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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
explosive properties of explosives
Type of information:
experimental study
Adequacy of study:
key study
Study period:
from 18 Sep 2017 to 02 Nov 2017
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2018
Report date:
2018

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
other: UN Manual of Tests and Criteria, Appendix 6 "Screening procedures" -Screening procedures for substances which may have explosive properties
Version / remarks:
2015
Deviations:
no
GLP compliance:
yes

Test material

Constituent 1
Chemical structure
Reference substance name:
Bis(dipentylphenyl) hydrogen phosphate
EC Number:
264-629-4
EC Name:
Bis(dipentylphenyl) hydrogen phosphate
Cas Number:
64051-38-3
Molecular formula:
C32H51O4P
IUPAC Name:
bis(2,3-dipentylphenyl) hydrogen phosphate
Test material form:
liquid: viscous
Details on test material:
- Physical appearance: dark brown viscous liquid
- Storage conditions: at room temperature
Specific details on test material used for the study:
The substance is an organic substance.

Results and discussion

Small-scale preliminary testsopen allclose all
Key result
Parameter:
other: exothermic decomposition energy [J/g]
Remarks on result:
not determinable
Remarks:
No exothermic decomposition at temperatures of < 550°C.
Key result
Parameter:
other: onset of the exothermic decomposition [°C]
Remarks on result:
not determinable

Any other information on results incl. tables

Representative  DSC curve: see picture below.

With both experiments, an endothermic peak between 225°C and 400°C was observed. It was due to reaction and/or decomposition of the test item.

After the experiments, a brown/black residue remained at the bottom of the sample container. The sample container had expanded due to pressure. It indicated reaction and/or decomposition of the test item during the test.

Applicant's summary and conclusion

Interpretation of results:
other: not classified under CLP or GHS
Conclusions:
The test item has no explosive properties.

Executive summary:

The DSC screening test for explosiveness was determined in a GLP study. From duplicate measurements it was concluded that the substance does not decomposes exothermically at temperatures of < 550°C.  Therefore it could safely be concluded that the exothermic decomposition energy is < 500 J/g and the onset of exothermic decomposition is < 500°C.

The acceptance procedure for Class 1 explosives do not have to be applied accoring to the UN Manual of Tests and Criteria, Appendix 6 "Screening procedures" -Screening procedures for substances which may have explosive properties. The substance has no explosive properties.