Registration Dossier
Registration Dossier
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EC number: 289-200-9 | CAS number: 86178-38-3
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Inhalation:
If inhaled, remove victim to fresh air.
Skin:
In case of contact, immediately flush skin with soap and plenty of water. Get medical attention. Remove contaminated
clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eyes:
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention.
Ingestion:
If swallowed, DO NOT induce vomiting. Get medical attention. Never give anything by mouth to an unconscious
person.
If inhaled, remove victim to fresh air.
Skin:
In case of contact, immediately flush skin with soap and plenty of water. Get medical attention. Remove contaminated
clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eyes:
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention.
Ingestion:
If swallowed, DO NOT induce vomiting. Get medical attention. Never give anything by mouth to an unconscious
person.
Fire-fighting measures
Water spray, Carbon dioxide (CO2), Foam, Dry chemical
Protective equipment:
Fire fighters and others who may be exposed to products of combustion should wear full fire fighting turn out gear
(full Bunker Gear) and self-contained breathing apparatus (pressure demand / NIOSH approved or equivalent).
Further firefighting advice:
Fight fire from a protected location.
Cool closed containers exposed to fire with water spray.
Closed containers of this material may explode when subjected to heat from surrounding fire.
Do not allow run-off from fire fighting to enter drains or water courses.
Fire fighting equipment should be thoroughly decontaminated after use.
Fire and explosion hazards:
When burned, the following hazardous products of combustion can occur:
Carbon oxides
Hazardous organic compounds
Polymerization is exothermic and can degenerate into an uncontrolled reaction.
Protective equipment:
Fire fighters and others who may be exposed to products of combustion should wear full fire fighting turn out gear
(full Bunker Gear) and self-contained breathing apparatus (pressure demand / NIOSH approved or equivalent).
Further firefighting advice:
Fight fire from a protected location.
Cool closed containers exposed to fire with water spray.
Closed containers of this material may explode when subjected to heat from surrounding fire.
Do not allow run-off from fire fighting to enter drains or water courses.
Fire fighting equipment should be thoroughly decontaminated after use.
Fire and explosion hazards:
When burned, the following hazardous products of combustion can occur:
Carbon oxides
Hazardous organic compounds
Polymerization is exothermic and can degenerate into an uncontrolled reaction.
Accidental release measures
Personal precautions, Emergency procedures, Methods and materials for containment/clean-up:
Prevent further leakage or spillage if you can do so without risk. Ventilate the area. Avoid generation of vapors.
Contain and collect spillage with non-combustible absorbent material such as clean sand, earth, diatomaceous
earth or non-acidic clay and place into suitable properly labeled containers for prompt disposal. Avoid dispersal of
spilled material and runoff and contact with soil, waterways, drains and sewers. Consult a regulatory specialist to
determine appropriate state or local reporting requirements, for assistance in waste characterization and/or
hazardous waste disposal and other requirements listed in pertinent environmental permits.
Prevent further leakage or spillage if you can do so without risk. Ventilate the area. Avoid generation of vapors.
Contain and collect spillage with non-combustible absorbent material such as clean sand, earth, diatomaceous
earth or non-acidic clay and place into suitable properly labeled containers for prompt disposal. Avoid dispersal of
spilled material and runoff and contact with soil, waterways, drains and sewers. Consult a regulatory specialist to
determine appropriate state or local reporting requirements, for assistance in waste characterization and/or
hazardous waste disposal and other requirements listed in pertinent environmental permits.
Handling and storage
Handling
General information on handling:
Avoid breathing processing vapor or mist.
Avoid contact with skin, eyes and clothing.
Wash thoroughly after handling.
Emptied container retains vapor and product residue.
Observe all labeled safeguards until container is cleaned, reconditioned or destroyed.
Storage
General information on storage conditions:
Keep in a dry, cool place. Store in closed containers, in a secure area to prevent container damage and subsequent
spillage. Store out of direct sunlight in a cool well-ventilated place. Keep stabilizer levels constant to avoid explosive
polymerization. An air space is required above the liquid in all containers; avoid storage under an oxygen-free
atmosphere.
