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Link to relevant study record(s)

Reference
Endpoint:
oxidising solids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
8.11.19 - 26.3.2020
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to
Guideline:
EU Method A.17 (Oxidising Properties (Solids))
Version / remarks:
2008
Deviations:
no
GLP compliance:
yes (incl. certificate)
Specific details on test material used for the study:
CAS No. 890707-28-5
Batch 628-042-00
Purity 99.0%
Analysis date 16 October 2019
Expiry date 16 October 2021
Supplier ADAMA Makhteshim Ltd.
Appearance Beige powder
Packaging White opaque plastic bag
Quantity received 1 kg
Date of receipt 12 November 2019
Storage In darkness at room temperature
Identification number 19-193
Contact with:
powdered cellulose
Key result
Sample tested:
test mixture as specified
Remarks:
10/90 test item/cellulose
Parameter:
burning rate
Result:
2.5 mm/s
Key result
Sample tested:
test mixture as specified
Remarks:
20/80 test item/cellulose
Parameter:
burning rate
Result:
2.27 mm/s
Key result
Sample tested:
test mixture as specified
Remarks:
30/70 test item/cellulose
Parameter:
burning rate
Result:
1.87 mm/s
Key result
Sample tested:
reference mixture as specified
Remarks:
10/90 barium nitate/cellulose
Parameter:
burning rate
Result:
2.94 mm/s
Key result
Sample tested:
reference mixture as specified
Remarks:
20/80 barium nitrate/cellulose
Parameter:
burning rate
Result:
2.5 mm/s
Key result
Sample tested:
reference mixture as specified
Remarks:
30/70 barium nitrate/cellulose
Parameter:
burning rate
Result:
2.11 mm/s

Reference item barium nitrate / cellulose mixtures containing 10 to 90% weight of oxidizer (reference item) in 10% increments were prepared.  

The pile was formed by means of a mould. After dropping the mould once from a height of 2 cm onto a solid surface, the remaining excess mixture was scraped off with an obliquely positioned sheet. A non-combustible, non-porous and low heat-conducting plate was then placed on the top of the mould. The apparatus was inverted and the mould was removed.

A hot flame of a gas burner heated to approximately 1000 °C was used as ignition source. The air-speed was sufficient to prevent fumes escaping into the laboratory and did not vary during the test. One end of the pile was ignited by touching with the flame.

The time of reaction over a 200 mm distance after the reaction zone had propagated an initial distance of 30 mm was measured.

After the test was performed with the reference item, the test was then carried out at least once with each mixture of the test item with cellulose.

If the maximum burning rate of the test item / cellulose mixtures was found to be significantly greater than for the reference item / cellulose mixtures, the test could be stopped. Otherwise the test should be continued with the following series, to determine the fastest burning rate.

The test was performed six times for the three mixtures having produced the highest burning rate, both for reference item / cellulose mixtures and for test item / cellulose mixtures.

Interpretation of results:
GHS criteria not met
Conclusions:
2-amino-5-chloro-N,3-dimethylbenzamide was not considered to have oxidising properties under the experimental conditions used.
Executive summary:

In compliance with Regulation (EC) No. 1907/2006, Council Regulation (EC) No. 440/2008 EC A.17. Method (2008) for 2-amino-5-chloro-N,3-dimethylbenzamide the following parameters were measured:

The maximum burning rate obtained with the test item was 2.50 mm/s for the test item / cellulose mixture (10/90% w/w).

The maximum burning rate obtained with the reference item was 2.94 mm/s for the reference item / cellulose mixture (10/90% w/w).

The maximum burning rate of test item / cellulose mixture was slower than the maximum burning rate with reference item / cellulose mixture.

 

The test item was not considered to have oxidizing properties under the experimental conditions used.

Description of key information

In compliance with Regulation (EC) No. 1907/2006, Council Regulation (EC) No. 440/2008 EC A.17. Method (2008) for 2-amino-5-chloro-N,3-dimethylbenzamide the following parameters were measured:

The maximum burning rate obtained with the test item was 2.50 mm/s for the test item / cellulose mixture (10/90% w/w).

The maximum burning rate obtained with the reference item was 2.94 mm/s for the reference item / cellulose mixture (10/90% w/w).

The maximum burning rate of test item / cellulose mixture was slower than the maximum burning rate with reference item / cellulose mixture.

 

The test item was not considered to have oxidizing properties under the experimental conditions used.

Key value for chemical safety assessment

Oxidising properties:
non oxidising

Additional information

Justification for classification or non-classification

No oxidising properties were found in a test accoding to EC A.17 (2008)