Registration Dossier

Classification & Labelling & PBT assessment

GHS

General Information

Name:
Benzene, tetrapropylene-, distn. residues, sulfonated, sodium salts
Implementation:
EU
Remarks:

The classification and labelling as sensitiser for benzene, tetrapropylene-, distn. residues, sulfonated, sodium salts (with a TBN of 3) is based on the LLNA positive results. In addition, the sensitisation weight of evidence for this category of sulfonates, is based on a series of studies conducted according to the Modified Buehler design and on the results of numerous skin sensitisation animal studies with low and high TBN calcium sulfonates. Results of Human Repeat Insult Test (HRIPT) with low and high TBN calcium sulfonates have also been considered (refer to the respective section of the IUCLID file). In accordance with EU CLP Regulation (EC) No. 1272/2008, classification is required for low TBN sodium sulfonates (TBN < 300) with a specific concentration limit of 10%, and classification is not required for high TBN sodium sulfonates (TBN ≥ 300).

Classificationopen allclose all

Explosives
Reason for no classification:
data conclusive but not sufficient for classification
Flammable gases and chemically unstable gases
Reason for no classification:
data conclusive but not sufficient for classification
Aerosols
Reason for no classification:
data conclusive but not sufficient for classification
Oxidising gases
Reason for no classification:
data conclusive but not sufficient for classification
Gases under pressure
Reason for no classification:
data conclusive but not sufficient for classification
Flammable liquids
Reason for no classification:
data conclusive but not sufficient for classification
Flammable solids
Reason for no classification:
data conclusive but not sufficient for classification
Self-reactive substances and mixtures
Reason for no classification:
data conclusive but not sufficient for classification
Pyrophoric liquids
Reason for no classification:
data conclusive but not sufficient for classification
Pyrophoric solids
Reason for no classification:
data conclusive but not sufficient for classification
Self-heating substances and mixtures
Reason for no classification:
data conclusive but not sufficient for classification
Substances and mixtures which in contact with water emit flammable gases
Reason for no classification:
data conclusive but not sufficient for classification
Oxidising liquids
Reason for no classification:
data conclusive but not sufficient for classification
Oxidising solids
Reason for no classification:
data conclusive but not sufficient for classification
Organic peroxides
Reason for no classification:
data conclusive but not sufficient for classification
Corrosive to metals
Reason for no classification:
data conclusive but not sufficient for classification
Desensitized explosives
Reason for no classification:
data lacking
Acute toxicity - oral
Reason for no classification:
data conclusive but not sufficient for classification
Acute toxicity - dermal
Reason for no classification:
data conclusive but not sufficient for classification
Acute toxicity - inhalation
Reason for no classification:
data lacking
Skin corrosion / irritation
Hazard category:
Skin Irrit. 2
Hazard statement:
H315: Causes skin irritation.
Serious eye damage / eye irritation
Reason for no classification:
data conclusive but not sufficient for classification
Respiratory sensitisation
Reason for no classification:
data lacking
Skin sensitisation
Hazard category:
Skin Sens. 1B
Hazard statement:
H317: May cause an allergic skin reaction.
Aspiration hazard
Reason for no classification:
data conclusive but not sufficient for classification
Reproductive toxicity
Reason for no classification:
data conclusive but not sufficient for classification
Effects on or via lactation
Reason for no classification:
data lacking
Germ cell mutagenicity
Reason for no classification:
data conclusive but not sufficient for classification
Carcinogenicity
Reason for no classification:
data lacking
1. Specific target organ toxicity - single
Reason for no classification:
data conclusive but not sufficient for classification
1. Specific target organ toxicity - repeated
Reason for no classification:
data lacking
1.
Concentration range (%):
> 10 - <= 100
Hazard categories:
Skin Sens. 1B
Hazardous to the aquatic environment (acute / short-term)
Reason for no classification:
data conclusive but not sufficient for classification
Hazardous to the aquatic environment (long-term)
Reason for no classification:
data conclusive but not sufficient for classification
Hazardous to the ozone layer
Reason for no classification:
data conclusive but not sufficient for classification

Labelling

Signal word:
Warning

Hazard pictogram

GHS07: exclamation mark

Hazard statements

H315: Causes skin irritation.
H317: May cause an allergic skin reaction.

Precautionary statements

P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P264: Wash ... thoroughly after handling.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
P362+P364: Take off contaminated clothing and wash it before reuse.
P302+P352: IF ON SKIN: Wash with plenty of water/…
P332+P313: If skin irritation occurs: Get medical advice/attention.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P321: Specific treatment (see ... on this label).
P332: If skin irritation occurs:
P501: Dispose of contents/container to ...

Notes