dinotefuran (ISO); 1-methyl-2-nitro-3-(tetrahydro-3-furylmethyl)guanidine

Guidance on Safe Use

First-aid measures

Ingestion

Rinse mouth with water. Get medical attention immediately. Induce vomiting as directed by medical personnel. Never give anything by mouth to an unconscious or convulsing person.

Inhalation

If you feel unwell, move to fresh air immediately. Get medical attention if cough or other symptoms develop. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.

Skin Contact

Immediately remove contaminated clothing and shoes. Flush skin and clean off with large amounts of water. Get medical attention if symptoms develop.

Eye Contact

Immediately flush with plenty of water. Part eyelids with fingers to assure complete flushing. Check for and remove contact lenses if easily possible. Get medical attention if irritation persists.

Fire-fighting measures

EXTINGUISHING MEDIA

Suitable Extinguishing Media Foam, water.

Unsuitable Extinguishing Media

CO2 or dry chemical are not effective for extinguish.

SPECIAL HAZARDS ARISING FROM THE SUBSTANCE

General Hazard:

Emits toxic fumes in fire condition.

This product is not expected to burn or explode in normal conditions, but will burn violently if involved in fire. Dinotefuran is self-reactive under high temperatures. Exposure to heat may promote violent decomposition.

Hazardous Combustion Products

Nitrogen oxides.

ADVICE FOR FIREFIGHTERS

Firefighting Instructions:

Keep  unnecessary  and  unprotected  personnel  away.  Shut  off  supply if  possible. Remove  containers to safe place if possible.

Keep containers and surroundings cool by spraying with water. Fight fire from an upwind position.

Firefighting Equipment:

Respiratory and eye protection is required for firefighting personnel.

Full protective equipment and self-contained breathing apparatus (SCBA) should be used for all indoor fires and any significant outdoor fires

Accidental release measures

PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES

Warn and evacuate in the neighborhood as necessary. Keep unnecessary and unprotected personnel away. Wear appropriate personal protective equipment as specified in Section 8. Remove all sources of ignition. Stop leak if possible without personal risk.

ENVIRONMENTAL PRECAUTIONS

Do not let this product enter the environment.

METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP

Use non-sparking tools and equipment.

Scoop or sweep up the spilled product and place it in a disposal container. Use appropriate tools. Avoid dispersal of dust in the air.

Handling and storage

PRECAUTIONS FOR SAFE HANDLING

Technical Measures:

Use only with adequate ventilation.

Where there may be potential of fire or explosion hazard, use explosion-proof electrical equipment and take precautions against build-up of electrostatic charges.

Wear appropriate personal protective equipment. Keep away from heat, sparks, open flames and hot surfaces.

Precautions:

Handle with care. Do not breathe dust. Avoid contact with eyes, skin and clothing. Take precautionary measures against static discharge.

Advice on general occupational hygiene

Provide hand and eye wash station near work area. Wash hands thoroughly after use. Take off contaminated protective equipment before entering rest areas. Do not eat, drink or smoke when using this product.

CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES

Storage Conditions:

Keep away from heat, flame, all sources of ignition，and combustible material. Store in a cool, dark and well ventilated area. Keep container tightly closed and sealed until ready for use.

Do not contaminate other pesticides, fertilizers, water, foodstuffs or feed by storage and disposal.

Packaging Materials:

Metal drum or conductive container.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

UN3077

Shipping information

Proper shipping name and description:

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.

Chemical name:

Dinotefuran

Language:

English

Labels:

9

Special provisions / remarks

Special provisions:

274
335
375
601

Inland waterway transport (UN RTDG/ADN(R))

UN number:

UN3077

Shipping information

Proper shipping name and description:

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.

Chemical name:

Dinotefuran

Language:

English

Labels:

9

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

UN3077

Shipping information

Proper shipping name and description:

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.

Chemical name:

Dinotefuran

Labels:

9

Marine pollutant

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

UN3077

Shipping information

Proper shipping name and description:

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.

Chemical name:

Dinotefuran

Labels:

9

Remarks

SpecialProvisions

Exposure controls / personal protection

Appropriate Engineering Controls:

Provide general ventilation. Using closed system or local exhaust ventilation is recommended. Provide safety shower and eye wash station near work area.

Personal Protection:

Eye/face protection:       Safety glasses, goggles. Skin Protection:

Hand protection:       Chemical resistant gloves.

Body Protection:       Safety helmet, protective clothing, safety boots.

Respiratory protection:       Dust respirator

Stability and reactivity

STABILITY AND REACTIVITY

Reactivity :Risk of dust explosion.

Chemical stability: Stable under normal conditions.

Possibility of hazardous reactions:  Dinotefuran is self-reactive under high temperatures. Exposure to heat may promote violent decomposition.

Conditions to avoid:Exposure to heat, ignition sources.

Incompatible materials: Strong oxidizing agents

Hazardous decompostion products: Nitrogen oxides

Disposal considerations

WASTE TREATMENT METHODS

Waste from Residues:

Waste must be disposed of in accordance with federal, state, local, national and international regulations.

Contaminated Packaging:

Empty the container completely before disposal.