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Physical & Chemical properties

Vapour pressure

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Reference
Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Study period:
30 October 2019 to 31 October 2019
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
OECD Guideline 104 (Vapour Pressure Curve)
Deviations:
no
Qualifier:
according to guideline
Guideline:
EU Method A.4 (Vapour Pressure)
Deviations:
no
GLP compliance:
yes
Other quality assurance:
other: Not specified
Type of method:
effusion method: isothermal thermogravimetry
Specific details on test material used for the study:
No further details specified in the study report
Key result
Test no.:
#1
Temp.:
20 °C
Vapour pressure:
0 Pa
Key result
Test no.:
#2
Temp.:
25 °C
Vapour pressure:
0 Pa

Results of the Vapour pressure Isothermal TGA Analysis

 

Temperature

[°C]

Weight loss

[μg/min]

vr

[g/cm2/h]

log vr

log Pr

Pr

[Pa]

140

0.826208

9.86 x 10-5

-4.01

0.12

1.3

0.787779

9.40 x 10-5

-4.03

0.10

1.2

150

1.42789

1.70 x 10-4

-3.77

0.39

2.4

1.37405

1.64 x 10-4

-3.79

0.37

2.3

160

2.522252

3.01 x 10-4

-3.52

0.66

4.6

2.44942

2.92 x 10-4

-3.53

0.65

4.5

170

4.32999

5.17 x 10-4

-3.29

0.93

8.5

4.14315

4.95 x 10-4

-3.31

0.91

8.0

 

 

Vapour Pressure of the Test Item

 

Temperature

[°C]

log Pr

Pr

[Pa]

Pr

[mm Hg]

20

-4.81

1.6 x 10-5

1.2 x 10-7

25

-4.53

3.0 x 10-5

2.2 x 10-7

Conclusions:
The vapour pressure of the test item at 20°C (293K) and 25°C (298K) was:
20°C
[Pa] [mm Hg]
≤ 1.6 × 10-5 ≤ 1.2 × 10-7

25°C
[Pa] [mm Hg]
≤ 3.0 × 10-5 ≤ 2.2 × 10-7
Executive summary:

The objective of this study was to determine the vapour pressure of test item CAS 577978 - 76-8, in accordance to OECD test guideline 104, in compliance with GLP.

The isothermal TGA effusion method was applied for the determination of the vapour pressure of CAS 577978-76-8. The weight losses of the test item had to be determined at temperatures above the melting temperature of the test item. According to this, the vapour pressure of the test item could be slightly overestimated and is reported as less than or equal to these values. The vapour pressure of the test item at 20°C (293K) and 25°C (298K) was:

20°C

[Pa] ≤ 1.6 × 10-5, [mm Hg] ≤ 1.2 × 10-7.

25°C

[Pa] ≤ 3.0 × 10-5, [mm Hg] ≤ 2.2 × 10-7.

Description of key information

Vapour Pressure of the Test Item

Temperature

[°C]

log Pr

Pr

[Pa]

Pr

[mm Hg]

20

-4.81

1.6 x 10-5

1.2 x 10-7

25

-4.53

3.0 x 10-5

2.2 x 10-7

Key value for chemical safety assessment

Vapour pressure:
0 Pa
at the temperature of:
20 °C

Additional information