Registration Dossier

Administrative data

First-aid measures

Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled: If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact: Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.
In case of eye contact: Flush eyes with water as a precaution
If swallowed: Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

Fire-fighting measures

Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture: Carbon oxides, nitrogen oxides (NOx), Sulphur oxides
Advice for firefighters: Wear self contained breathing apparatus for fire fighting if necessary.

Accidental release measures

Personal precautions, protective equipment and emergency procedures: Wear respiratory protection. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.
Methods and materials for containment and cleaning up: Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed
containers for disposal.

Handling and storage

Precautions for safe handling: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed.Normal measures for preventive fire protection.
Conditions for safe storage, including any incompatibilities: Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

Handling and storage:

Handle the substance under strictly controlled conditions according to Article 18(4) of REACH Regulation. Rigorous containment should be achieved.

Exposure controls/personal protection:

The substance is used under strictly controlled conditions during its whole lifecycle as described under Article 18 (4) and Section 2.1 of the Guidance for Intermediates. The substance should be rigorously contained by technical means during its whole lifecycle and procedural and control technologies should be in place in order to minimize emissions and any resulting exposure as described under Article 18(4). Personal protective equipment (PPE) should be used in cases of accidents and where waste is generated. The PPE may be also used as a good practice.

Transport information

Land transport (ADR/RID)

UN number:
2811
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Class:
TOXIC SOLID, ORGANIC, N.O.S. (Thiosemicarbazide)
Classification code:
6.1
Packaging group:
II
Labels:
No
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Marine transport (IMDG)

UN number:
2811
Proper shipping name and description:
TOXIC SOLID, ORGANIC, N.O.S. (Thiosemicarbazide)
Chemical name:
Thiosemicarbazide
Class:
6.1
Packaging group:
II
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
2811
Proper shipping name and description:
Toxic solid, organic, n.o.s. (Thiosemicarbazide)
Chemical name:
Thiosemicarbazide
Class:
6.1
Packaging group:
II
Labels:
No
Remarksopen allclose all
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Exposure controls / personal protection

Eye/face protection: Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection: Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
Body Protection: Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection: Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Stability and reactivity

Reactivity: No data available
Chemical stability: No data available
Posibility of hazardous reactiins: No data available
Conditions to avoid: No data available
Incompatible Materials: Strong oxidisuing agents, Strong acids, Strong bases.
Hazardous decomposition products: No data available.

Disposal considerations

Waste treatment methods
Product:
Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed
professional waste disposal service to dispose of this material. Dissolve or mix the material with a
combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging: Dispose of as unused product.