Registration Dossier

Administrative data

First-aid measures

Emergency measure - Inhalation: Administration of oxygen or fresh air. Seek medical
attention. Medical supervision at least 48 hours.
Emergency measure - Eyes: Flush with copious amounts of water under open eyelid for
several minutes. Protect unaffected eye. Seek medical
attention. Medical supervision at least 48 hours.
Emergency measure - Skin: Take off contaminated clothing immediately. Wash affected
areas with copious amounts of water. Seek medical attention.
Medical supervision at least 48 hours.
Emergency measure - Ingestion: Rinse mouth with water. Afterwards drink plenty amounts of
water. Seek medical attention. Medical supervision for at
least 48 hours.

Fire-fighting measures

Recommended extinguishing agent: Adjust extinguishing operations according to the
environment.

Dry powder, foam and carbon dioxide

Product arising from burning: Residues of combustion and contaminated water for fire
protection have to be disposed according to competent
authority regulations.


Phosphorous oxides, hydrogen chloride gas, carbon oxides

Product determined by test: N

Protective equipment: Circulating air independent respirator.

Avoid inhaling of evolving explosion and fire gases.

Accidental release measures

Emergency measures in case of spillage: Wear personnel protective clothing. Avoid dust formation.
Keep unprotected persons away. Remove all ignition sources.


Take up mechanically. Use appropriate vacuum cleaner for
absorption.


Do not drain into surface water of canalisation.

Handling and storage

Handling: Handle only in rooms with plain, seamless floors . Avoid
exposition - gather instructions before use. Protect against
air moisture and water.


All working methods must always be designed so that skin and
eye contact with the substance are excluded. Inhalation of
the substance must be avoided. Closed equipment should be
used during filling and metered feeding as well as during
sampling. In the case of handling in open systems, if
applicable, any dust or vapours (HCl) that can form should
be extracted directly at the point of origin. The extracted
air should only be returned to the work area after adequate
cleaning using tested equipment. If technical extraction or
ventilation measures are not possible or are insufficient,
respiratory protection (see below) should be worn. Even if
skin contact is only possible for short periods, tested
protective gloves (see below) and suitable protective
clothing (e.g. :::) must be worn. Safe eye protection (see
below) is absolutely essential. Adequate washing facilities
should be available in the immediate vicinity of the work
area and eye douches should be made available and their
location indicated conspicuously. Adequate washing
facilities should be available in the immediate vicinity of
the work area and eye douches should be made available and
their location indicated conspicuously. After contact with
the skin, as far as possible, the affected parts of the skin
should be wiped completely dry and then cleaned thoroughly
with :::. Contaminated clothing must be changed immediately.
Special skin-protection and skin-care measures are
recommended. A skin-protection plan must be drawn up.
Outdoor clothing should be kept separate from working
clothes.


Personal protective equipment:

- full protective-mask (EN 136) with ABEK-P3 filter P2 (EN
141)

- protective gloves category III (EN 374), e.g. PVA,
synthetic material, synthetic or natural rubber

- tightly fitting goggles (with lateral protection), not
necessary if full protection mask is used).


Industrial hygiene:

Protect against heat and keep away from ignition sources.
Wash hands before breaks and at work finishing time.

Storage: Keep containers tightly closed and store dry.

Static discharges must be avoided. Protect container from
heat and direct insolation. Open handling without suitable
personel protective equipment must be avoided. Avoid
formation of dust. Keep away from nourishments, beverage and
animal food.

Protect against air moisture and water.

Storage Class: flammable, toxic solid

Packaging of the substance and or preparation: Drums with polyethylene bags

Content: 20 kg

Transport information

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Marine transport (IMDG)

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Air transport ICAO/IATA

Remarks
Transport code: UN-No. 2928
Transport: For the internal transportation:

Use original containers or other unbreakable and correctly
labelled containers. Keep containers tightly closed and
secure by suitable measures against falling down.


UN-No. 2928

Class: 6.1

Classification code: TC2

Packaging group: II

Hazard classification: 68

Limited Amount: LQ18

Hazard note: 6.1, 8

Name of Good: Toxic solid, corrosive, organic,

n.o.s. (Dichlortriphenylphosphorane)
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Stability and reactivity

Danger other than fire: Dangerous degradation products:

Hydrochloric Acid, Triphenylphosphine oxide


Protect against strong oxidising agents.


Classified in WGK 3 - severely hazardous to water.

Chemical reaction with water: Protect against air moisture and water.

Dust explosion: Classified as BZ 2:

capable of dust explosion (strong to most intensive dust
explosion violence)

Dust explosion determined by test: Y

Disposal considerations

Industry - Possibility of recovery/recycling: Mechanical recovery of the substance and disposal in
appropriate containers.

Industry - Possibility of neutralisation: None known

Industry - Possibility of destruction: controlled discharge: Not known

Industry - Possibility of destruction - incineration: Code: 661

Incinerator with flue gas scrubbing

Industry - Possibility of destruction - water purification: Not known

Industry - Possibility of destruction - other: None

Public at large - Possibility of recovery/recycling: Not applicable