Iron, bis(glycinato-.kappa.N,.kappa.O)-

Guidance on Safe Use

First-aid measures

Description of first aid measures: If health problems arise or in case of doubt, always seek medical attention and provide him with the information given in this safety data sheet.

Inhalation: Stop work, take the victim away or take him to fresh air and provide conditions for rest in a position that allows breathing. In case of unconsciousness keep airways open. If breathing difficulties persist, get medical attention.

Skin contact: Take off contaminated clothing. Wash contaminated skin with plenty of soap and water. Wash clothing before reuse. If any symptoms occur, contact a physician.

Eye contact: If the victim is wearing contact lenses, they should be removed before washing, if possible. Flush eyes with plenty of water as soon as possible and as thoroughly as possible for about 15 minutes with the eyelid held wide open. Avoid strong water stream due to the risk of mechanical damage to the cornea. Contact an ophthalmologist.

Ingestion: Rinse mouth with water. Give plenty of water to drink, only if the injured person is conscious. Never give anything by mouth to an unconscious person. Do not induce vomiting. Call a doctor if you feel unwell or if you have swallowed large amounts.

Fire-fighting measures

Extinguishing media: CO2, foams, water spray and other extinguishing media suitable for materials burning around the product.

Unsuitable extinguishing media: water jet.

Special hazards arising from the substance or mixture: The product is not flammable under normal conditions. The products of decomposition and combustion of the mixture may be toxic: carbon oxides, sulfur oxides, iron oxide vapors. Inhalation of gases formed during thermal decomposition may cause irritation and corrosive effects on the respiratory system. Lung effects may be delayed. Persons who have been exposed to the inhalation of decomposition gases should receive immediate medical attention.

Advice for firefighters: Use gas-tight protective clothing and personal breathing apparatus. Quench (smoke) fumes / gases / vapors / mists with a water spray jet. Fire residues should be disposed of in accordance with applicable regulations. Do not allow contaminated fire extinguishing water to reach ground and surface waters. In the event of environmental contamination, notify the appropriate local authorities.

Accidental release measures

Personal precautions, protective equipment and emergency procedures: Inform the surroundings about the accident; remove from the danger area all persons not involved in the liquidation of the accident; if necessary, order evacuation. Avoid direct long-term contact with the released substance. Avoid creating and inhaling dust. If released in a closed space, ensure effective ventilation. Use personal protection equipment .

Environmental precautions: Prevent product from entering drains, underground and surface waters, and soil. In the event of environmental contamination inform appropriate services.

Methods and material for containment and cleaning up: Secure the sewers inlets. If possible, protect against further spillage. Place damaged packaging in replacement packaging. Collect spilled product dry. Flush residue with plenty of water. Used product and washings should be used as intended or disposed of in accordance with local regulations.

Handling and storage

Precautions for safe handling: Use as intended only by trained and properly equipped with personal protective equipment personnel in well ventilated rooms with exhaust ventilation. Do not breathe dust. When working with the product, do not eat, drink or smoke. Before entering food-handling areas, remove contaminated clothing and protective equipment. Wash hands before breaks and after finishing work. Wash contaminated clothing before reuse.

Conditions for safe storage, including information on any mutual incompatibilities: Hygroscopic product - store in an airtight, labeled container in dry, cool and well ventilated rooms. Protect against sunlight and weather conditions. Keep away from incompatible materials and food products.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

3077

Shipping information

Proper shipping name and description:

MATERIAŁ ZAGRAŻAJĄCY ŚRODOWISKU STAŁY I.N.O.

Chemical name:

glicynian żelaza

Language:

Polish

Class or division:

Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances

Packing group:

Packing group III: Substances presenting low danger

Labels:

9

SpecialProvisions

Inland waterway transport (UN RTDG/ADN(R))

UN number:

3077

Shipping information

Proper shipping name and description:

MATERIAŁ ZAGRAŻAJĄCY ŚRODOWISKU STAŁY I.N.O.

Chemical name:

glicynian żelaza

Language:

Polish

Class or division:

Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances

Packing group:

Packing group III: Substances presenting low danger

Labels:

9

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

3077

Shipping information

Proper shipping name and description:

MATERIAŁ ZAGRAŻAJĄCY ŚRODOWISKU STAŁY I.N.O.

Chemical name:

glicynian żelaza

Language:

Polish

Class or division:

Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances

Packing group:

Packing group III: Substances presenting low danger

Labels:

9

Marine pollutant

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

UN3077

Shipping

Class or division:

Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances

Packing group:

Packing group III: Substances presenting low danger

Labels:

9

Remarks

SpecialProvisions

Exposure controls / personal protection

Personal protective equipment should meet the requirements european and national law. Use in accordance with the principles of good industrial practice and safety principles. Do not eat, drink or smoke when using this product. Avoid contact with skin, eyes and clothing. Keep away from food. Wash hands and face after handling the product. Take off contaminated clothing immediately and wash before reuse.

Appropriate engineering controls: local and general ventilation.

Individual protection measures, such as personal protective equipment:

Eye / face protection: close-fitting safety glasses (EN 166)

Skin protection:

Hand protection: coated protective gloves in accordance with EN374 and CE marking

Other: safety shoes and clothing (EN 340).

Respiratory protection: the use of appropriate breathing apparatus or air filters is required when dusts are generated or when the maximum occupational exposure limit is exceeded. The choice of respirator should be based on the known or expected level of exposure, product danger and occupational safety limits (according to EN 143).

Environmental exposure controls: Emissions from ventilation systems and process equipment should be controlled to determine their compliance with the requirements of environmental protection laws.

Stability and reactivity

Reactivity: The product is not reactive under recommended storage conditions.

Chemical stability: The product is stable under recommended conditions of use and storage. The product is hygroscopic - moisture may be absorbed from the air if the packaging leaks.

Possibility of hazardous reactions: Under normal conditions of use, hazardous reactions may not occur.

Conditions to avoid: Water, moisture, mechanical damage to the packaging, high temperature (the product decomposes at 150 ° C).

Incompatible materials: Unknown.

Hazardous decomposition products: Under normal conditions of use, there are no hazardous decomposition products. Under the influence of high temperature, it can decompose with the release of harmful carbon oxides, sulfur oxides, and iron oxide fumes.

Disposal considerations

Do not dispose of the mixture together with municipal waste. Avoid contamination of ground and surface water. Do not store in municipal landfills. Consider the possibility of use. Recovery or disposal of waste product should be carried out in accordance with applicable regulations.

Recovery / recycling / liquidation of packaging waste should be carried out in accordance with applicable regulations. Only completely emptied packaging can be recycled. Do not mix with other waste.