Registration Dossier
Registration Dossier
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EC number: 947-152-2 | CAS number: -
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
In case of inhalation
- If breathed in, move person into fresh air.
- Victim to lie down in the recovery position, cover and keep him warm.
- Oxygen or artificial respiration if needed.
- Immediate medical attention is required.
In case of skin contact
- Remove clothes carefully
- Wash off immediately with plenty of water.
- Immediately apply calcium gluconate gel 2.5% and massage into the affected area using rubber gloves; continue to massage while repeatedly applying gel until 15 minutes after pain is relieved.
- Call a physician immediately.
In case of eye contact
- Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
- Rinse the eyes with a calcium gluconate 1% solution in physiological serum (10 ml of calcium gluconate 10% in 90 ml of physiological serum)
- Immediate medical attention is required.
In case of ingestion
- Drink 1 or 2 glasses of water.
- Give to drink milk of magnesia
- Do NOT induce vomiting.
- Call a physician immediately.
Most important symptoms and effects, both acute and delayed
In case of inhalation
Effects
- Fatal if inhaled.
- Corrosive to the respiratory tract.
Symptoms
- Breathing difficulties
- Cough
- Headache
In case of skin contact
Effects
- Causes severe burns.
Symptoms
- Redness
- Irritation
- Burn
In case of eye contact
Effects
- Causes serious eye damage.
Symptoms
- Redness
- Pain
- Lachrymation
In case of ingestion
Effects
- Ingestion causes burns of the upper digestive and respiratory tracts.
Symptoms
- Abdominal pain
- Nausea
- Vomiting
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician
- If breathed in, move person into fresh air.
- Immediately apply calcium gluconate gel 2.5% and massage into the affected area using rubber gloves; continue to massage while repeatedly applying gel until 15 minutes after pain is relieved.
- Keep under medical supervision for at least 48 hours.
In case of inhalation
- If breathed in, move person into fresh air.
- Victim to lie down in the recovery position, cover and keep him warm.
- Oxygen or artificial respiration if needed.
- Immediate medical attention is required.
In case of skin contact
- Remove clothes carefully
- Wash off immediately with plenty of water.
- Immediately apply calcium gluconate gel 2.5% and massage into the affected area using rubber gloves; continue to massage while repeatedly applying gel until 15 minutes after pain is relieved.
- Call a physician immediately.
In case of eye contact
- Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
- Rinse the eyes with a calcium gluconate 1% solution in physiological serum (10 ml of calcium gluconate 10% in 90 ml of physiological serum)
- Immediate medical attention is required.
In case of ingestion
- Drink 1 or 2 glasses of water.
- Give to drink milk of magnesia
- Do NOT induce vomiting.
- Call a physician immediately.
Most important symptoms and effects, both acute and delayed
In case of inhalation
Effects
- Fatal if inhaled.
- Corrosive to the respiratory tract.
Symptoms
- Breathing difficulties
- Cough
- Headache
In case of skin contact
Effects
- Causes severe burns.
Symptoms
- Redness
- Irritation
- Burn
In case of eye contact
Effects
- Causes serious eye damage.
Symptoms
- Redness
- Pain
- Lachrymation
In case of ingestion
Effects
- Ingestion causes burns of the upper digestive and respiratory tracts.
Symptoms
- Abdominal pain
- Nausea
- Vomiting
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician
- If breathed in, move person into fresh air.
- Immediately apply calcium gluconate gel 2.5% and massage into the affected area using rubber gloves; continue to massage while repeatedly applying gel until 15 minutes after pain is relieved.
- Keep under medical supervision for at least 48 hours.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media
- Foam
- Dry chemical
- Carbon dioxide (CO2)
- powder
Special hazards arising from the substance or mixture
Specific hazards during firefighting
- The product is not flammable.
- Not explosive
- In case of fire hazardous decomposition products may be produced such as:
Hazardous combustion products:
- Gaseous hydrogen fluoride (HF).
- Fluorophosgene
- Carbon dioxide (CO2)
- Carbon monoxide
- Sulphur oxides
Advice for firefighters
Special protective equipment for firefighters
- Wear self-contained breathing apparatus and protective suit.
- When intervention in close proximity wear acid resistant over suit.
Further information
- Evacuate personnel to safe areas.
- Approach from upwind.
- Protect intervention team with a water spray as they approach the fire.
- Keep containers and surroundings cool with water spray.
- Keep product and empty container away from heat and sources of ignition.
Suitable extinguishing media
- Foam
- Dry chemical
- Carbon dioxide (CO2)
- powder
Special hazards arising from the substance or mixture
Specific hazards during firefighting
- The product is not flammable.
- Not explosive
- In case of fire hazardous decomposition products may be produced such as:
Hazardous combustion products:
- Gaseous hydrogen fluoride (HF).
