Registration Dossier

Administrative data

First-aid measures

· 4.1 Description of first aid measures
· General information No special measures required.
· After inhalation Supply fresh air; consult doctor in case of symptoms.
· After skin contact Immediately rinse with water.
· After eye contact Rinse opened eye for several minutes under running water. Then consult doctor.
· After swallowing
Drink large quantities of water, do not induce vomiting. Consult a physician immediately.
· 4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

Fire-fighting measures

· 5.1 Extinguishing media
· Suitable extinguishing agents Foam, carbon dioxide, dry powder, water spray.
· 5.2 Special hazards arising from the substance or mixture
Can be released in case of fire :
- carbon dioxide, carbon monoxide
Sulphur dioxide (SO2)
- hydrogen sulfide (H2S)
- sulphur trioxide (SO3)
· 5.3 Advice for firefighters
· Protective equipment: Wear self-contained breathing apparatus.

Accidental release measures

· 6.1 Personal precautions, protective equipment and emergency procedures
Wear protective clothing.
· 6.2 Environmental precautions: Do not allow the product to enter drains, waterways or soil.
· 6.3 Methods and material for containment and cleaning up:
Collect mechanically.
Dispose of contaminated material as waste according to item 13.
· 6.4 Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for information on disposal.

Handling and storage

· 7.1 Precautions for safe handling Prevent formation of dust.
· Information about protection against explosions and fires:
Cool endangered containers by water spray
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage
· Requirements to be met by storerooms and containers: No special requirements.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: Store in a cool place.

Transport information

Land transport (ADR/RID)

UN number:
3077
Shippingopen allclose all
Class:
9
Classification code:
9
Packaging group:
III
Labels:
9
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
3077
Shippingopen allclose all
Class:
9
Classification code:
9
Packaging group:
III
Labels:
9
Remarksopen allclose all

Marine transport (IMDG)

UN number:
3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS
SUBSTANCE, SOLID, N.O.S.
Chemical name:
2,2'-
ethylenedithiodiethanol
Class:
9
Packaging group:
III
EmS code:
F-A,S-F
Labels:
9
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS
SUBSTANCE, SOLID, N.O.S.
Chemical name:
2,2'-
ethylenedithiodiethanol
Class:
9
Packaging group:
III
Labels:
9
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

· Additional information about design of technical systems: No further data; see item 7.
· 8.1 Control parameters
· Components with limit values that require monitoring at the workplace: Not required.
· Additional information: The lists that were valid during the compilation were used as basis.
· 8.2 Exposure controls
· Personal protective equipment
· General protective and hygienic measures
Do not eat, drink or smoke while working.
Wash hands during breaks and at the end of the work.
· Breathing equipment:
In case of formation of vapours/dusts:
Short term filter device:
Filter P1.
· Protection of hands: PVC gloves
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks
of quality and varies from manufacturer to manufacturer.
· Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and
has to be observed.
· Eye protection: Tightly sealed safety glasses.
· Body protection: suitable clothing

Stability and reactivity

10.1 Reactivity No dangerous reaction known under conditions of normal use.
· 10.2 Chemical stability
No hazardous reactions if the regulations / instructions for storage and handling are considered.
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· 10.3 Possibility of hazardous reactions No dangerous reactions known
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: No further relevant information available.
· 10.6 Hazardous decomposition products:
Sulphur dioxide
Hydrogen sulphide
Sulphur trioxide (SO3) or SO3-mist
Carbon monoxide and carbon dioxide

Disposal considerations

· 13.1 Waste treatment methods
· Recommendation Must be specially treated under adherence to official regulations.
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.
· Recommended cleaning agent: Water, if necessary with cleaning agent.