Registration Dossier

Administrative data

First-aid measures

General information: Remove contaminated clothing immediately and dispose of safely.
Inhalation: Take the victim out of the contaminated area. Move to fresh air. Make the victim blow his nose. Seek medical advice.
Skin contact: Rinse immediately with plenty of water for at least 15 minutes. Seek medical advice.
Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Seek medical advice.
Ingestion: Do not induce vomiting. Make the victim rinse his mouth with water. Seek medical advice immediately

Fire-fighting measures

Suitable extinguishing media: All means (e.g. water, carbon dioxide, dry chemical extinguisher).
Extinguishing media that must not be used for safety reasons: Strong water jet.
Specific hazards: In case of fire, the product may emit toxic and/or irritating fumes. Supposed thermal decomposition/oxidation: Carbon monoxide and carbon dioxide, Nitrogen oxides (NOx), Hydrogen chloride (HCl)
Protection during intervention: Use self-contained breathing apparatus. Wear full protective suit.
Further information: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Avoid rejection of extinguishing water in the environment.

Accidental release measures

Personal precautions: Particle filter half mask, filter P3. Safety glasses. Suitable gloves. Work clothes.
Environmental precautions: Avoid any spreading of product.
Methods for cleaning
up/taking up: Sweep and shovel the solid product in a container adapted for its recovery or destroying (avoiding dust formation). Close and label
rigorously.
Cleaning of contaminated zone : After taking up the product, rinse the polluted area with water.
Elimination of recovered materials: Deliver to Environmental service of the factory or to any specialized and approved disposal service.
Further information: Intervention of special services recommended.

Handling and storage

The intermediate substance is directly loaded from the container to the reactor using an ventilation system.
The intermediate is completely transformed in another product and no residue is released.
Sampling, analysis, storage, loading and unloading of equipment, cleaning and waste disposal are managed under exhaust ventilation to prevent any significant release of the substance.
During these process workers follow the internal procedure and wear appropriate PPE.
Only trained and authorised personnel handle the substance. The workers are provided with training and with a "safety sheet" for each substance they use; this sheet contains the procedures during the normal handling and during the malfunctioning of the process and in accidental situations with the actions to be taken in order to safeguard themselves and other workers at the workplace.
Access to all safety data sheet is provided for all workers.
Advice on safe handling (workshop): Local ventilation and emission point extraction. Take precautionary measures against electrostatic loading.
Render equipment and apparatus inert (nitrogen, inert gases).
Requirements for storage rooms and vessels: Keep only in the original container
Further information on storage conditions: Keep container tightly closed and dry. Protect from light. Keep away from heat.

Transport information

Land transport (ADR/RID)

UN number:
3077
Shippingopen allclose all
Class:
9
Classification code:
M7
Packaging group:
III
Labels:
9
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
3077
Shippingopen allclose all
Class:
9
Classification code:
M7
Packaging group:
III
Labels:
9
Remarksopen allclose all

Marine transport (IMDG)

UN number:
9
Proper shipping name and description:
Environmentally hazardous substance, solid, n.o.s. (Benzyl transcycloprolinate hydrochloride)
Chemical name:
Benzyl transcycloprolinate hydrochloride
Class:
9
Packaging group:
III
EmS code:
F-A, S-F
Labels:
9
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
9
Proper shipping name and description:
Environmentally hazardous substance, solid, n.o.s. (Benzyl transcycloprolinate hydrochloride)
Chemical name:
Benzyl transcycloprolinate hydrochloride
Class:
9
Packaging group:
III
Labels:
9
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Protective equipment and measures (IMPORTANT: to be adapted following the workplace risk assessment.)
General protective measures: Specific dermal hazard: avoid any contact with skin.
Laboratory
Respiratory protection: Handling in a hood.
Hand protection: Suitable gloves.Nitrile rubber gloves.
Eye protection: Safety glasses.
Body protection: Working clothes.
Hygiene measures: Wash hands.
Workshop
Respiratory protection: Particle filter half mask recommended.
Hand protection: Suitable gloves. Nitrile rubber gloves.
Eye protection: Safety glasses.
Body protection: Work clothes.
Hygiene measures: Wash hands.

Stability and reactivity

Stability: Unstable in water at pH > 4.
Substances to avoid: Strong oxidizing agents.
Hazardous decomposition products: Supposed thermal decomposition/oxidation: Carbon monoxide and carbon dioxide, Nitrogen oxides (NOx), Hydrogen chloride (HCl)

Disposal considerations

Product residue: Deliver to the Environmental service of the factory or to any specialized and approved disposal service.
Uncleaned packaging: Deliver to the Environmental service of the factory or to any specialized and approved disposal service.