Registration Dossier

Administrative data

First-aid measures

General advice : Never give anything by mouth to an unconscious person.
Inhalation : Move to fresh air. Consult a physician after significant exposure. Artificial respiration and/or oxygen may be necessary.
Skin contact : Wash off immediately with soap and plenty of water. Take off contaminated clothing and shoes immediately. In the case of skin irritation or allergic reactions see a physician. Wash contaminated clothing before re-use.
Eye contact : If easy to do, remove contact lens, if worn. Hold eye open and rinse slowly and gently with water for 15-20 minutes. If eye irritation persists, consult a specialist.
Ingestion : Obtain medical attention. DO NOT induce vomiting unless directed to do so by a physician or poison control center. If victim is conscious: Rinse mouth with water.
Symptoms : No information available.
Treatment : Treat symptomatically.

Fire-fighting measures

Suitable extinguishing media : Water spray, Foam, Dry chemical, Carbon dioxide (CO2)
Extinguishing media which shall not be used for safety reasons : High volume water jet, (contamination risk)
Specific hazards during firefighting: Hazardous decomposition products formed under fire conditions. Carbon dioxide (CO2) Nitrogen oxides (NOx)
Special protective equipment for firefighters : Wear full protective clothing and self-contained breathing apparatus.
Further information: Prevent fire extinguishing water from contaminating surface water or the ground water system. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
(on small fires) If area is heavily exposed to fire and if conditions permit, let fire burn itself out since water may increase the area contaminated. Cool containers/tanks with water spray.

Accidental release measures

Personal precautions: Control access to area. Keep people away from and upwind of spill/leak. Avoid dust formation. Avoid breathing dust. Use personal protective equipment. Refer to protective measures listed in sections 7 and 8.
Environmental precautions: Prevent further leakage or spillage if safe to do so. Use appropriate container to avoid environmental contamination. Do not flush into surface water or sanitary sewer system. Do not allow material to contaminate ground water system. Local authorities should be advised if significant spillages cannot be contained. If the product contaminates rivers and lakes or drains inform respective authorities. If the spill area is porous, the contaminated material must be collected for subsequent treatment or disposal.
Methods for cleaning up: Clean-up methods - small spillage Sweep up or vacuum up spillage and collect in suitable container for disposal.
Clean-up methods - large spillage Avoid dust formation. Knock down dust with water spray jet. Contain spillage, pick up with an electrically protected vacuum cleaner or by wet-brushing and transfer to a container for disposal according to local regulations (see section 13). If spill area is on ground near valuable plants or trees, remove 5 cm of top soil after initial clean-up.
Other information: Never return spills in original containers for re-use. Dispose of in accordance with local regulations.

Handling and storage

Advice on safe handling: Use only according to our recommendations. Use only clean equipment. Avoid contact with skin, eyes and clothing. Do not breathe dust or spray mist. Wear personal protective equipment. For personal protection see section 8. Prepare the working solution as given on the label(s) and/or the user instructions. Use prepared working solution as soon as possible - Do not store. Provide appropriate exhaust ventilation at places where dust is formed. Avoid exceeding the given occupational exposure limits.
Advice on protection against fire and explosion: Keep away from heat and sources of ignition. Avoid dust formation in confined areas. During processing, dust may form explosive mixture in air.
Requirements for storage areas and containers: Store in a place accessible by authorized persons only. Store in original container. Keep in properly labelled containers. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep out of the reach of children.
Advice on common storage: No special restrictions on storage with other products.
Other data: Stable under recommended storage conditions.

Transport information

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Marine transport (IMDG)

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Exposure controls / personal protection

Engineering measures: Ensure adequate ventilation, especially in confined areas. Provide for appropriate exhaust ventilation and dust collection at machinery. Use sufficient ventilation to keep employee exposure below recommended limits.
Eye protection: Safety glasses with side-shields conforming to EN166
Hand protection: Material: Nitrile rubber
Glove thickness: 0,3 mm
Glove length: Gauntlets
Protection index: Class 6
Wearing time: 8 h
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time. The suitability for a specific workplace should be discussed with the producers of the protective gloves. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough. Before removing gloves clean them with soap and water.
Skin and body protection: Manufacturing and processing work: Full protective clothing Type 5 (EN 13982-2)
Protective measures: The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. All chemical protective clothing should be visually inspected prior to use. Clothing and gloves should be replaced in case of chemical or physical
damage or if contaminated.
Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing. Keep working clothes separately. Contaminated work clothing should not be allowed out of the workplace. Wash hands and face before breaks and immediately after handling the product. When using do not eat, drink or smoke. Keep away from food, drink and animal feedingstuffs. For environmental protection remove and wash all contaminated protective equipment before re-use. Remove clothing/PPE immediately if material gets inside. Wash thoroughly and put on clean clothing.
Dispose of rinse water in accordance with local and national regulations.
Respiratory protection : Manufacturing and processing work: Half mask with a particle filter FFP1 (EN149)

Stability and reactivity

Reactivity : No hazards to be specially mentioned.
Chemical stability : The product is chemically stable.
Possibility of hazardous reactions: No dangerous reaction known under conditions of normal use. Polymerization will not occur. No decomposition if stored and applied as directed.
Conditions to avoid : To avoid thermal decomposition, do not overheat. Under severe dusting conditions, this material may form explosive mixtures in air.
Incompatible materials : No materials to be especially mentioned.
Hazardous decomposition products: No materials to be especially mentioned.

Disposal considerations

Product : In accordance with local and national regulations. Must be incinerated in a suitable incineration plant holding a permit delivered by the competent authorities. Do not contaminate ponds, waterways or ditches with chemical or used container.
Contaminated packaging : Do not re-use empty containers.
European Waste Catalogue number: 020108: agrochemical waste containing dangerous substances