Registration Dossier

Administrative data

First-aid measures

General information:
Take persons to a safe place. Observe self-protection for first aid. Always seek medical advice in the event of contact with this
substance.
After contact with the eyes:
Rinse immediately with plenty of water for 10-15 minutes. Keep eyelids well open to rinse the whole eye surface and eyelids with
water. Seek medical advice immediately and clearly identify substance. Continue to bathe eyes during transport to medical
practitioner.
After contact with the skin:
Remove contaminated clothes at once. Wash off with plenty of water or water and soap immediately for 10-15 minutes. In serious
cases, use emergency shower immediately. Seek medical advice immediately and clearly identify substance.
After inhalation:
Keep the patient calm. If unconscious place in stable sideways position. Protect against loss of body heat. If breathing stops,
administer artificial respiration. Seek medical advice immediately and clearly identify substance.
After swallowing:
If conscious, give several small portions of water to drink. Do not induce vomiting. Seek medical advice immediately and clearly
identify substance.
Most important symptoms and effects, both acute and delayed
Any relevant information can be found in other parts of this section.
Indication of any immediate medical attention and special treatment needed
After inhalation: treat as early as possible using cortisone spray. Medical checks necessary up to a latency period of at least 24
hours. In the event of 1st degree burns use corticoid-externa. In the case of 2nd degree burns, use symptomatic treatment.
Further toxicology information must be observed.

Fire-fighting measures

Extinguishing media
Suitable extinguishing media:
water mist , extinguishing powder , alcohol-resistant foam , carbon dioxide , sand .
Extinguishing media which must not be used for safety reasons:
water spray , water jet .
Special hazards arising from the substance or mixture
Hazardous combustion products: nitrous gases .
Advice for firefighters
Special protective equipment for fire fighting:
Use respiratory protection independent of recirculated air.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment. Keep unprotected persons away. Avoid contact with eyes and skin. Avoid
inhaling mists and vapours. If material is released indicate risk of slipping.
Environmental precautions
Prevent material from entering surface waters, drains or sewers and soil. Contain any fluid that runs out using suitable material
(e.g. earth). Retain contaminated water/extinguishing water. Dispose of in prescribed marked containers.
Methods and material for containment and cleaning up
Do not flush away with water. For small amounts: Absorb with a liquid binding material such as diatomaceous earth and dispose
of according to local/state/federal regulations. Contain larger amounts and pump up into suitable containers. Clean any slippery
coating that remains using a detergent / soap solution or another biodegradable cleaner. Exhaust vapours.
Further information:
Eliminate all sources of ignition.
Reference to other sections
Relevant information in other sections has to be considered. This applies in particular for information given on personal protective
equipment and on disposal.

Handling and storage

Precautions for safe handling:
Avoid formation of aerosols. In case of aerosol formation special protective measures are required (exhausting by suction,
respiratory protection). Ensure adequate ventilation. Keep away from incompatible substances.
Spilled substance increases risk of slipping.
Precautions against fire and explosion:
Product can separate methanol. Flammable vapors may accumulate and form explosive mixtures with air in containers, process
vessels, including partial, empty and uncleaned containers and vessels, or other enclosed spaces. Keep away from sources of
ignition and do not smoke. Take precautionary measures against electrostatic charging. Cool endangered containers with water.
Conditions for safe storage, including any incompatibilities
Conditions for storage rooms and vessels:
Advice for storage of incompatible materials:
Avoid contact with acids.
Further information for storage:
Protect against moisture. Keep container tightly closed and store in a cool, well ventilated place.

Transport information

Land transport (ADR/RID)

UN number:
2734
Proper shipping name and description:
AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S.
Chemical name:
((Aminomethyl)dimethoxy(methyl)silane)
Class:
8 (3)
Packaging group:
II
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
2734
Proper shipping name and description:
Amines, liquid, corrosive, flammable, n.o.s. ((Aminomethyl)dimethoxy(methyl)silane)
Chemical name:
(Aminomethyl)dimethoxy(methyl)silane
Class:
8 (3)
Packaging group:
II
Remarksopen allclose all

Marine transport (IMDG)

UN number:
2734
Proper shipping name and description:
Amines, liquid, corrosive, flammable, n.o.s.
Chemical name:
(Aminomethyl)dimethoxy(methyl)silane
Class:
8 (3)
Packaging group:
II
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
2734
Proper shipping name and description:
Amines, liquid, corrosive, flammable, n.o.s.
Chemical name:
(Aminomethyl)dimethoxy(methyl)silane
Class:
8 (3)
Packaging group:
II
Remarksopen allclose all

Additional transport information

Additional transport information
Bulk transport in tankers is not intended.

Exposure controls / personal protection

Control parameters
Maximum airborne concentrations at the workplace:
67-56-1 Methanol AGW 270,0 mg/m3, 200,0 ppm
Methanol (CAS no. 67-56-1): Refer to Technical Rules for Hazardous Substances "TRGS 900" for more details on the German
AGW.
BAT-Value:
67-56-1 METHANOL 30 mg/l URIN Time C,B

Exposure controls
Exposure in the work place limited and controlled
General protection and hygiene measures:
Avoid contact with eyes and skin. Do not inhale gases/vapours/aerosols. Do not eat, drink or smoke when handling.
Personal protection equipment:
Respiratory protection
In case of long or strong exposure: gas mask filter ABEK .
Eye protection
tight fitting protective goggles . Provide work station with eye bathing equipment.
Hand protection
Rubber gloves .
Skin protection
protective clothing .
Exposure to the environment limited and controlled
Prevent material from entering surface waters, drains or sewers and soil. Do not introduce large amounts into purification plants.

Stability and reactivity

Reactivity; Chemical stability; Possibility of hazardous reactions
If stored and handled in accordance with standard industrial practices no hazardous reactions are known.
Relevant information can possibly be found in other parts of this section.
Conditions to avoid
moisture
Incompatible materials
Reacts with: water and acids . Reaction causes the formation of: methanol .
Hazardous decomposition products
methanol . If stored and handled properly: none known .

Disposal considerations

Waste treatment methods
Material
Recommendation:
Dispose of according to regulations by incineration in a special waste incinerator. Observe local/state/federal regulations.
Uncleaned packaging
Recommendation:
Completely discharge containers (no tear drops, no powder rest, scraped carefully). Containers may be recycled or re-used.
Observe local/state/federal regulations.
Waste Disposal Legislation Ref.No.(EC)
It is not possible to determine a waste code for this product in accordance with the European Waste Catalogue (EWC) since it is
only possible to classify it according to how it is used by the customer. The waste code is to be determined within the EU in liaison
with the waste-disposal operator.