Registration Dossier

Administrative data

First-aid measures

After inhalation: Move the affected person to fresh air.If breathing becomes irregular or ceases, apply mouth-to-mouth resuscitation or artifical respiration immediately. Get medical attention.After skin contact: Immediately remove contaminated clothing, wash off the skin with plenty of water.After eye contact: Rinse the eyes with water for several minutes with eyelids open wide. Having rinsed the eyes, obtain ophthalmologic attention as soon as possible.After swallowing: Wash out the mouth with plenty of water, give plenty of water to drink, then obtain medical attenton immediately.Information for doctor: The physician must be informed on the time, type and extent of exposure.

Fire-fighting measures

Suitable extinguishing media: Available extinguishing media: water spray, extinguishing powder, carbon dioxid, foam.Unsuitable extinguishing media: Full waterjet are not suitable for extinguishing.Special hazards arising from the substance or mixture:Substance is combustible. Combustion products: carbonmonoxide/ dioxide.Advice for firefighters:Outdoors stay on the weatherside and extinguish from there. In closed places, and in case of wreck, wear fireproof working clothes and use selfcontained breathing apparatus.

Accidental release measures

Personal precautions, protective equipment and emergency procedures:Only the trained personnel in charge of release is allowed to be present at the site of spilling, wearing the prescribed protective equipments.Environmental precautions:Hinder the spilled substance from entering the soil, sewers or living water.Methods and material for containment and cleaning up:Collect spilt substance aspiring to the lowest possible dustlevel. Put the collected substance into adequately labelled empties and transport them to the site of disposal, then wash the contaminated area with plenty of water.

Handling and storage

Precautions for safe handling:Handled it the compliance with good industrial hygiene and safety procedures. Avoid: dust formation; deposition, contact with skin, eyes; inhalation or ingestion. Avoid any possibility of direct contact with substance while manipulating. It is necessary to wash a hand and a face with water and a soap after the work made with the substance.Conditions for safe storage, including any incompatibilities:Store it in a cool, dry, wellventilated place. Storage in a tighltly fitting package, protected from light, protected from humidity/water.

Transport information

Land transport (ADR/RID)

UN number:
3077
Shippingopen allclose all
Class:
9
Classification code:
M7
Packaging group:
III
Labels:
9
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
3077
Shippingopen allclose all
Class:
9
Classification code:
M7
Packaging group:
III
Labels:
9
Remarksopen allclose all

Marine transport (IMDG)

UN number:
3077
Proper shipping name and description:
Environmentally hazardous substance, solid, n.o.s.
Chemical name:
silyl-fluconazole
Class:
9
Packaging group:
III
EmS code:
F-A, S-F
Labels:
9
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
3077
Proper shipping name and description:
Environmentally hazardous substance, solid, n.o.s.
Chemical name:
silyl-fluconazole
Class:
9
Packaging group:
III
Labels:
9
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

This intermediate is handled under Strictly Controlled Conditions in accordance with the ECHA REACH Guidance on Intermediates.The substance is rigorously contained during storage, the packaging is opened only in case of sampling, and when the substance is used in the process. When the substance is put in the reactor, air filtration (99% efficiency) is used along with personal protective equipment. The process is thereafter fully closed; no emission is detected until sampling of the reaction mass. During sampling air filtration (99% efficiency) is used along with personal protective equipment. At the end of the process, during the unloading of the substance and the sampling general air filtration is used along with personal protective equipment.No occupational limits have been established.Individual protection measures / personal protective equipment:The personal protective equipment for the working process are determined by internal standards.Wear closed protection glasses. Closed protective clothing against particulate matter. Protective gloves made of neopren-Wear P3 dust mask for respiatory protection.

Stability and reactivity

The substance is stabil at dry place for 12 months.Chemical stability: stable under normal circumstances.Possibility of hazardous reactions: danger of electrostatic charge, danger of dust explosion.Conditions to avoid: sensitive to the following physical effects: light, intense heat.Incompatible materials: strong acids, strong basics, strong reducers.

Disposal considerations

Suggestions for disposal procedures of the substance/product:Incineration in a special waste incineration plant.Suggestions for disposal procedures of contaminated packaging (vessels):Flammable empties must be incinerated in waste increation plant, in compliance with local regulations. Empties should be washed with plenty of water before reuse/recycling.