Registration Dossier

Administrative data

First-aid measures

4 First aid measures
4.1 Description of first aid measurements:
• General advice:
Remove contaminated clothing even underwear and shoes immediately and wash before next use.
• After inhalation:
Ensure supply of fresh air. Store person in a position comfortable for breath. Summon a doctor immediately if feel unwell.
• After skin contact:
Wash immediately with plenty of soap and water. In case of persistent skin irritation get medical
advice.
• After eye contact:
Rinse opened eye several minutes with fluent water. Remove contact lenses if present and easy to
do.
Continue rinsing. In case of persistent complaints get medical advice.
• After swallowing:
Cause no vomit, rinse the mouth and drink plenty of water; get medical attention immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms: The most known symptoms are described in the labelling and in chapter 11.
4.3 Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

Fire-fighting measures

5 Fire- fighting measures
5.1 Extinguishing agents: Water spray jet, alcohol resistant foam, ABC- powder or carbon dioxide.
Unsuitable extinguishing media: Water full jet.
5.2 Special hazards arising from the substance or mixture: Hazardous steam, smoke or mist.
A fire may form Carbon monoxide (CO), Carbon dioxide (CO2) and nitrogen oxides (NOx).
5.3 Advice for fire-fighters: Use self containing breathing apparatus, protective clothing and rubber
boots.
Do not breathe explosion or combustion gases. Cool down container with water spray jet.
Additional information: Contaminated fire water has to be disposed according to regional regulations.

Accidental release measures

6 Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures:
Use personal protection equipment. Provide for sufficient ventilation.
6.2 Environment precautions:
Do not allow to enter drains or waterways.
Inform respective authorities when entering in waters or the sewerage.
6.3 Methods and material for containment and cleaning- up:
Pick up mechanically with liquid binding materials (sand, kieselgur, wood shavings, universal binding
agent).
Dispose of absorbed material in accordance with the regional regulations.
6.4 Reference to other sections:
For further information on exposure monitoring and disposal see section 8 and 13.

Handling and storage

7 Handling and storage
7.1 Precautions for safe handling
Protective measures:
• Advice on safe handling: When used appropriately there are no further measures necessary.
• Fire preventions: When used appropriately there are no further measures necessary.
• Hygiene measures: Do not eat, drink and smoke when working. Wash hands before break and after
work.
• General safety measures: Don´t inhale aerosole, gas or dust. Avoid contact with skin.
• Environmental precautions: Avoid release to the environment.
7.2 Condition for safe storage, including any incompatibilities
• Technical matters and storage conditions:
Store only in well closed original container, in a cool, well- ventilated place.
• Packaging materials: PE
• Further information on storage rooms and vessels: -
Hints on storage assembly
• German storage class: 12
• Materials to avoid: Exothermal reaction with isocaynates.
7.3 Specific end use(s): No further recommendations (see chapter 1).

Transport information

Land transport (ADR/RID)

UN number:
No dangerous goods according to transport regulations.
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Inland waterway transport (ADN(R))

UN number:
No dangerous goods according to transport regulations.
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Marine transport (IMDG)

UN number:
No dangerous goods according to transport regulations.
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Air transport ICAO/IATA

UN number:
No dangerous goods according to transport regulations.
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Exposure controls / personal protection

8 Exposure control/ Personal protection
8.1 Control parameter
8.1.1 Occupational exposure limits*
Ethanediol CAS-Nr. 107-21-1
Specification: Working place- air limit TRGS 900 (MAK- value): 10ml/m3 (ppm) / 26 mg/m3
Max. limit: Exceeding factor 2 (I)
Comment: H (scin resorptive), Y, DFG
Specification: Working place regulation: 2000/39/EG
Value: 8 h: 52mg/m3 # 20ppm; Short time: 104mg/m3 # 40ppm
Hint: skin
8.1.2 Biological limit values*
Contains no substances with biological values
8.1.3 Exposure limits at intended use*
No limits known
8.1.4 DNEL/ PNEC values
DNEL: No DNEL/DMEL/PNEC values on file
8.2 Limited and controlled exposition parameters
8.2.1 Appropriate engineering controls:
Ensure adequate ventilation. Provide suitable exhaust ventilation at the processing machines.
8.2.2 Personal safety equipment:
• General safety and hygiene measurements:
Avoid contact with eyes and skin. Don't eat and drink while working. Don´t smoke.
Breathing protection: In case of arise from steam/ aerosol use self containing breathing apparatus.
Hand protection: Glove material has to be impermeable and persistent for product/ mixture.
Choose glove material under observance of break time, permeation rate und degregation.
Glove material: Neopren, Butylkautschuk, Nitrilkautschuk following EN 374
Polychloropren -CR: Thickness > 0,5mm; Breakthrough time > 480 min
Nitrilkautschuk -NBR: Thickness > 0,35mm; Breakthrough time 480 min
Butylkautschuk -IIR: Thickness > 0,5mm; Breakthrough time > 480 min
Fluorkautschuk -FKM: Thickness > 0,4 mm; Breakthrough time > 480 min
Hint: Dispose contaminated gloves
Eye protection: Wear protection glasses
Body protection: One time clothing or chemistry kittle.
Protection gloves Protection glasses Protection clothing
8.2.3 Environmental exposure controls
No data available

Stability and reactivity

10 Stability and reactivity
10.1 Reactivity: No dangerous reactions if stored and handled appropriately.
10.2 Chemical stability:
• Thermal decomposition/ avoidable conditions:
Stable under appropriate conditions (see chapter 7). Avoid temperatures above boiling point.
10.3 Possibility of hazardous reactions: Reaction with isocyanates
10.4 Conditions to avoid: Temperatures above 1000C (see chapter 7)
10.5 Incompatible materials: Isocanates
10.6 Hazardous decomposition products: CO, CO2, NOx, NH3

Disposal considerations

13. Disposal considerations
13.1 Waste treatment methods:
• Product: In accordance with local authority regulations, take a special waste incineration plant.
• Contaminated packages:
If empty contaminated containers are recycled or disposed of, the receiver must be informed about
possible hazards.
Not contaminated packaging can be reused.