Registration Dossier

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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

First-aid measures

General advice: consult a physician.


Eye: Immediately and thoroughly flush the eyes with large amounts of water for at least 15 minutes, occasionally lifting the lower and upper eyelids. 

Skin: Do NOT rub the affected areas or flush them with water. In order to prevent further tissue damage, do NOT attempt to remove frozen clothing from frostbitten areas. If frostbite has NOT occurred, immediately and thoroughly wash contaminated skin with soap and water.

Breathing: If a person breathes large amounts of this chemical, move the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the affected person warm and at rest. 

Fire-fighting measures

IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area for at least 100 meters (330 feet) in all directions.

SMALL FIRE: CAUTION: These materials do not burn but will support combustion. Some will react violently with water. Contain fire and let burn. If fire must be fought, water spray or fog is recommended. Water only; no dry chemical, CO2 or Halon®. Do not get water inside containers. If it can be done safely, move undamaged containers away from the area around the fire. Damaged cylinders should be handled only by specialists.

FIRE INVOLVING TANKS: Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Do not direct water at source of leak or safety devices; icing may occur. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. For massive fire, use unmanned master stream devices or monitor nozzles; if this is impossible, withdraw from area and let fire burn. 

 


Do not touch or walk through spilled material.

Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do it without risk.

Use water spray to reduce vapors or divert vapor cloud drift. Never direct water jet on liquid.

Avoid allowing water runoff to contact spilled material. Do not direct water at spill or source of leak. If possible, turn leaking containers so that gas escapes rather than liquid. Prevent entry into waterways, sewers, basements or confined areas. Isolate area until gas has dispersed. Ventilate the area. 

Accidental release measures

Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.


Evacuate danger area. Consult an expert.


Personal protection: complete protective clothing including self-contained breathing apparatus. Provide ventilation. 

Handling and storage

Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use. Provide appropriate exhaust ventilation.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
3083
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Class or division:
Class 2: Gases; Division 2.1
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Marine transport (UN RTDG/IMDG)

UN number:
3083
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Class or division:
Class 2: Gases; Division 2.1
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Air transport (UN RTDG/ICAO/IATA)

UN number:
3083
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Class or division:
Class 2: Gases; Division 2.1
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Exposure controls / personal protection

Skin: FROSTBITE - Compressed gases may create low temperatures when they expand rapidly. Leaks and uses that allow rapid expansion may cause a frostbite hazard. Wear appropriate personal protective clothing to prevent the skin from becoming frozen.

Eyes: FROSTBITE - Wear appropriate eye protection to prevent eye contact with the liquid that could result in burns or tissue damage from frostbite.

Wash skin: No recommendation is made specifying the need for washing the substance from the skin (either immediately or at the end of the work shift).

Remove: No recommendation is made specifying the need for removing clothing that becomes wet or contaminated.

Change: No recommendation is made specifying the need for the worker to change clothing after the workshift.

Provide: FROSTBITE WASH - Quick drench facilities and/or eyewash fountains should be provided within the immediate work area for emergency use where there is any possibility of exposure to liquids that are extremely cold or rapidly evaporating. (NIOSH, 2022)


Personal protective equipments have to satisfy the UNI EN specifications.

Stability and reactivity

PERCHLORYL FLUORIDE is a propellant; a powerful oxidant. It ignites upon contact with alcohols, amines, ammonia, beryllium alkyls, boranes, dicyanogen, hydrazines, hydrocarbons, hydrogen, nitroalkanes, powdered metals, silanes, or thiols.

It may generate hydrofluoric acid if it comes into contact with water.

Disposal considerations

Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.


Dispose following the local regulations.