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Endpoint:
flammability
Type of information:
other: Expert statement
Adequacy of study:
key study
Study period:
2014
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: Guideline study with acceptable restrictions.
Qualifier:
according to
Guideline:
other: UN-RTDG ‘Manual of Tests and Criteria’ (appendix 6, article 5.3, Procedure N.5).
Deviations:
no
GLP compliance:
no

The structural formula of 14H-benz[4,5]isoquino[2,1-a]perimidin-14-one contains none of the functional groups quoted in UN-RTDG ‘Manual of Tests and Criteria’ (appendix 6, article 5.3) which may react with water to emit flammable gases.

Therefore, it can be concluded by expert judgement that 14H-benz[4,5]isoquino[2,1-a]perimidin-14-one does not emit flammable gases in contact with water. The determination according to UN-RTDG Procedure N.5 is not necessary.

Interpretation of results:
non flammable
Remarks:
Migrated information
Conclusions:
The structural formula of 14H-benz[4,5]isoquino[2,1-a]perimidin-14-one contains none of the functional groups quoted in UN-RTDG ‘Manual of Tests and Criteria’ (appendix 6, article 5.3) which may react with water to emit flammable gases.
Therefore, it can be concluded by expert judgement that 14H-benz[4,5]isoquino[2,1-a]perimidin-14-one does not emit flammable gases in contact with water. The determination according to UN-RTDG Procedure N.5 is not necessary.
Executive summary:

The structural formula of 14H-benz[4,5]isoquino[2,1-a]perimidin-14-one contains none of the functional groups quoted in UN-RTDG ‘Manual of Tests and Criteria’ (appendix 6, article 5.3) which may react with water to emit flammable gases.

Therefore, it can be concluded by expert judgement that 14H-benz[4,5]isoquino[2,1-a]perimidin-14-one does not emit flammable gases in contact with water. The determination according to UN-RTDG Procedure N.5 is not necessary.

Endpoint:
flammability
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2014
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: Guideline study with acceptable restrictions.
Qualifier:
according to
Guideline:
other: UN test procedure ‘Recommendations on the Transport of Dangerous Goods’ (UN-RTDG), ‘Manual of Tests and Criteria’ (Part III, sub-section 33.2.1.4.1, Test N.1 ‘Test method for readily combustible solids’).
Deviations:
no
GLP compliance:
no

14H-benz[4,5]isoquino[2,1-a]perimidin-14-one melted when approached by the ignition flame. The substance did not burn up. No further testing was required.

14H-benz[4,5]isoquino[2,1-a]perimidin-14-one is classified as a not readily combustible solid when tested according to UNRTDG Procedure N.1.

Interpretation of results:
non flammable
Remarks:
Migrated information
Conclusions:
14H-benz[4,5]isoquino[2,1-a]perimidin-14-one melted when approached by the ignition flame and did not burn up.
14H-benz[4,5]isoquino[2,1-a]perimidin-14-one is classified as a not readily combustible solid when tested according to UNRTDG Procedure N.1.
Executive summary:

The test of flammability of 14H-benz[4,5]isoquino[2,1-a]perimidin-14-one was performed as stipulated in UN test procedure ‘Recommendations on the Transport of Dangerous Goods’ (UN-RTDG), ‘Manual of Tests and Criteria’ (Part III, sub-section 33.2.1.4.1, Test N.1 ‘Test method for readily combustible solids’).

14H-benz[4,5]isoquino[2,1-a]perimidin-14-one melted when approached by the ignition flame and did not burn up. 14H-benz[4,5]isoquino[2,1-a]perimidin-14-one is classified as a not readily combustible solid.

Endpoint:
flammability
Type of information:
other: expert statement
Adequacy of study:
key study
Study period:
2014
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: Guideline study with acceptable restrictions.
Qualifier:
according to
Guideline:
other: UN-RTDG Procedure N.2
Deviations:
no
GLP compliance:
no

14H-benz[4,5]isoquino[2,1-a]perimidin-14-one not deliver indications of pyrophoric properties during the realization of other tests. The determination according to UN-RTDG Procedure N.2 is not necessary.

14H-benz[4,5]isoquino[2,1-a]perimidin-14-one is has no pyrophoric properties.

Interpretation of results:
non flammable
Remarks:
Migrated information
Conclusions:
14H-benz[4,5]isoquino[2,1-a]perimidin-14-one not deliver indications of pyrophoric properties during the realization of other tests. The determination according to UN-RTDG Procedure N.2 is not necessary.
14H-benz[4,5]isoquino[2,1-a]perimidin-14-one is has no pyrophoric properties.
Executive summary:

14H-benz[4,5]isoquino[2,1-a]perimidin-14-one not deliver indications of pyrophoric properties during the realization of other tests. The determination according to UN-RTDG Procedure N.2 is not necessary.

