Registration Dossier

Administrative data

First-aid measures

General information:
Personal protection for the First Aider.
Immediately remove any clothing soiled by the product.
After inhalation:
Take affected persons into fresh air and keep quiet.
Call a doctor immediately.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:
Call a doctor immediately.
Immediately wash with water and soap and rinse thoroughly.
After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing:
Rinse out mouth and then drink plenty of water.
Drink plenty of water and provide fresh air. Call for a doctor immediately.

Fire-fighting measures

Extinguishing media
Suitable extinguishing agents:
Carbon dioxide
Foam
Sand
Water spray
Use fire extinguishing methods suitable to surrounding conditions.
For safety reasons unsuitable extinguishing agents: Water
· Special hazards arising from the substance or mixture
In case of fire, the following can be released:
Carbon monoxide (CO)
Nitrogen oxides (NOx)
Advice for firefighters:
Protective equipment: Wear self-contained respiratory protective device.
Additional information Cool endangered receptacles with water spray.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Wear protective clothing.
Wear protective equipment. Keep unprotected persons away.
Environmental precautions: Do not allow to penetrate the ground/soil.
Methods and material for containment and cleaning up:
Send for recovery or disposal in suitable receptacles.
Dispose of the material collected according to regulations.
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Use neutralizing agent.
Dispose contaminated material according to disposal consideration section.
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents

Handling and storage

Handling:
Precautions for safe handling
Keep receptacles tightly sealed.
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Information about fire - and explosion protection: No special measures required.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility:
Store away from water.
Store away from oxidizing agents.
Further information about storage conditions:
Protect from humidity and water.
Keep container tightly sealed.
Store in cool, dry conditions in well sealed receptacles.

Transport information

Land transport (ADR/RID)

UN number:
3265
Proper shipping name and description:
CORROSIVE, LIQUID, ACIDIC, ORGANIC, N.O.S. (Vinyltriacetoxysilane (VTAS))
Chemical name:
Vinyltriacetoxysilane (VTAS)
Language:
English
Class:
(C3) Corrosive substances
Classification code:
8
Packaging group:
II
Labels:
8
Remarks:
Dander code (Kemler): 80
Tunnel restriction code: E
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Marine transport (IMDG)

UN number:
3265
Proper shipping name and description:
CORROSIVE, LIQUID, ACIDIC, ORGANIC, N.O.S. (Vinyltriacetoxysilane (VTAS))
Chemical name:
Vinyltriacetoxysilane (VTAS)
Class:
8
Packaging group:
II
EmS code:
F-A, S-B
Labels:
8
Remarks
Segregation groups: acids.

Air transport ICAO/IATA

UN number:
3265
Proper shipping name and description:
CORROSIVE, LIQUID, ACIDIC, ORGANIC, N.O.S. (Vinyltriacetoxysilane (VTAS))
Chemical name:
Vinyltriacetoxysilane (VTAS)
Class:
8
Packaging group:
II
Labels:
8
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Exposure controls / personal protection

Control parameters
Ingredients with limit values that require monitoring at the workplace: Not required.
Additional information: The lists valid during the making were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Do not eat, drink, smoke or sniff while working.
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Standards of Personal Protective Equipment
Respiratory protection EN 136, 140, 149
Eye protection EN 166
Body protection EN 340, 463, 468, 943-1, 943-2
Protection of hands EN 374
Safety shoes EN-ISO 20345
Respiratory protection:
Suitable respiratory protective device recommended.
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves:
Rubber gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.
Penetration time of glove material:
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
Strong material gloves
Leather gloves
Eye protection:
Tightly sealed goggles
Body protection:
Use protective suit.

Stability and reactivity

Reactivity:
Chemical stability:
Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
Possibility of hazardous reactions
Explosive reaction with water.
Reacts with acids.
Reacts with alkali (lyes).
Reacts with alcohols.
Reacts with strong oxidizing agents.
Contact with water will cause spontaneous hydrolysis (Can be explosive!).
Hazardous decomposition products: Ethanoic acid

Disposal considerations

Waste treatment methods:
Recommendation:
After prior treatment product has to be disposed of in an incinerator for hazardous waste adhering to the regulations pertaining to the disposal of particularly hazardous waste.
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Uncleaned packaging:
Recommendation: Disposal must be made according to official regulations.