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Physical & Chemical properties

Flash point

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Reference
Endpoint:
flash point of flammable liquids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
from 2016-01-29 to 2016-02-09
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to
Guideline:
EU Method A.9 (Flash-Point)
Version / remarks:
2008
Deviations:
no
Qualifier:
according to
Guideline:
ASTM D93 (Standard test methods for flash point by pensky-martens closed cup tester)
Deviations:
no
Qualifier:
according to
Guideline:
other: ASTM D6450 - 12e1 Standard Test Method for Flash Point by Continuously Closed Cup (CCCFP) Tester
Deviations:
no
Qualifier:
according to
Guideline:
other: ASTM D7094 – 12e1 Standard Test Method for Flash Point by Modified Continuously Closed Cup (MCCCFP) Tester
Deviations:
no
Qualifier:
according to
Guideline:
EPA OPPTS 830.6315 (Flammability)
Version / remarks:
1996
Deviations:
no
Qualifier:
according to
Guideline:
other: UN Handbook “Recommendations on the Transport of Dangerous Goods - Manual of Tests and Criteria” Rev. 6, 2015, Method 32.4 “Test methods used for determining flash point and viscosity”
Version / remarks:
2015
Deviations:
no
GLP compliance:
yes (incl. certificate)
Type of method:
closed cup
Flash point apparatus:
Pensky-Martens apparatus
Key result
Flash point:
116 °C
Atm. press.:
1 013.25 hPa

The flash point of Dodecane control was determined to be 80.2 °C, hardly deviating from the literature value (78.6 °C, ASTM D 7094, Table X1.1). For the determination of the initial temperature of flash point measurement a screen test was performed with the test item. The sample was heated from 30 °C to 200 °C using 5.5 °C/min heating rate. Based on this preliminary test the flash point of the test item was determined to be: 118.3 °C. In the course of the study three subsequent tests with the test item were carried out. The measured flash points of the test item were: 116.3 °C, 116.3 °C and 115.3 °C resulting a mean value: 116 °C at 101.3 kPa. The repeatability criterion was met because the maximum difference between replicate determinations was less than 2 °C.

Interpretation of results:
GHS criteria not met
Conclusions:
The flash point of the test item was determined to be: 116 °C at 101.3 kPa.
Executive summary:

A study was conducted according to Regulation (EC) No 440/2008 method A.9, OPPTS 830.6513, ASTM D93, ASTM D6450 and ASTM DT7094 to determine the flash point of the test item using a closed cup method with Pensky-Martens apparatus. For the test about 2 mL of the test item were filled in the cup. The test was performed twice. The measured flash point at atmospheric pressure was corrected to a standard pressure of 1013 hPa. The flash point was determined to be 116 °C at 101.3 kPa.

Description of key information

The flash point of the test item was determined to be: 116 °C at 101.3 kPa.

Key value for chemical safety assessment

Flash point at 101 325 Pa:
116 °C

Additional information

A study was conducted according to Regulation (EC) No 440/2008 method A.9, OPPTS 830.6513, ASTM D93, ASTM D6450 and ASTM DT7094 to determine the flash point of the test item using a closed cup method with Pensky-Martens apparatus. For the test about 2 mL of the test item were filled in the cup. The test was performed twice. The measured flash point at atmospheric pressure was corrected to a standard pressure of 1013 hPa. The flash point was determined to be 116 °C at 101.3 kPa.