Storage stability – Remarks:
Inhibitor levels should be maintained. The typical shelf-life for this product is 12 months.
Store separate from:
Strong oxidizing agents
Strong reducing agents
Free radical generators
Inert gas
Oxygen scavenger.
Peroxides
Temperature tolerance – Do not store below:–
32 °F (0 °C)
Temperature tolerance – Do not store above:
100 °F (38 °C)
General information on handling:
Avoid breathing processing vapor or mist.
Avoid contact with skin, eyes and clothing.
Wash thoroughly after handling.
Emptied container retains vapor and product residue.
Observe all labeled safeguards until container is cleaned, reconditioned or destroyed.
Storage
General information on storage conditions:
Keep in a dry, cool place. Store in closed containers, in a secure area to prevent container damage and subsequent
spillage. Store out of direct sunlight in a cool well-ventilated place. Keep stabilizer levels constant to avoid explosive
polymerization. An air space is required above the liquid in all containers; avoid storage under an oxygen-free
atmosphere.
Storage stability – Remarks:
Inhibitor levels should be maintained. The typical shelf-life for this product is 12 months.
Store separate from:
Strong oxidizing agents
Strong reducing agents
Free radical generators
Inert gas
Oxygen scavenger.
Peroxides
Temperature tolerance – Do not store below:–
32 °F (0 °C)
Temperature tolerance – Do not store above:
100 °F (38 °C)
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 3082
Shipping information
- Proper shipping name and description:
- Environmentally hazardous substance, liquid, n.o.s.
- Chemical name:
- (3,3,5-Trimethylcyclohexanol acrylate)
- Language:
- English
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- 3082
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
- Chemical name:
- (3,3,5-TRIMETHYLCYCLOHEXANOL ACRYLATE)
- Marine pollutant
Remarksopen allclose all
Shippingopen allclose all
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Engineering controls:
Investigate engineering techniques to reduce exposures below airborne exposure limits or to otherwise reduce
exposures. Provide ventilation if necessary to minimize exposures or to control exposure levels to below
airborne exposure limits (if applicable see above).If practical, use local mechanical exhaust ventilation at
sources of air contamination such as open process equipment.
Respiratory protection:
Avoid breathing processing vapor or mist. Where airborne exposure is likely or airborne exposure limits are
exceeded (if applicable, see above), use NIOSH approved respiratory protection equipment appropriate to the
material and/or its components. Full facepiece equipment is recommended and, if used, replaces need for face
shield and/or chemical goggles. Consult respirator manufacturer to determine appropriate type equipment for a
given application. Observe respirator use limitations specified by NIOSH or the manufacturer. For emergency
and other conditions where there may be a potential for significant exposure or where exposure limit may be
significantly exceeded, use an approved full face positive-pressure, self-contained breathing apparatus or
positive-pressure airline with auxiliary self-contained air supply.
Skin protection:
Wear appropriate chemical resistant protective clothing and chemical resistant gloves to prevent skin contact.
Consult glove manufacturer to determine appropriate type glove material for given application. Avoid natural
rubber gloves.
Wear chemical goggles, a face shield, and chemical resistant clothing such as a rubber apron
when splashing may occur. Rinse immediately if skin is contaminated. Remove contaminated clothing
immediately and wash before reuse. Clean protective equipment before reuse. Provide a safety shower at any
location where skin contact can occur. Wash thoroughly after handling.
Eye protection:
Where there is potential for eye contact, wear chemical goggles and have eye flushing equipment immediately
available.
Investigate engineering techniques to reduce exposures below airborne exposure limits or to otherwise reduce
exposures. Provide ventilation if necessary to minimize exposures or to control exposure levels to below
airborne exposure limits (if applicable see above).If practical, use local mechanical exhaust ventilation at
sources of air contamination such as open process equipment.
