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Physical & Chemical properties

Boiling point

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Administrative data

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Reference
Endpoint:
boiling point
Type of information:
experimental study
Adequacy of study:
key study
Study period:
October 16, 2017 - October 18, 2017
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
OECD Guideline 103 (Boiling Point)
Deviations:
no
Qualifier:
according to guideline
Guideline:
EU Method A.2 (Boiling Temperature)
Deviations:
no
GLP compliance:
no
Type of method:
differential scanning calorimetry
Key result
Decomposition:
yes
Decomp. temp.:
> 420 °C

Two DSC measurements in aluminium crucibles with a hole showed an endothermal effect in the temperature range of 420 – 490 °C. After the measurements the test item was a black residue. The mass loss after the DSC measurements amounted to 22 % and to 30 %, respectively.

The results of the DSC measurements are summarized in Table1.

Table1: DSC measurements

Ident No.

Test item /

mg

Starting temperature /

°C

Final test temperature /

°C

Temperature range /

°C

Crucible

Observations after the measurement

36637

6.29

25

500

420 – 470
(endothermal)

Aluminium with a hole

Test item was a black residue after the measurement; mass loss: 22 %

36640

12.48

25

500

420 – 495
(endothermal)

Aluminium with a hole

Test item was a black residue after the measurement; mass loss: 30 %

Under consideration of the results from the DSC measurements it was concluded that the test item had no melting point and no boiling point at atmospheric conditions. Decomposition started at approx. 420 °C.

Executive summary:

The test item had no melting point and no boiling point at atmospheric conditions. Decomposition started at approx. 420 °C.

Description of key information

The test item had no melting point and no boiling point at atmospheric conditions. Decomposition started at approx. 420 °C.

Key value for chemical safety assessment

Additional information