- Fluorophosgene
- Carbon dioxide (CO2)
- Carbon monoxide
- Sulphur oxides
Advice for firefighters
Special protective equipment for firefighters
- Wear self-contained breathing apparatus and protective suit.
- When intervention in close proximity wear acid resistant over suit.
Further information
- Evacuate personnel to safe areas.
- Approach from upwind.
- Protect intervention team with a water spray as they approach the fire.
- Keep containers and surroundings cool with water spray.
- Keep product and empty container away from heat and sources of ignition.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel
- Prevent further leakage or spillage if safe to do so.
Advice for emergency responders
- Evacuate personnel to safe areas.
- Ensure adequate ventilation.
- Cover the spreading liquid with foam in order to slow down the evaporation.
- Keep away from open flames, hot surfaces and sources of ignition.
Environmental precautions
- Should not be released into the environment.
- Do not flush into surface water or sanitary sewer system.
6.3 Methods and materials for containment and cleaning up
- Soak up with inert absorbent material.
- Suitable material for picking up.
- Dry sand
- Earth
- Shovel into suitable container for disposal.
Reference to other sections
- Refer to protective measures listed in sections 7 and 8 of SDS
Advice for non-emergency personnel
- Prevent further leakage or spillage if safe to do so.
Advice for emergency responders
- Evacuate personnel to safe areas.
- Ensure adequate ventilation.
- Cover the spreading liquid with foam in order to slow down the evaporation.
- Keep away from open flames, hot surfaces and sources of ignition.
Environmental precautions
- Should not be released into the environment.
- Do not flush into surface water or sanitary sewer system.
6.3 Methods and materials for containment and cleaning up
- Soak up with inert absorbent material.
- Suitable material for picking up.
- Dry sand
- Earth
- Shovel into suitable container for disposal.
Reference to other sections
- Refer to protective measures listed in sections 7 and 8 of SDS
Handling and storage
Precautions for safe handling
- Ensure adequate ventilation.
- Keep away from heat and sources of ignition.
- Use personal protective equipment.
- To avoid thermal decomposition, do not overheat.
Hygiene measures
- Ensure that eyewash stations and safety showers are close to the workstation location.
- When using do not eat, drink or smoke.
- Wash hands before breaks and at the end of workday.
- Handle in accordance with good industrial hygiene and safety practice.
Conditions for safe storage, including any incompatibilities
Technical measures/Storage conditions
- Keep in a well-ventilated place.
- Keep away from heat and sources of ignition.
- Avoid moisture.
- Keep away from combustible material.
- Keep away from incompatible products
- Provide tight electrical equipment well protected against corrosion.
- Refer to protective measures listed in sections 7 and 8.
Packaging material
Suitable material
- Steel
- Plastic materials.
Specific end use(s)
- Contact your supplier for additional information
- Ensure adequate ventilation.
- Keep away from heat and sources of ignition.
- Use personal protective equipment.
- To avoid thermal decomposition, do not overheat.
Hygiene measures
- Ensure that eyewash stations and safety showers are close to the workstation location.
- When using do not eat, drink or smoke.
- Wash hands before breaks and at the end of workday.
- Handle in accordance with good industrial hygiene and safety practice.
Conditions for safe storage, including any incompatibilities
Technical measures/Storage conditions
- Keep in a well-ventilated place.
- Keep away from heat and sources of ignition.
- Avoid moisture.
- Keep away from combustible material.
- Keep away from incompatible products
- Provide tight electrical equipment well protected against corrosion.
- Refer to protective measures listed in sections 7 and 8.
Packaging material
Suitable material
- Steel
- Plastic materials.
Specific end use(s)
- Contact your supplier for additional information
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN 3390
Shipping information
- Proper shipping name and description:
- TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. (Reaction mass of difluoro(fluorosulphonyl)acetyl fluoride and 3,3,4,4-tetrafluoro-1,2-oxathietane 2,2-dioxide)
- Labels:
- 6.1 (8)
Special provisions / remarks
- Special provisions:
- Special precautions for user
Hazard Identification Number: 668
Tunnel restriction code (C/D)
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- UN 3390
Shipping information
- Proper shipping name and description:
- TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. (Reaction mass of difluoro(fluorosulphonyl)acetyl fluoride and 3,3,4,4-tetrafluoro-1,2-oxathietane 2,2-dioxide)
- Labels:
- 6.1 (8)
Special provisions / remarks
- Remarks:
- Special precautions for user
Hazard Identification Number: 668
Marine transport (UN RTDG/IMDG)
- UN number:
- UN 3390
Shipping information
- Proper shipping name and description:
- TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. (Reaction mass of difluoro(fluorosulphonyl)acetyl fluoride and 3,3,4,4-tetrafluoro-1,2-oxathietane 2,2-dioxide)
- Labels:
- 6.1 (8)
Special provisions / remarks
- Remarks:
- Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
No data available
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- UN 3390
Shipping information
- Proper shipping name and description:
- Not permitted for transport
Special provisions / remarks
- Remarks:
- Packing instruction (cargo aircraft) Not permitted for transport
Packing instruction (passenger aircraft) Not permitted for transport
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Exposure controls
Control measures
Engineering measures
- Ensure adequate ventilation.
