Registration Dossier

Administrative data

First-aid measures

· General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.
· After inhalation:
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
In case of unconsciousness place patient stably in side position for transportation.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing:
Call for a doctor immediately.
Drink plenty of water and provide fresh air. Call for a doctor immediately.

Most important symptoms and effects, both acute and delayed:
No further relevant information available.

Indication of any immediate medical attention and special treatment needed:
No further relevant information available

Fire-fighting measures

5.1 Extinguishing media
· Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water.
· For safety reasons unsuitable extinguishing agents: Water with full jet

Special hazards arising from the substance or mixture
No further relevant information available.

Advice for firefighters
· Protective equipment: Mouth respiratory protective device.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.

Environmental precautions:
Inform respective authorities in case of seepage into water course or sewage system.

Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Use neutralising agent.
Dispose contaminated material as waste according to "Disposal considerations" (below)
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents

Handling and storage

Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.

Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.

Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: Keep container tightly sealed.

Specific end use(s) No further relevant information available.

Transport information

Land transport (ADR/RID)

UN number:
2929
Proper shipping name and description:
2929 TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S.
(prop-2-yn-1-ol)
Language:
English
Class:
6.1 Toxic substances.
Packaging group:
II
Labels:
6.1+3
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
2929
Shippingopen allclose all
Remarksopen allclose all

Marine transport (IMDG)

UN number:
2929
Proper shipping name and description:
TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S. (prop-2-yn-1-ol)
Class:
6.1 Toxic substances
Packaging group:
II
EmS code:
F-E,S-D
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
2929
Proper shipping name and description:
TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S. (prop-2-yn-1-ol)
Class:
6.1 Toxic substances.
Packaging group:
II
Labels:
6.1 (3)
Remarksopen allclose all

Additional transport information

Additional transport information
Warning: Toxic substances
Danger code (Kemler): 63

Exposure controls / personal protection

Control parameters
· Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.

Exposure controls

· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.

· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use self-contained respiratory protective device.

· Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.

· Eye protection:
Tightly sealed goggles

Stability and reactivity

Reactivity
No further relevant information available.

Chemical stability
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.

Possibility of hazardous reactions
No dangerous reactions known.

Conditions to avoid
No further relevant information available.

Incompatible materials:
No further relevant information available.

Hazardous decomposition products:
No dangerous decomposition products known.

Disposal considerations

Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.

· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.