Registration Dossier

Administrative data

First-aid measures

General information:
Consult a physician. Show the safety data sheet to the doctor in attendance.
Inhalation:
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
Skin contact:
Wash off with soap and plenty of water.Consult a physician.
Eye contact:
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Ingestion:
Never give anything by mouth to an unconscious person.Rinse mouth with water.Consult a physician.

Fire-fighting measures

Suitable extinguishing media:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Special hazards arising from the substance or mixture:
Very high dust explosion hazard.
In case of fire, product may form irritant menadione vapors and toxic fumes such as CO.

Advice for firefighters:
Wear self contained breathing apparatus for fire fighting if necessary. Precipitate gases/vapours/mists with water spray.

Accidental release measures

Personal precautions,protective equipment and emergency procedures:
Use personal protective equipment according to the circumstances.
Collect spilled solid material avoiding dust formation.
Avoid breathing vapors, mist or gas.
Ensure adequate ventilation.
Evacuate personnel to safe areas.
Avoid breathing dust.

Environmental precautions:
Do not let product enter drains.

Methods and materials for containment and cleaning up:
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal in compliance with law.

Handling and storage

Precautions for safe handling:
When handling apply local exhaust ventilation.
Avoid formation of dust and aerosols; very high dust explosion hazard.
Take precautionary measures against electrostatic charging.
Wear protective equipment.
Avoid contact with eyes and skin.
Wash thoroughly with cold water after handling.

Conditions for safe storage:
Keep containers tightly closed and away from heat. Store in cool, dry and well ventilated place.
Avoid heat and light exposure, store separate from basic substances.
Standard packaging: carton boxes with inner polyethylene bag.

Transport information

Land transport (ADR/RID)

UN number:
Not regulated
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Inland waterway transport (ADN(R))

UN number:
3077
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Class:
9
Classification code:
M7
Packaging group:
III
Labels:
9
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Marine transport (IMDG)

UN number:
3077
Proper shipping name and description:
Environmentally hazardous substance,
solid, n.o.s (Menadione)
Chemical name:
Menadione
Class:
9
Packaging group:
III
EmS code:
F-A S-F
Labels:
9
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Air transport ICAO/IATA

UN number:
3077
Proper shipping name and description:
Environmentally hazardous substance,
solid, n.o.s (Menadione)
Chemical name:
Menadione
Class:
9
Packaging group:
III
Labels:
9
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Exposure controls / personal protection

Appropriate engineering controls:
Install local dust collection device and overall ventilation device in the workplace, minimize the exposure opportunities to contact the product as far as possible.
Control parameters:
Components with workplace control parameters.
Average allowed concentration in eight-hour working day / Maximum allowed concentration in short exposure: No data available
Biological indicators: No data available
Personal protective equipment and measurement:
Respiratory protection: particulate dust respirator.
Hand protection: industrial quality gloves (PVC, rubber).
Eye protection: safety goggles with side-shields, face shield and eye-cleaning equipment.
Body protection: Complete suit protecting against chemicals and preventing penetration.
Hygiene measures: avoid the bare parts of the body to contact the product, don’t wear contaminated clothing, banded to eat, drink and smoke at workplace after working.
Environmental exposure controls:
No data available

Stability and reactivity

Conditions to avoid:
The product is stable under the suggested handling and storage conditions not causing dangerous reactions.
Materials to avoid:
Strong oxidising agents, strong acids, strong alkalis and iron container.
Hazardous decomposition products:
Irritant menadione vapours and fumes containing CO, CO2, are produced respectively by thermal decomposition or when the product burns.

Disposal considerations

Disposal methods of the substance/preparation:
Whatever cannot be saved for recovery or recycling should be managed in an appropriate waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations.
Disposal methods of the contaminated packaging:
Dispose of contaminated packaging and unused materials in accordance with federal, state and local requirements.