Registration Dossier

Administrative data

First-aid measures

If inhaled
- Quickly move the person away from the contaminated area. Make the affected person rest.
- Immediate medical attention is required.
- Show this sheet to the doctor.
- Be prepared to provide first aid or medical support if necessary.

In case of eye contact
- Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
- Keep eye wide open while rinsing.
- Show this sheet to the doctor.
- Always obtain medical advice, even if there are no symptoms.
- Be prepared to provide first aid or medical support if necessary.

In case of skin contact
- Wash off immediately with plenty of water for at least 15 minutes.
- Use appropriate protective equipment when treating a contaminated person.
- Obtain medical attention.
- Show this sheet to the doctor.
- Be prepared to provide first aid or medical support if necessary.

If swallowed
- Do NOT induce vomiting.
- Immediate medical attention is required.
- Show this sheet to the doctor.
- Do not give anything to drink.
- Be prepared to provide first aid or medical support if necessary.

Fire-fighting measures

Suitable extinguishing media
- Water spray
- Foam
- Carbon dioxide (CO2)
- Multi-purpose powders

Extinguishing media which shall not be used for safety reasons
- High volume water jet

Special exposure hazards in a fire
- Under fire conditions:
- Will burn
- On combustion, toxic gases are released

Special protective equipment for fire-fighters
- In the event of fire, wear self-contained breathing apparatus.
- Personal protective equipment comprising: suitable protective gloves, safety goggles and protective clothing

Specific fire fighting methods
- Cool containers/tanks with water spray.
- Do not use a solid water stream as it may scatter and spread fire.

Other information
- Standard procedure for chemical fires.
- Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
- Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

Accidental release measures

Personal precautions
- Where exposure level is not known, wear approved, positive pressure, self-contained respirator.
- Where exposure level is known, wear approved respirator suitable for level of exposure.
- In addition to the standard protective clothing/equipment (see section on exposure controls/personal protection), wear a two piece PVC suit with hood or PVC overalls with hood.

Environmental precautions
- Stop the leak. Turn leaking containers leak-side up to prevent the escape of liquid.
- Contain the spilled material by bunding.
- Do not let product enter drains.
- Do not allow uncontrolled discharge of product into the environment.

Methods for cleaning up
- Stop leak if safe to do so.
- Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).
- Keep in properly labelled containers.
- Keep in suitable, closed containers for disposal.
- After cleaning, flush away traces with water.
- Recover the cleaning water for subsequent disposal.
- If slipperiness remains apply more dry-sweeping compound.
- Decontaminate tools, equipment and personal protective equipment in a segregated area.
- Dispose of in accordance with local regulations.
- Never return spills in original containers for re-use

Handling and storage

Handling
- Handle in accordance with good industrial hygiene and safety practice.
- Wash hands before breaks and at the end of workday.
- When using do not eat, drink or smoke.
- Eye wash bottles or eye wash stations in compliance with applicable standards.
- Ensure that eyewash stations and safety showers are close to the workstation location.

Storage
- Storage period: > 12 Months
- Store in accordance with the particular national regulations.
- To guarantee the quality and properties of the product keep according to Storage temperature and conditions.

Transport information

Land transport (ADR/RID)

UN number:
UN 3278
Proper shipping name and description:
ORGANOPHOSPHORUS COMPOUND, LIQUID, TOXIC, N.O.S. (phosphonium salt)
Class:
Hazard Class: 6.1
Classification code:
T1
Packaging group:
III
Labels:
6.1 - Toxic
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
UN 3278
Proper shipping name and description:
ORGANOPHOSPHORUS COMPOUND, LIQUID, TOXIC, N.O.S. (phosphonium salt)
Class:
Hazard Class: 6.1
Classification code:
T1
Packaging group:
III
Labels:
6.1 - Toxic
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN 3278
Proper shipping name and description:
ORGANOPHOSPHORUS COMPOUND, LIQUID, TOXIC, N.O.S. (phosphonium salt)
Class:
Hazard Class: 6.1
Packaging group:
III
EmS code:
F-A , S-A
Labels:
6.1 - Toxic
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN 3278
Proper shipping name and description:
ORGANOPHOSPHORUS COMPOUND, LIQUID, TOXIC, N.O.S. (phosphonium salt)
Class:
Hazard Class: 6.1
Packaging group:
III
Labels:
6.1 - Toxic
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Technical protection measures
- Ensure adequate ventilation.
- Apply technical measures to comply with the occupational exposure limits.

Occupational exposure controls

Respiratory protection
- When used in a spray application, a NIOSH-certified dust/mist respirator is required.
- Keep in a well-ventilated place.

Hand protection
- Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact).
- Impervious gloves
Suitable material
- Nitrile or fluorinated rubber gloves.

Eye protection
- Chemical resistant goggles must be worn.
- Tightly fitting safety goggles

Skin and body protection
- Impervious clothing
- Full protective suit
- Change working clothes after each workshift.
- Contaminated work clothing should not be allowed out of the workplace.

Hygiene measures
- Handle in accordance with good industrial hygiene and safety practice.
- Wash hands before breaks and at the end of workday.
- When using do not eat, drink or smoke.
- Eye wash bottles or eye wash stations in compliance with applicable standards.
- Ensure that eyewash stations and safety showers are close to the workstation location.

Environmental exposure controls
- Dispose of rinse water in accordance with local and national regulations.

Stability and reactivity

Stability
- Stable

Possibility of hazardous reactions
- No data available

Conditions to avoid
- No data available

Materials to avoid
- None

Hazardous decomposition products
- Oxides of phosphorus
- Phosphorus compounds

Disposal considerations

Product Disposal
- The Company encourages the recycle, recovery and reuse of materials, where permitted. If disposal is necessary,
- The Company recommends that organic materials, especially when classified as hazardous waste, be disposed of by thermal treatment or incineration at approved facilities. All local and national regulations should be followed.