Registration Dossier

Administrative data

First-aid measures

After inhalation: Remove casualty to fresh air and keep warm and at rest. If breathing is irregular or stopped, administer artificial
respiration. If unconscious place in recovery position and seek medical advice.
After skin contact: Remove contaminated, saturated clothing immediately. After contact with skin, wash immediately with plenty of water
and soap. Do not wash with: Solvents/Thinner
After eye contact: In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart
and consult an ophthalmologist. Protect uninjured eye.
After ingestion: If accidentally swallowed rinse the mouth with plenty of water (only if the person is conscious) and obtain immediate
medical attention. Do NOT induce vomiting. Keep at rest.

Fire-fighting measures

Suitable extinguishing media: alcohol resistant foam, Carbon dioxide (CO2), Extinguishing powder, Water mist
Special hazards arising from the substance or mixture: In case of fire toxic gases may be formed. In flames as well as on hot surfaces toxic and decomposition products with penetrating smell may be formed.
Advice for firefighters: In case of fire: Wear self-contained breathing apparatus.
Additional information: Cool endangered containers with water in case of fire. Do not allow run-off from fire-fighting to enter drains or water
courses.

Accidental release measures

Personal precautions, protective equipment and emergency procedures: Provide adequate ventilation. Avoid generation of dust.
Environmental precautions: Do not allow to enter into surface water or drains.Do not allow to enter into soil/subsoil. In case of gas escape or of
entry into waterways, soil or drains, inform the responsible authorities.
Methods and material for containment and cleaning up: Contain and collect spillage with a vacuum cleaner or by wet brushing and place in container for disposal according to local regulations. Avoid generation of dust. Collect in closed and suitable containers for disposal. Clean contaminated objects and areas thoroughly observing environmental regulations. Ventilate affected area.

Handling and storage

Precautions for safe handling: If handled uncovered, arrangements with local exhaust ventilation should be used if possible. Normal precautions
taken when handling chemicals should be observed. Keep away from sources of heat (e.g. hot surfaces, sparks and open flames). Take precautionary measures against static discharges. Provide earthing of containers, equipment, pumps and ventilation facilities. Avoid generation of dust. Provide working site with eye and safety showers. Avoid contact withskin and eyes. Do not eat or drink during work - no smoking. Comply with the health and safety at work laws.
Conditions for safe storage, including any incompatibilities: Keep container tightly closed and in a well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Containers should be kept dry and sealed.
Further information on storage conditions: Always keep in containers of same material as the original one. See also instructions on the label.
Avoid heating and direct sunlight. Keep away from sources of ignition. - No smoking.

Transport information

Land transport (ADR/RID)

UN number:
1325
Proper shipping name and description:
ENTZÜNDBARER ORGANISCHER FESTER STOFF, N.A.G. ( 1-Phenyl-5-mercaptotetrazol )
Chemical name:
1-Phenyl-5-mercaptotetrazol
Language:
German
Class:
4.1
Classification code:
F1
Packaging group:
II
Labels:
4.1
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Marine transport (IMDG)

UN number:
1325
Proper shipping name and description:
FLAMMABLE SOLID, ORGANIC, N.O.S. ( 1-Phenyl-5-mercaptotetrazole )
Chemical name:
1-Phenyl-5-mercaptotetrazole
Class:
4.1
Packaging group:
II
Labels:
4.1
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Air transport ICAO/IATA

UN number:
1325
Proper shipping name and description:
FLAMMABLE SOLID, ORGANIC, N.O.S. ( 1-Phenyl-5-mercaptotetrazole )
Chemical name:
1-Phenyl-5-mercaptotetrazole
Class:
4.1
Packaging group:
II
Labels:
4.1
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

General health and safety measures: The usual precautionary measures for the handling of chemicals have to be observed. Do not eat or drink during work - no smoking. Wash hands and face before breaks and after work and take a shower if necessary.
Hand protection: The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place concentration and quantity of hazardous substances. Avoid contact with the skin and mouth. After washing hands replace lost skin fat by fat containing skin
creams.
Body protection: Use appropriate skin protection cream before work. Chemical resistant safety clothing.
Eye/face protection: Eye glasses with side protection
Respiratory protection: If technical exhaust or ventilation measures are not possible or insufficient, respiratory protection must be worn.
Suitable respiratory protection apparatus: Combination filtering device (EN 14387), Fresh-air tube device (DIN EN 138)

Stability and reactivity

Chemical stability: The substance is chemically stable under recommended conditions of storage, use and temperature.
Possibility of hazardous reactions: No information available.
Conditions to avoid: Stable under recommended storage and handling conditions. Do not store at temperatures above 40°C.
Incompatible materials: Strong oxidizing agents.

Disposal considerations

Do not empty into waters or drains. Dispose according to legislation.
Product/Packaging disposal: Contaminated packages must be completely emptied and can be re-used following proper cleaning.
Handle contaminated packages in the same way as the substance itself.