- Refer to protective measures listed in sections 7 and 8.
- Apply technical measures to comply with the occupational exposure limits.
Individual protection measures
Respiratory protection
- Use respirator when performing operations involving potential exposure to vapour of the product.
- The filter class for the respirator must be suitable for the maximum expected contaminant concentration (gas/vapour/aerosol/particulates) that may arise when handling the product. If this concentration is exceeded, self-contained breathing apparatus must be used.
- Use only respiratory protection that conforms to international/ national standards.
- Remove respiratory and skin/eye protection only after vapours have been cleared from the area.
Hand protection
- Neoprene gloves
- Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact).
Eye protection
- Tightly fitting safety goggles
Skin and body protection
- Wear work overall and safety shoes.
- If risk of contact: wear chemically resistant over suits.
Hygiene measures
- Ensure that eyewash stations and safety showers are close to the workstation location.
- When using do not eat, drink or smoke.
- Wash hands before breaks and at the end of workday.
- Handle in accordance with good industrial hygiene and safety practice.
Environmental exposure controls
- Dispose of rinse water in accordance with local and national regulations.
Control measures
Engineering measures
- Ensure adequate ventilation.
- Refer to protective measures listed in sections 7 and 8.
- Apply technical measures to comply with the occupational exposure limits.
Individual protection measures
Respiratory protection
- Use respirator when performing operations involving potential exposure to vapour of the product.
- The filter class for the respirator must be suitable for the maximum expected contaminant concentration (gas/vapour/aerosol/particulates) that may arise when handling the product. If this concentration is exceeded, self-contained breathing apparatus must be used.
- Use only respiratory protection that conforms to international/ national standards.
- Remove respiratory and skin/eye protection only after vapours have been cleared from the area.
Hand protection
- Neoprene gloves
- Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact).
Eye protection
- Tightly fitting safety goggles
Skin and body protection
- Wear work overall and safety shoes.
- If risk of contact: wear chemically resistant over suits.
Hygiene measures
- Ensure that eyewash stations and safety showers are close to the workstation location.
- When using do not eat, drink or smoke.
- Wash hands before breaks and at the end of workday.
- Handle in accordance with good industrial hygiene and safety practice.
Environmental exposure controls
- Dispose of rinse water in accordance with local and national regulations.
Stability and reactivity
Reactivity
- Reacts on contact with humidity in the air or with water to release of hydrofluoric acid.
Chemical stability
- Stable under recommended storage conditions.
Possibility of hazardous reactions
- No dangerous reaction known under conditions of normal use.
Conditions to avoid
- Exposure to moisture
- Keep away from flames and sparks.
- To avoid thermal decomposition, do not overheat.
Incompatible materials
- Water
- Strong bases
- Strong acids
- Strong oxidizing agents
- Alkali metals
- alkaline hydroxides
- Dimethyl sulphoxide
Hazardous decomposition products
- Gaseous hydrogen fluoride (HF).
- Fluorophosgene
- Carbon dioxide (CO2)
- Carbon monoxide
- Sulphur oxides
- Reacts on contact with humidity in the air or with water to release of hydrofluoric acid.
Chemical stability
- Stable under recommended storage conditions.
Possibility of hazardous reactions
- No dangerous reaction known under conditions of normal use.
Conditions to avoid
- Exposure to moisture
- Keep away from flames and sparks.
- To avoid thermal decomposition, do not overheat.
Incompatible materials
- Water
- Strong bases
- Strong acids
- Strong oxidizing agents
- Alkali metals
- alkaline hydroxides
- Dimethyl sulphoxide
Hazardous decomposition products
- Gaseous hydrogen fluoride (HF).
- Fluorophosgene
- Carbon dioxide (CO2)
- Carbon monoxide
- Sulphur oxides
Disposal considerations
Waste treatment methods
Product Disposal
- Dispose of in accordance with the European Directives on waste and hazardous waste.
Advice on cleaning and disposal of packaging
- Empty containers can be landfilled, when in accordance with the local regulations.
Product Disposal
- Dispose of in accordance with the European Directives on waste and hazardous waste.
Advice on cleaning and disposal of packaging
- Empty containers can be landfilled, when in accordance with the local regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
