge to the environment will be minimal. Recovery from
minor spillages or accidental discharge is not economically
or technically feasible, and such waste material will be
disposed of by incineration. In principle, it may be
possible to recover larger spillages of uncontaminated
material for subsequent use.

Industry - Possibility of neutralisation: The notification tests have shown that the substance is
harmful by acute oral exposure, corrosive, and a skin
sensitiser.


No chemical treatment is practicable to neutralise the
hazardous health properties.


The is no dust hazard as the notified chemical is a liquid.


With regards to the enviornment, the substance is very

toxic to aquatic organisms and may cause long-term ad-
verse effects in the aquatic environment.


No chemical treatment is practicable to neutralise the
hazardous environmental properties.

Industry - Possibility of destruction: controlled discharge: None recommended.

Industry - Possibility of destruction - incineration: The substance can be disposed of by incineration by burning
under controlled conditions at a licensed waste treatment
processor in accordance with local regulations. Stack gases
should be scrubbed, because noxious fumes containing carbon
oxides and chlorine containing compounds could be formed.

Industry - Possibility of destruction - water purification: The substance should not normally be discharged directly
tothe sewage system or the aqueous environment. However,
adverse effects on sewage treatment systems would be
unlikely.

Industry - Possibility of destruction - other: None.

Public at large - Possibility of recovery/recycling: Not applicable as the substance is not made available to the
public.