Registration Dossier

Administrative data

First-aid measures

After inhalation: Supply fresh air; consult doctor in case of symptoms.
After skin contact: Instantly rinse with water
After eye contact: Rinse eyes thoroughly with plenty of water for at least 10 minutes while holding eyelids open. If symptoms persist, consult a physician.
After swallowing: IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

Most important symptoms and effect, both acute and delayed are described in section 2 and 11 of the SDS

Fire-fighting measures

-Extinguishing media
Suitable extinguishing agents: Water spray jet, extinguishing powder, CO2, foam.
Unsuitable extinguishing agents for reasins of safety: None

-Special hazards arising from the substance or mixture
In case of fire, toxic incineration products may be released such as: Carbon monoxide (CO), Nitrogen oxides (NOx)

-Advice for firefighter
Protective equipment: Waer self-contained breathing apparatus.
Additional information: Collect contaminated fire fighting water separately. It must not enter drains.

Accidental release measures

-Personal precautions, protective equipment and ermergeny procedures
Waer protective clothing (see section 8 of the SDS), Keep unprotected persons away

-Environmental precautions:
As the product is hazardous for the aquatic environment, it must be prevented from reaching surface water.

-Methods and material for containment and cleaning up
Collect mechanically. Send for recovery or disposal in suitable containers. Dispose of contaminated material as waste according to section 13 of the SDS

Handling and storage

-Precautions for safe handling
Provide good room ventilation or local exhaust ventilation at the workplace. Dusty surfaces and floors should be wiped wet preferably.
Risks to the safety and health of workers may not only be created by work involving chemicals but, inter alia by work equipment and the fitting-out of
work-places. Those risks shall be identified and evaluated.
Information about protection against explosion and fire: No special measures required.

-Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and containers: No special requirements.
Information about storage in a common storage facility: none
Further information about storage conditions: none

-Specific end use(s) No further relevant information available.

Transport information

Land transport (ADR/RID)

UN number:
None
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Inland waterway transport (ADN(R))

UN number:
None
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Marine transport (IMDG)

UN number:
None
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Air transport ICAO/IATA

UN number:
None
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Additional transport information

Additional transport information
Not hazardous for transport according to a.m. regulations.

Exposure controls / personal protection

-Control parameters
· Components with critical values that require monitoring at the workplace:
56-81-5 glycerol
WEL (Great Britain) Long-term value: 10 mg/m³
· Additional information: Information valid at the time of review of safety data sheet.

- Exposure controls
· Personal protective equipment
· General protective and hygienic measures: Wash hands during work breaks and at the end of the shift. Avoid contact with the eyes. Use skin cream for skin protection. Provide skin protection plan.
· Respiratory protection: Not required
· Protection of hands: Chemical protective gloves according to DIN EN 374 with CE-labelling.
Check the condition of protective gloves after each use for any damages like holes, cuts or tears.
Do not wear protective gloves longer than necessary.
After use of gloves apply skin-cleaning agents and skin cosmetics.
· Material of gloves Nitrile rubber, NBR
· Gloves made of the following materials are not suitable: Gloves for mechanical protection do not provide protection against chemicals.
· Eye protection: Safety glasses recommended during refilling.
· Body protection: Protective clothing.
· Risk management measures: The operators shall be instructed adequately. The workplace shall be inspected regularly by competent personnel e.g. the safety representative.

Stability and reactivity

-Reactivity
Up to now, no dangers resulting from a reactivity of the mixture have been identified.

-Chemical stability
· Conditions to be avoided: No decomposition if used according to specifications.
· Minimum shelf life: 24 months from production date.

- Possibility of hazardous reactions No dangerous reactions known.

- Conditions to avoid No further relevant information available.

-Incompatible materials: No further relevant information available.

- Hazardous decomposition products: None, if storage and handling is done according to specification.

Disposal considerations

-Waste treatment methods
· Recommendation: Must be specially treated as hazardous waste under adherence to official regulations. Appropriate disposal operations according to Directive 2008/98/EC on waste: D 10 Incineration on land
· European waste catalogue
16 00 00 WASTES NOT OTHERWISE SPECIFIED IN THE LIST
16 03 00 off-specification batches and unused products
16 03 06 Organic wastes other than those mentioned in 16 03 05
HP 14 Ecotoxic
· Contaminated packaging:
· Recommendation: Packaging can be reused or recycled after cleaning.
· Recommended cleaning agent: Water, if necessary with cleaning agent.