Registration Dossier

Administrative data

First-aid measures

General advice
Take off contaminated clothing and shoes immediately.

Inhalation
Remove to fresh air. Give oxygen. If symptoms persist, call a physician.

Skin contact
Wash off immediately with plenty of water for at least 15 minutes. Call a physician immediately.

Eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

Ingestion
In the case of spontaneous vomiting, hold person's head low to prevent inhalation into the wind-pipe. Rinse mouth with water. If conscious, drink plenty of water. Call a physician immediately.

Most important symptoms and effects, both acute and delayed
Lungs: Depending on the concentration coughing, asthmatic reaction, glottis edema, pulmonary edema.
Eyes: Depending on the concentration conjunctivitis to severe chemical burn of the cor-nea/necrosis, iritis.
Skin: Irritation up to severe chemical burn
Ingestion: Depending on the concentration irritation to severe chemical burn of the affected esophageal, gastric and intestinal mucosa (risk of perforation!), cardiac reaction, respiratory distress, acid-base balance disorders, cramps.

Notes to physician / Possible hazards
Deep skin or corneal necrosis, pneumonia, esophageal/gastric perforation, pulmonary edema (up to 2 days latency time).

Indication of any immediate medical attention and special treatment needed
Irritation of the skin and mucus membranes can be treated with corticosteroids.
Provided there are no signs of esophageal and gastric perforation, an immediate gastric lavage using a large-bore gastric probe is useful (leave probe until at the hospital). Subsequent admin-istration of charcoal powder useful.
Anti-aspiration prophylaxis possible through early intubation.
With respiratory and pulmonary damages as well as large-area chemical skin burns antibiotic prophylaxis useful.
Treatment of severe chemical burns is the same as with thermal burns.
Treat symptomatically.

Fire-fighting measures

Extinguishing media
Water
Foam
Carbon dioxide (CO2)

Special hazards arising from the substance or mixture
Exposure to decomposition products may be a hazard to health.
Hazardous decomposition products formed under fire conditions.
Carbon monoxide
Sulphur oxides

Advice for firefighters

Special protective equipment for firefighters
In the event of fire, wear self-contained breathing apparatus.
Use personal protective equipment.

Additional advice
Use water spray to cool unopened containers.
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Prevent fire extinguishing water from contaminating surface water or the ground water system.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation.
Use personal protective equipment.
Evacuate personnel to safe areas.
Keep people away from and upwind of spill/leak.
Avoid contact with the skin and the eyes.
Exposure controls

Environmental precautions
Must not get into the soil, sewerage systems and surface water. In the event of contamination, notify the responsible authorities.

Methods and materials for containment and cleaning up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, saw-dust).
Treat recovered material as described in the section "Disposal considerations".

Handling and storage

Precautions for safe handling

Advice on safe handling
Use only in area provided with appropriate exhaust ventilation.
Handle and open container with care.
Exposure controls
Smoking, eating and drinking should be prohibited in the ap-plication area.
Avoid contact with skin and eyes.
Ensure that eye flushing systems and safety showers are located close to the working place.

Advice on protection against fire and explosion
The product should only be used in areas from which all na-ked lights and other sources of ignition have been excluded.


Conditions for safe storage, including any incompatibilities

Requirements for storage areas and containers
Store at room temperature in the original container.
Keep tightly closed in a dry, cool and well-ventilated place.
Containers of polyethylene, polypropylene, stove-enamelled steel, glass.
Use PTFE seals.

Further information on stor-age conditions
Store in accordance with the particular national regulations.

Advice on common storage
Keep away from food, drink and animal feedingstuffs.
Incompatible with strong bases and oxidizing agents.

Storage period
12 Months

Storage temperature
< 25 °C

Other data
Stable under recommended storage conditions.

Transport information

Land transport (ADR/RID)

UN number:
UN number: 2936
Shippingopen allclose all
Class:
Class: 6.1
Packaging group:
Packing group: II
Labels:
Labels: 6.1
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Marine transport (IMDG)

UN number:
UN number: 2936
Proper shipping name and description:
Thiolactic acid
Chemical name:
Thiolactic acid
Class:
Class: 6.1
Packaging group:
Packing group: II
EmS code:
EmS Number 1: F-A
EmS Number 2: S-A
Labels:
Labels: 6.1
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN number: 2936
Proper shipping name and description:
Thiolactic acid
Chemical name:
Thiolactic acid
Class:
Class: 6.1
Packaging group:
Packing group: II
Labels:
Packing instruction (cargo aircraft): 662
Packing instruction (passenger aircraft): 654
Remarksopen allclose all
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Exposure controls / personal protection

a) Respiratory protection
Should fumes/aerosols arise, wear breathing apparatus with its own separate air supply.
Suitable for use as an emergency mask: Filter Type A
Follow the instructions for use issued by the producer.

b) Hand protection
Protective gloves
Butyl-rubber / Layer thickness 0,6 - 0,8 mm / Break through time > 480 min (level 6) / EN 374
General recommendation: the usage time for protective gloves is approx. 50% of the breakthrough time measured in the laboratory.


c) Eye protection
Tightly fitting safety goggles
Face-shield

d) Skin and body protection
Safety shoes
Wear closed work/protective clothing. When filling and refilling outside a closed system, additionally put on aprons made of polyethylene (PE).

e) Hygiene measures
Ensure adequate ventilation, especially in confined areas.
General industrial hygiene practice.
Avoid contact with the skin and the eyes.
Regular cleaning of equipment, work area and clothing.
Keep working clothes separately.
Wash hands before breaks and at the end of workday.
Preventive skin protection
Do not eat, drink or smoke when using this product.
Exposure controls

Environmental exposure controls
General advice
Must not get into the soil, sewerage systems and surface water. In the event of contamination, notify the responsible authorities.

Stability and reactivity

Reactivity
No dangerous reaction known under conditions of normal use.

Chemical stability
Storage time: 12 Months
Storage temperature: < 25 °C
Note: Stable under recommended storage conditions.

Hazardous reactions
Response: Keep away from oxidising agents, strongly alkaline and strongly acid materials in order to avoid exothermic reactions.
Note Stability: Stable under normal conditions.

Incompatible materials to avoid
Incompatible with oxidizing agents.


Disposal considerations

Waste from residues / unused products
Can be incinerated, when in compliance with local regulations.
Avoid release to the environment.
This material and its container must be disposed of as hazardous waste.

Disposal of contaminated packaging
This material and its container must be disposed of as hazardous waste.

Suitable cleaning agents
Water

Waste Code
16 05 08: discarded organic chemicals consisting of or containing dangerous substances

Additional advice
The allocation of waste key numbers must be conducted according to specific industrial sectors and processes.
Above-mentioned waste code number is valid for the unused product.
Obtain approval of the relevant authorities before discharging into a sewage treatment plant.