Registration Dossier

Data platform availability banner - registered substances factsheets

Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Auto flammability

Currently viewing:

Administrative data

Link to relevant study record(s)

Reference
Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
26 Nov - 03 Dec 2015
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Version / remarks:
2008
Qualifier:
according to guideline
Guideline:
DIN 51794 (Testing of mineral oil hydrocarbons - Determination of ignition temperature)
Version / remarks:
2003
Qualifier:
according to guideline
Guideline:
other: DIN EN 14522: Determination of the Ignition Temperature of gases and liquids
Version / remarks:
2005
GLP compliance:
no
Key result
Auto-ignition temperature:
235 °C
Atm. press.:
1 017.6 hPa

Results

Preliminary test

An approximate value of the ignition temperature of the test item was first determined in a preliminary test. Results are given in the table below. An “ignition” is indicated by + and “no ignition” by -. Five drops were added into the Erlenmeyer flask at each temperature.

 

Results of the preliminary test 

Preliminary Test

Temperature / °C

Ignition / +/-

306

+

285

+

265

+

244

+

224

-

234

-

239

-

Atmospheric pressure: 1004.1 - 1008.6 hPa

 

In the preliminary test, the lowest temperature at which an ignition occurred was 244 °C.

 

Main test

The lowest temperatures at which an ignition occurred in the main tests are given in the following table.

Results of third test series

Main test series

Lowest temperatures of an ignition

Highest temperatures without an ignition

Atmospheric Pressure

1

244 °C

242 °C

1017.6 hPa

2

236 °C

234 °C

1017.6 hPa

3

238 °C

236 °C

1017.6 hPa

 

Based on the results of the main test series, the lowest auto-ignition temperature was 236 °C.

Regulation EC No. 440/2008 and DIN 51794: The auto-ignition temperature rounded down to the nearest multiple of 5 °C was determined as 235 °C.

 

Final results

The test item has an auto-ignition temperature of 235 °C according to Regulation EC No. 440/2008 Method A.15 Auto-Ignition Temperature (Liquids and Gases) and DIN 51794 (2003): Determination of Ignition Temperature.

Conclusions:
The auto-ignition temperature of the test item was determined to be 235 °C.
Executive summary:

An experimental study was conducted to determine the flash point of the test item according to Regulation EC No. 440/2008 Method A.15. and DIN 51794. The experiment was performed in a semi-automated (ZT1) and fully automated apparatus (ZT2). The lowest temperature of ignition rounded down to the nearest multiple of 5 °C was determined to be 235 °C.

Description of key information

Auto-ignition temperature: 235 °C at 1017.6 hPa (EU Method A.15)

Key value for chemical safety assessment

Additional information