Registration Dossier

Administrative data

First-aid measures

General notes
Take off immediately all contaminated clothing.
In all cases of doubt, or when symptoms persist, seek medical advice.

Following inhalation
Provide fresh air.
If breathing is irregular or stopped, immediately seek medical assistance and start first aid actions.
In case of respiratory tract irritation, consult a physician.

Following skin contact
Wash with plenty of soap and water.

Following eye contact
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Remove contact lenses, if present and easy to do. Continue rinsing.

Following ingestion
Rinse mouth. Do not induce vomiting.
Call a physician immediately.

Notes for the doctor
None

Fire-fighting measures

Suitable extinguishing media
water spray, alcohol resistant foam, fire extinguishing powder, carbon dioxide (CO2)

Unsuitable extinguishing media
water jet

Special hazards arising from the substance or mixture
None

Hazardous combustion products
carbon monoxide (CO), carbon dioxide (CO2)

Advice for firefighters
In case of fire and/or explosion do not breathe fumes.
Co-ordinate firefighting measures to the fire surroundings.
Do not allow firefighting water to enter drains or water courses.
Collect contaminated firefighting water separately.
Fight fire with normal precautions from a reasonable distance.
Keep containers cool with water spray.

Special protective equipment for firefighters
use suitable breathing apparatus






Accidental release measures

Personal precautions, protective equipment and emergency procedures

For non-emergency personnel
Remove persons to safety.
Ventilate affected area.
Wearing of suitable protective equipment to prevent any contamination of skin, eyes and personal clothing.

For emergency responders
Wear breathing apparatus if exposed to vapours/dust/spray/gases.

Environmental precautions
Keep away from drains, surface and ground water.
Retain contaminated washing water and dispose of it.

Methods and material for containment and cleaning up
Advices on how to clean up a spill
Collect spillage.
Absorbent material (e.g. sand, diatomaceous earth, acid binder, universal binder, sawdust, etc.).

Appropriate containment techniques
Use of adsorbent materials.

Other information relating to spills and releases
Place in appropriate containers for disposal.
Ventilate affected area.







Handling and storage

Precautions for safe handling
Measures to prevent fire as well as aerosol and dust generation
Use local and general ventilation.
Keep away from sources of ignition - No smoking.

Specific notes/details
none

Measures to protect the environment
Avoid release to the environment.

Advice on general occupational hygiene
Avoid contact with skin and eyes.
Avoid breathing gas/mist/vapours/spray.
Do not eat, drink and smoke in work areas.
Wash hands after use.
Preventive skin protection (barrier creams/ointments) is recommended.
Remove contaminated clothing and protective equipment before entering eating areas.

Conditions for safe storage, including any incompatibilities
Flammability hazards
none

Incompatible substances or mixtures
bases, oxidisers

Protect against external exposure, such as
heat, humidity

Consideration of other advice
Keep away from food, drink and animal feedingstuffs.
Keep container tightly closed and in a well-ventilated place.
Storage temperature 2 - 8°C.

Ventilation requirements
Provision of sufficient ventilation.

Packaging compatibilities
Only packagings which are approved (e.g. acc. to ADR) may be used.

Specific end use(s)
No information available.


Transport information

Land transport (ADR/RID)

UN number:
2810
Proper shipping name and description:
TOXIC LIQUID, ORGANIC, N.O.S.
Chemical name:
Diallyl maleate
Language:
English
Class:
6.1
Classification code:
T1
Packaging group:
III
Labels:
6.1
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
2810
Proper shipping name and description:
TOXIC LIQUID, ORGANIC, N.O.S.
Chemical name:
Diallylmaleate
Language:
English
Class:
6.1
Classification code:
T1
Packaging group:
III
Labels:
6.1
Remarksopen allclose all

Marine transport (IMDG)

UN number:
2810
Proper shipping name and description:
UN2810, TOXIC LIQUID, ORGANIC, N.O.S., (diallyl
maleate), 6.1, III
Chemical name:
Diallylmaleate
Class:
6.1
Packaging group:
III
EmS code:
F-A, S-A
Labels:
6.1
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
2810
Proper shipping name and description:
UN2810, Toxic liquid, organic, n.o.s., (diallyl
maleate), 6.1, III
Chemical name:
Diallylmaleate
Class:
6.1
Packaging group:
III
Labels:
6.1
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Appropriate engineering controls
General ventilation.

Individual protection measures (personal protective equipment)
Eye/face protection
Wear eye/face protection.

Hand protection
Wear suitable gloves.
Chemical protection gloves are suitable, which are tested according to EN 374.
Check leak-tightness/impermeability prior to use.
In the case of wanting to use the gloves again, clean them before taking off and air them well.
For special purposes, it is recommended to check the resistance to chemicals of the protective gloves
mentioned above together with the supplier of these gloves.

IIR: isobutene-isoprene (butyl) rubber ≥ 0,5 mm >480 minutes (permeation: level 6)
FKM: fluoro-elastomer ≥ 0,4 mm >480 minutes (permeation: level 6)
CR: chloroprene (chlorobutadiene) rubber ≥ 0,5 mm >240 minutes (permeation: level 5)

Respiratory protection
In case of inadequate ventilation wear respiratory protection.

Environmental exposure controls
Use appropriate container to avoid environmental contamination.
Keep away from drains, surface and ground water.

Stability and reactivity

Reactivity
This material is not reactive under normal ambient conditions.

Chemical stability
The material is stable under normal ambient and anticipated storage and handling conditions of temperature
and pressure.

Possibility of hazardous reactions
No known hazardous reactions.

Conditions to avoid
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Incompatible materials
bases, oxidisers

Hazardous decomposition products
Reasonably anticipated hazardous decomposition products produced as a result of use, storage, spill
and heating are not known.

Disposal considerations

Waste treatment methods
This material and its container must be disposed of as hazardous waste.

Sewage disposal-relevant information
Do not empty into drains.

Waste treatment of containers/packagings
It is a dangerous waste; only packagings which are approved (e.g. acc. to ADR) may be used.
Handle contaminated packages in the same way as the substance itself.

Remarks
Please consider the relevant national or regional provisions.