Respiratory protection:
Avoid breathing processing vapor or mist. Where airborne exposure is likely or airborne exposure limits are
exceeded (if applicable, see above), use NIOSH approved respiratory protection equipment appropriate to the
material and/or its components. Full facepiece equipment is recommended and, if used, replaces need for face
shield and/or chemical goggles. Consult respirator manufacturer to determine appropriate type equipment for a
given application. Observe respirator use limitations specified by NIOSH or the manufacturer. For emergency
and other conditions where there may be a potential for significant exposure or where exposure limit may be
significantly exceeded, use an approved full face positive-pressure, self-contained breathing apparatus or
positive-pressure airline with auxiliary self-contained air supply.
Skin protection:
Wear appropriate chemical resistant protective clothing and chemical resistant gloves to prevent skin contact.
Consult glove manufacturer to determine appropriate type glove material for given application. Avoid natural
rubber gloves.
Wear chemical goggles, a face shield, and chemical resistant clothing such as a rubber apron
when splashing may occur. Rinse immediately if skin is contaminated. Remove contaminated clothing
immediately and wash before reuse. Clean protective equipment before reuse. Provide a safety shower at any
location where skin contact can occur. Wash thoroughly after handling.
Eye protection:
Where there is potential for eye contact, wear chemical goggles and have eye flushing equipment immediately
available.
Stability and reactivity
This material is chemically stable under normal and anticipated storage, handling and processing conditions.
However, this material can undergo hazardous polymerization.
Hazardous reactions:
Hazardous polymerisation may occur.
Polymerization is exothermic and can degenerate into an uncontrolled reaction.
Materials to avoid:
Strong reducing agents
Free radical generators
Inert gas
Oxygen scavenger.
Peroxides
Strong oxidizing agents
Conditions / hazards to avoid:
This material polymerizes exothermically in the presence of heat, contamination, oxygen free atmosphere, free
radicals, peroxides and inhibitor depletion liberating heat. Avoid direct sunlight. Do NOT expose to ultraviolet light.
Hazardous decomposition products:
Thermal decomposition giving flammable and toxic products:
Carbon oxides
Acrylates
Hazardous organic compounds
However, this material can undergo hazardous polymerization.
Hazardous reactions:
Hazardous polymerisation may occur.
Polymerization is exothermic and can degenerate into an uncontrolled reaction.
Materials to avoid:
Strong reducing agents
Free radical generators
Inert gas
Oxygen scavenger.
Peroxides
Strong oxidizing agents
Conditions / hazards to avoid:
This material polymerizes exothermically in the presence of heat, contamination, oxygen free atmosphere, free
radicals, peroxides and inhibitor depletion liberating heat. Avoid direct sunlight. Do NOT expose to ultraviolet light.
Hazardous decomposition products:
Thermal decomposition giving flammable and toxic products:
Carbon oxides
Acrylates
Hazardous organic compounds
Disposal considerations
Waste disposal:
Disposal via incineration is recommended. Dispose of in accordance with federal, state and local regulations.
Consult a regulatory specialist to determine appropriate state or local reporting requirements, for assistance in
waste characterization and/or hazardous waste disposal and other requirements listed in pertinent environmental
permits. Note: Chemical additions to, processing of, or otherwise altering this material may make this waste
management information incomplete, inaccurate, or otherwise inappropriate. Furthermore, state and local waste
disposal requirements may be more restrictive or otherwise different from federal laws and regulations.
Disposal via incineration is recommended. Dispose of in accordance with federal, state and local regulations.
Consult a regulatory specialist to determine appropriate state or local reporting requirements, for assistance in
waste characterization and/or hazardous waste disposal and other requirements listed in pertinent environmental
permits. Note: Chemical additions to, processing of, or otherwise altering this material may make this waste
management information incomplete, inaccurate, or otherwise inappropriate. Furthermore, state and local waste
disposal requirements may be more restrictive or otherwise different from federal laws and regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
