Registration Dossier

Administrative data

Endpoint:
melting point/freezing point
Type of information:
experimental study
Adequacy of study:
key study
Study period:
January 2013
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
guideline study with acceptable restrictions

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2013
Report Date:
2013

Materials and methods

Test guideline
Qualifier:
equivalent or similar to
Guideline:
OECD Guideline 102 (Melting point / Melting Range)
Principles of method if other than guideline:
Modulated DSC was used for glass transition analysis during this study and is a technique in which a sinusoidal temperature oscillation is overlaid with the standard linear DSC experiment. This increases resolution and allows for thermal events due to changes in heat capacity to be separated from thermal events due to kinetics. A glass transition (Tg) is a thermal event due to changes in heat capacity and therefore if a given specimen has a Tg it will occur in the reversing heat flow. This technique also removes any thermal history from the thermal event therefore a second heat cycle is not needed. The midpoint is used to represent the glass transition, although the glass transition occurs over a temperature range.
GLP compliance:
no
Type of method:
differential scanning calorimetry

Test material

Reference
Name:
Unnamed
Type:
Constituent
Test material form:
liquid
Remarks:
Homogenous Liquid
Specific details on test material used for the study:
Trade name: CYPHOS IL 101 Phosphonium Salt
Physical state: liquid
Composition of test material, percentage of components: Trihexyl(tetradecyl)phosphonium chloride (258864-54-9), > 95%
Lot/batch No.: WEC031280
Expiration date of the lot/batch: >1 year (March 2016) when stored at room temperature and protected from direct contact with water (hydrophobic)

Results and discussion

Melting / freezing point
Melting / freezing pt.:
> -66.8 - < -66.1 °C
Remarks on result:
other: Glass transition temperature

Applicant's summary and conclusion

Conclusions:
The glass transition temperature of the substance was tested in duplicates and is ca. -66.5 °C.
Executive summary:

The glass transition temperature of the substance was tested in duplicates and is ca. -66.5 °C.