Registration Dossier
Registration Dossier
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EC number: - | CAS number: -
Guidance on Safe Use
Administrative data
First-aid measures
General advice:
Move out of dangerous area.
Consult a physician.
Show this safety data sheet to the doctor in attendance.
Symptoms of poisoning may appear several hours later.
Do not leave the victim unattended.
Protection of first aiders:
First Aid responders should pay attention to self-protection and use the recommended protective clothing.
Inhalation:
Remove to fresh air immediately. Get medical attention immediately.
Keep patient warm and at rest.
If breathing is irregular or stopped, administer artificial respiration.
Skin contact:
Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.
Take victim immediately to hospital.
Eye contact:
Immediately flush eye(s) with plenty of water.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
Ingestion:
If accidentally swallowed obtain immediate medical attention.
Rinse mouth with water.
Keep respiratory tract clear.
Do NOT induce vomiting.
Never give anything by mouth to an unconscious person.
Fire-fighting measures
Suitable extinguishing media:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Unsuitable extinguishing media:
High volume water jet.
Special protective equipment for firefighters:
In the event of fire, wear self-contained breathing apparatus.
Further information:
In the event of fire and/or explosion do not breathe fumes.
Standard procedure for chemical fires.
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Use a water spray to cool fully closed containers.
Accidental release measures
Personal precautions:
Use personal protective equipment.
Ensure adequate ventilation.
Remove all sources of ignition.
Evacuate personnel to safe areas.
Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas.
Environmental precautions:
Do not flush into surface water or sanitary sewer system.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform respective authorities.
Methods for cleaning up:
Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations.
Handling and storage
Advice on safe handling
Take precautionary measures against static discharges.
Avoid formation of aerosol.
Use personal protective equipment.
Smoking, eating and drinking should be prohibited in the application area.
Provide sufficient air exchange and/or exhaust in work rooms.
Open drum carefully as content may be under pressure.
Dispose of rinse water in accordance with local and national regulations.
Advice on protection against fire and explosion:
Do not spray on a naked flame or any incandescent material. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours). Use only explosion-proof equipment. Keep away from open flames, hot surfaces and sources of ignition.
Hygiene measures:
Avoid contact with skin, eyes and clothing. When using do not eat or drink. When using do not smoke. Wash hands before breaks and immediately after handling the product.
Requirements for storage areas and containers:
No smoking. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards.
Advice on common storage:
No special restrictions on storage with other products.
Further information on storage stability:
No decomposition if stored and applied as directed.
This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substances should be handled at these sites under the Strictly Controlled Conditions as specified in Reach regulation Article 18(4). Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each manufacturing site.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 1992
Shipping information
- Proper shipping name and description:
- FLAMMABLE LIQUID, TOXIC, N.O.S.
- Chemical name:
- TOLUENE, DIPHENYL AMINE
- Class or division:
- Class 3: Flammable liquids
- Packing group:
- Packing group II: Substances presenting medium danger
- Labels:
- 3
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 1992
Shipping information
- Proper shipping name and description:
- FLAMMABLE LIQUID, TOXIC, N.O.S.
- Chemical name:
- TOLUENE, DIPHENYL AMINE
- Class or division:
- Class 3: Flammable liquids
- Packing group:
- Packing group II: Substances presenting medium danger
- Labels:
- 3
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- 1992
Shipping information
- Proper shipping name and description:
- FLAMMABLE LIQUID, TOXIC, N.O.S.
- Chemical name:
- TOLUENE, DIPHENYL AMINE
- Class or division:
- Class 3: Flammable liquids
- Packing group:
- Packing group II: Substances presenting medium danger
- EmS code:
- F-E
- S-D
- Labels:
- 3
- Marine pollutant
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 1992
Shipping information
- Proper shipping name and description:
- FLAMMABLE LIQUID, TOXIC, N.O.S.
- Chemical name:
- TOLUENE, DIPHENYL AMINE
- Class or division:
- Class 3: Flammable liquids
- Packing group:
- Packing group II: Substances presenting medium danger
- Labels:
- 3
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Eye protection:
Eye wash bottle with pure water
Tightly fitting safety goggles
Wear face-shield and protective suit for abnormal processing problems.
Hand protection:
Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact). As the product is a mixture of several substances, the durability of the glove materials cannot be calculated in advance and has to be tested before use. Wear chemicals-resistant gloves, e.g. safety gloves of nitril (thickness 0.4mm) or of butyl rubber (thickness 0.7mm).
Skin and body protection:
Impervious clothing.
Choose body protection according to the amount and concentration of the dangerous substance at the work place.
Respiratory protection :
In the case of dust or aerosol formation use respirator with filter model ABEK.
This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substances should be handled at these sites under the Strictly Controlled Conditions as specified in Reach regulation Article 18(4). Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each manufacturing site.
Stability and reactivity
Reactivity and chemical stability:
No decomposition if stored and applied as directed.
Hazardous reactions:
Stable under recommended storage conditions.
Vapours may form explosive mixture in air.
Conditions to avoid:
Heat, flames and sparks.
Hazardous decomposition products:
No hazardous decomposition products are known.
Disposal considerations
Product:
The product should not be allowed to enter drains, water courses or the soil.
Do not contaminate ponds, waterways or ditches with chemical or used container.
Send to a licensed waste management company.
Contaminated packaging:
Dispose of as unused product.
Empty containers should be taken to an approved waste handling site for recycling or disposal.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
