Registration Dossier

Administrative data

First-aid measures

Emergency measure - Inhalation: Move exposed person to fresh air; in case of indisposition
seek medical advice.
Emergency measure - Eyes: Rinse with plenty of water; if irritation occurs, seek
medical advice.
Emergency measure - Skin: Wash with soap and water.
Emergency measure - Ingestion: Symptomatic treatment; in case of indisposition seek medical
advice.

Fire-fighting measures

Recommended extinguishing agent: Water, dry powder, foam

Product arising from burning: Combustion products may contain carbon-, nitrogen- and
sulfuroxides as well as hydrogen fluoride

Product determined by test: N

Protective equipment: Wear self contained breathing apparatus

Accidental release measures

Emergency measures in case of spillage: Avoid skin and eye contact. Do not inhale dust. Wear
appropriate personal protective equipment (see "handling").
Solids: sweep up avoiding dust formation (wet powders with
water or use an approved industrial vacuum cleaner) and
place in suitable containers for disposal.

Liquids: absorb using an adequate absorbent (such as
kieselgur, sand, saw dust), collect and place in suitable
containers (labelled according to TRGS 201) for disposal.
Dispose of waste material in authorized incineration
facilities.

Handling and storage

Handling: Alle Arbeitsverfahren sind grundsätzlich so zu gestalten,
dass die Belastung durch Einatmen des Stoffes so gering wie
möglich und der Augenkontakt ausgeschlossen ist.

Bei Abfüll-, Umfüll- und Dosierarbeiten sowie bei Probe-
nahmen sollten geschlossene bzw. zumindest staubdichte
Vorrichtungen verwendet werden.

Beim Umgang in offenen Systemen sollte möglicher Staub
unmittelbar am Entstehungsort abgesaugt werden.

Wenn technische Absaug-oder Lüftungsmaßnahmen nicht möglich
oder unzureichend sind, sollte Atemschutz (z.B. Staubmaske
mit Partikelfilter) getragen werden.

Zur Vermeidung von Hautkontakt sollten geprüfte Schutzhand-
schuhe (z.B. aus PVC oder Nitrilkautschuk) und geeignete
Schutzkleidung (z.B. normale Arbeitskleidung) getragen
werden.

Ein sicherer Augenschutz (z.B. Korbbrille) ist unbedingt
erforderlich.

In unmittelbarer Nähe des Arbeitsbereiches sollten Augen-
brausen bereitgestellt und ihr Standort auffällig gekenn-
zeichnet werden.

Bei möglicher Staubentwicklung sollten wegen der poten-
tiellen Staubexplosionsgefahr potentielle Zündquellen

aus dem Arbeitsbereich entfernt werden. Des weiteren

sollten Maßnahmen gegen elektrostatische Aufladungen
getroffen werden.

"ENGLISH"

All work processes must always be designed so that the
exposure through inhalation of the substance is as low as
possible and eye contact is excluded.

Closed or at least dustproof equipment should be used during
filling, transfer, metered feeding and sampling.

In the case of handling in open systems, any dust which may
form should be extracted directly at the point of origin.

If technical extraction or ventilation measures are not
possible or are insufficient, respiratory protection (e.g.
dust mask with particle filter) should be worn.

In order to avoid skin contact, protective gloves (e.g. made
of PVC or nitrile rubber) and suitable protective clothing
(e.g. normal working clothes) should be worn.

Safe eye protection (e.g. tightly fitting goggles) is
absolutely essential.

Eye douches should be made available in the immediate
vicinity of the working area and their location labelled
conspicuously.

Due to the potential dust-explosion risk, any dust that may
form should be removed from the working area. In addition,
measures should be taken to prevent static discharge.

Storage: The substance should be stored in well sealed, labelled
according to the regulations and secure containers in
adequate rooms at room temperature. The containers should be
secured against falling down. Avoid residues outside the
containers.

Packaging of the substance and or preparation: Adequate plastic containers: Big-Bags (ca 500 kg)

cardboard folding box with PE inliners: 15-30 kg


(Wellpappfaltkiste mit PE Inliner)

Transport information

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Marine transport (IMDG)

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Air transport ICAO/IATA

Remarks
Transport: Not classified

Transport in well sealed suitable containers. The containers
should be secured against falling down. Label containers in
accordance with pertinent regulations.
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Exposure controls / personal protection

Stability and reactivity

Danger other than fire: Not known

Chemical reaction with water: No reaction with water

Dust explosion: Not to be expected if handled under good industrial hygiene
practices.

Dust explosion determined by test: N

Disposal considerations

Industry - Possibility of recovery/recycling: Normal application results in the consumption of ca. 95 %

by irreversible binding to the cellulose or cotton fibers;
recovery or recycling of the remaining test substance is

not possible.

Industry - Possibility of neutralisation: No suitable method known

Industry - Possibility of destruction: controlled discharge: Not suitable for deposit in landfill site.

Industry - Possibility of destruction - incineration: Incineration with flue gas scrubbing.

Industry - Possibility of destruction - water purification: Removal by controlled discharge to a waste water treatment
plant. It is estimated that approx. 5 % of the total
quantity used is discharged into internal industrial
effluents as highly diluted solution. A purification of

the waste water in a waste water treatment plant is
recommended. The dyestuff should be used in a well

equiped dyehouse.

If necessary the waste water can be purified prior to the
waste water treatment by membrane filtration or by
floculation with cationic agents or by treatment with ozone.
The most effective method is the membrane filtration: more
than 99 % of the remaining dyestuff can be removed from the
waste water.

Industry - Possibility of destruction - other: None

Public at large - Possibility of recovery/recycling: Not applicable