14H-benz[4,5]isoquino[2,1-a]perimidin-14-one is has no pyrophoric properties.

Endpoint:
flammability
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2014
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: Guideline study with acceptable restrictions.
Qualifier:
according to
Guideline:
other: UN test procedure ‘Recommendations on the Transport of Dangerous Goods’ (UN-RTDG), ‘Manual of Tests and Criteria’ (Bowes-Cameron-Test, Test N.4).
Deviations:
no
Qualifier:
according to
Guideline:
other: VDI 2263, Part 1 'Test Methods for the Determination of the Safety Characteristic of Dusts'
Deviations:
no
GLP compliance:
no

No exothermic effects were determined up to the point at which 4H-benz[4,5]isoquino[2,1-a]perimidin-14-one melted. The wire mesh basket was empty after the measurement.

14H-benz[4,5]isoquino[2,1-a]perimidin-14-one is not a self-heating substance in the sence of CPL Annex I, 2.11. The determination according to UNRTDG Procedure N.4 (Bowes-Cameron-Test) is not necessary.

Interpretation of results:
non flammable
Remarks:
Migrated information
Conclusions:
No exothermic effects were determined up to the point at which 4H-benz[4,5]isoquino[2,1-a]perimidin-14-one melted. The wire mesh basket was empty after the measurement.
14H-benz[4,5]isoquino[2,1-a]perimidin-14-one is not a self-heating substance in the sence of CPL Annex I, 2.11. The determination according to UNRTDG Procedure N.4 (Bowes-Cameron-Test) is not necessary.
Executive summary:

No exothermic effects were determined up to the point at which 4H-benz[4,5]isoquino[2,1-a]perimidin-14-one melted. The wire mesh basket was empty after the measurement.

14H-benz[4,5]isoquino[2,1-a]perimidin-14-one is not a self-heating substance in the sence of CPL Annex I, 2.11. The determination according to UNRTDG Procedure N.4 (Bowes-Cameron-Test) is not necessary.

Description of key information

Flammability:
14H-benz[4,5]isoquino[2,1-a]perimidin-14-one melted when approached by the ignition flame and did not burn up.
14H-benz[4,5]isoquino[2,1-a]perimidin-14-one is classified as a not readily combustible solid when tested according to UNRTDG Procedure N.1.
Contact with water:
The structural formula of 14H-benz[4,5]isoquino[2,1-a]perimidin-14-one contains none of the functional groups quoted in UN-RTDG ‘Manual of Tests and Criteria’ (appendix 6, article 5.3) which may react with water to emit flammable gases.
Therefore, it can be concluded by expert judgement that 14H-benz[4,5]isoquino[2,1-a]perimidin-14-one does not emit flammable gases in contact with water. The determination according to UN-RTDG Procedure N.5 is not necessary.
Pyrophoric properties:
14H-benz[4,5]isoquino[2,1-a]perimidin-14-one not deliver indications of pyrophoric properties during the realization of other tests. The determination according to UN-RTDG Procedure N.2 is not necessary.
14H-benz[4,5]isoquino[2,1-a]perimidin-14-one is has no pyrophoric properties.
Self-heating substances and mixtures:
No exothermic effects were determined up to the point at which 4H-benz[4,5]isoquino[2,1-a]perimidin-14-one melted. The wire mesh basket was empty after the measurement.
14H-benz[4,5]isoquino[2,1-a]perimidin-14-one is not a self-heating substance in the sence of CPL Annex I, 2.11. The determination according to UNRTDG Procedure N.4 (Bowes-Cameron-Test) is not necessary.

Key value for chemical safety assessment

Flammability:
non flammable

Additional information

Justification for classification or non-classification

14H-benz[4,5]isoquino[2,1-a]perimidin-14-one is not yet classified in the Annex I of Directive 67/548/EEC. According to the information summarized in this below, no classification on flammability is needed:

- As liquid, no flash point up to 249 °C;

- As liquid, boiling point is higher than 300 °C;

- No pyrophoric property, based on experience from production and handling;

- It does not ignite spontaneously with water and does not liberate flammable gases in hazardous amounts in contact with water.

Based on the data summarized above, 14H-benz[4,5]isoquino[2,1-a]perimidin-14-one is also not flammable according to GHS (Regulation EC 1272/2008).