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Diss Factsheets

Administrative data

Endpoint:
flash point of flammable liquids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
09 Feb 2016
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Remarks:
GLP guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2016
Report date:
2016

Materials and methods

Test guidelineopen allclose all
Qualifier:
according to guideline
Guideline:
EU Method A.9 (Flash-Point)
Version / remarks:
adopted in 2008
Deviations:
no
Qualifier:
according to guideline
Guideline:
ISO 3679 (Determination of flash point - Rapid equilibrium closed cup method)
Version / remarks:
adopted in 2004
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Remarks:
Hess. Ministerium für Umwelt, Energie, Landwirtschaft und Verbraucherschutz,Wiesbaden, Germany
Type of method:
equilibrium method closed cup
Flash point apparatus:
other: Rapid tester NPV 310 Normalab

Test material

Constituent 1
Chemical structure
Reference substance name:
Reaction products of trimethylolpropane triglycidyl ether and acrylic acid
EC Number:
603-303-1
Cas Number:
128819-84-1
Molecular formula:
C18 H30 O9, C21 H35 Cl O10, C24 H38 O12 and C27 H43 Cl O13 (mainly)
IUPAC Name:
Reaction products of trimethylolpropane triglycidyl ether and acrylic acid
Specific details on test material used for the study:
Storage conditions: ambient temperature (< 40 °C), keep container tightly closed, protected from sunlight

Results and discussion

Flash point
Atm. press.:
ca. 1 013 hPa
Remarks on result:
other: no flash point up to 300 °C

Any other information on results incl. tables

Preliminary test results

Results from the preliminary test with the search program are shown in Table 1. An ignition is indicated by ‘+’ and no ignition by ‘-‘.

 

Table 1 – Preliminary test

Amount of test item [g]

Temperature [°C]

Ignition [+/-]

Air pressure [hPa]

Remark

2

100.0

-

987.8

--

4

300.0

-

987.8

--

 

No ignition was observed up to 300 °C.

 

Main test results

Main test results are shown in Table 2. An ignition is indicated by ‘+’ and no ignition by ‘-‘.

 

Table 2 – Main test

 

Amount of test item [g]

Temperature [°C]

Ignition [+/-]

Air pressure [hPa]

Remark

4

150.0

-

987.8

Flame extinguished, no ignition

4

180.0

-

987.8

4

210.0

-

980.8

4

240.0

-

980.8

4

270.0

-

980.8

4

300.0

-

980.8

No ignition was seen up to the maximum test temperature of 300 °C.

 

Conclusion

According to Regulation EC No. 440/2008 Method A.9. Flash Point and DEN EN ISO 3679 (2004), the test item has no flash point up to 300 °C.

Applicant's summary and conclusion