Registration Dossier

Administrative data

First-aid measures

• General information:
Immediately remove any clothing soiled by the product.
• After inhalation:
Supply fresh air; consult doctor in case of complaints.
• After skin contact:
Immediately rinse with water.
If skin irritation continues, consult a doctor.
• After eye contact:
Rinse opened eye for several minutes under running water.
Call a doctor immediately.
• After swallowing:
Call for a doctor immediately.
• Most important symptoms and effects, both acute and delayed
No further relevant information available.
• Indication of any immediate medical attention and special treatment needed
No further relevant information available.

Fire-fighting measures

• Extinguishing media
• Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray. water spray.
• For safety reasons unsuitable extinguishing agents:
Water with full jet
• Special hazards arising from the substance or mixture
Formation of toxic gases is possible during heating or in case of fire.
In case of fire, the following can be released:
Nitrogen oxides (NOx)
Carbon monoxide (CO)
Hydrogen cyanide (HCN)
• Advice for firefighters
• Protective equipment:
Wear self-contained respiratory protective device.

Accidental release measures

• Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Avoid contact with the eyes and skin.
• Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Prevent from spreading (e.g. by damming-in or oil barriers).
• Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).

Handling and storage

• Handling:
• Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Avoid contact with the eyes and skin.
Information about fire - and explosion protection:
No special measures required.
• Conditions for safe storage, including any incompatibilities
• Storage:
• Requirements to be met by storerooms and receptacles:
Prevent any seepage into the ground.
• Information about storage in one common storage facility:
Store away from oxidizing agents.
• Further information about storage conditions:
None.
• Specific end use(s)
No further relevant information available.

Transport information

Shippingopen allclose all
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all

Marine transport (IMDG)

Remarksopen allclose all
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

• Additional information about design of technical facilities:
No further data; see item 7.
• Control parameters
• is recommended :
Ingredients w ith limit values where monitoring at the workplace
67-56-1 methanol
OES
Short-term value 333 mg/m3
250 ppm
Long-term value 266 mg/m3
200 ppm
Sk, ILV
WEL
Short-term value 333 mg/m3
250 ppm
Long-term value 266 mg/m3
200 ppm
Sk
• Additional information:
The lists valid during the making were used as basis.
• Exposure controls
• Personal protective equipment:
• General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
Immediately remove all soiled and contaminated clothing
Avoid contact with the eyes and skin.
Safety shower at proximity.
Eye wash station at proximity.
• Respiratory protection: Use suitable respiratory protective device in case of insufficient ventilation.
• Protection of hands: The glove material has to be impermeable and resistant to the product/ the substance/ the
preparation. PVC gloves
• Eye protection: Tightly sealed goggles, face protection
• Body protection: Protective work clothing, boots

Stability and reactivity

• Reactivity
• Chemical stability
• Thermal decomposition / conditions to be avoided:
To avoid thermal decomposition do not overheat.
• Possibility of hazardous reactions
• Conditions to avoid
No further relevant information available.
• Incompatible materials:
No further relevant information available.
Dangerous reactions
Reacts with strong acids.
• Hazardous decomposition products:
Nitrogen oxides (NOx)
Carbon monoxide and carbon dioxide

Disposal considerations

• Waste treatment methods
• Recommendation
Must be specially treated adhering to official regulations.
Contact manufacturer for recycling information.
Do not empty into drains and avoid release to the environment. This product must be disposed in a certificated
hazardous or special waste collection point.
• Uncleaned packaging:
• Recommendation:
Disposal must be made according to official regulations.
Packaging may be reused or recycled after cleaning.
If recycling is not possible, dispose according to the local regulations.