Registration Dossier

Administrative data

First-aid measures

After inhalation:
Remove person to fresh air and keep comfortable for breathing.
In case of unconsciousness, place the victim in recovery position and call medical assistance.
If breathing is difficult, immediately call medical assistance. Give oxygen or artificial respiration.

After skin contact:
Take off immediately all contaminated clothing. Rinse skin with water/shower for 15 minutes.
Wash contaminated clothing before reuse.
If skin irritation or rash occurs: Get medical advice/attention.

After eyes contact:
Rinse cautiously with water for 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Call an ophthalmologist.

After ingestion:
Immediately call a POISON CENTER or doctor/physician.
Rinse mouth. Do NOT induce vomiting.
In case of unconsciousness, place the victim in recovery position until the arrival of the medical assistance.
If person is conscious, give plenty of water to drink to dilute the substance.

Fire-fighting measures

Extinguishing media:
Suitable extinguishing media: Alcohol resistant foam, carbon dioxide, dry sand. The use of foam causes, at least initially, the release of large quantities of flammable and
corrosive vapors. These vapors can be trapped under the foam mat.
Unsuitable extinguishing media: Water jet.

Special hazards arising from the substance or mixture: Substance is not flammable. However, in a fire, it can decompose, giving off toxic fumes of carbon monoxide (CO), carbon dioxide (CO2), hydrochloric acid gas (HCl) and hydrofluoric acid gas (HF).

Advice for firefighters:
Firefighting responders should equip themselves with a complete body and heat resistant protective equipment and self contained breathing apparatus (EN 137 / EN 14593 / EN 14594).
Water should be applied to cool containers that are exposed to flames.
Keep run-off water out of sewers and water sources.

Accidental release measures

Personal precautions, protective equipment and emergency procedures:
Ventilate contaminated area. Avoid contact with the released substance. Avoid inhalation.
Remove from spill site any person whose presence is not necessary. Keep upwind. The others should wear protective cloth, breathing apparatus, chemical safety goggles, rubber boots and rubber gloves.

Environmental precautions:
Shut off leaks if without risk. Prevent liquid from entering the environment.
Do not flush spill area with plenty of water before picking-up.

Methods and material for containment and cleaning up:
Pump the largest quantity of spilled product in a drum (use an explosion proof pump). This product should be disposed.
Absorb the last traces of liquid on sand or vermiculite and place in tightly closed and labelled drums/containers for disposal (see section 13).
Wash spill site with plenty of water after material pickup is complete.

Handling and storage

7.1 Precautions for safe handling:
Handle and use only in well-ventilated areas.
Safety shower and eyewash fountain should be available.
Avoid contact with skin, eyes and clothes. Avoid inhalation. Avoid repeated or prolonged exposure.
Wash thoroughly after handling this substance. Keep apart working clothes.

Conditions for safe storage, including any incompatibilities:
Technical measures: The ground of the storage area must be waterproof and form retention basin.
Storage conditions: Keep containers tightly closed. The product should be stored under inert gaz: nitrogen. Store in a cool, dry and well-ventilated area.
Incompatible materials: Keep away from water, acids, basis, alcohols, cetones and aldehydes.
Packaging materials: Plastic PEHD.

Transport information

Land transport (ADR/RID)

UN number:
2987
Proper shipping name and description:
CHLOROSILANE, CORROSIVE, N.O.S.
Chemical name:
CHLORO(3-(3-CHLORO-4-FLUOROPHENYL)PROPYL)DIMETHYLSILANE
Language:
English
Class:
8
Classification code:
C3
Packaging group:
II
Labels:
8
Special Provisions:
548

Inland waterway transport (ADN(R))

UN number:
2987
Proper shipping name and description:
CHLOROSILANE, CORROSIVE, N.O.S.
Chemical name:
CHLORO(3-(3-CHLORO-4-FLUOROPHENYL)PROPYL)DIMETHYLSILANE
Language:
English
Class:
8
Classification code:
C3
Packaging group:
II
Labels:
8
Remarksopen allclose all

Marine transport (IMDG)

UN number:
2987
Proper shipping name and description:
CHLOROSILANE, CORROSIVE, N.O.S.
Chemical name:
CHLORO(3-(3-CHLORO-4-FLUOROPHENYL)PROPYL)DIMETHYLSILANE
Class:
8
Packaging group:
II
EmS number:
F-A, S-B
Labels:
8
Marine pollutant:
no
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
2987
Proper shipping name and description:
CHLOROSILANE, CORROSIVE, N.O.S.
Chemical name:
CHLORO(3-(3-CHLORO-4-FLUOROPHENYL)PROPYL)DIMETHYLSILANE
Class:
8
Packaging group:
II
Labels:
8
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Engineering measures: The use of local exhaust is recommended to avoid vapour emissions.

Personal protective equipment:
Eyes / Face protection: Chemical safety goggles with side shields / Face shield (EN 166)
Skin protection: Suitable protective body clothing (EN 14605 in case of splashes)
Hand protection:
In case of limited contact or for a protection against splashes: gloves with minimum protection index of 2 (permeation time > 30 min according to EN 374-3):
PVC, Fluorinated material (Teflon ®, Viton ®)
In case of direct prolonged exposure: gloves with minimum protection index of 4 (permeation time > 120 min according to EN 374-3):
PVC, Fluorinated material (Teflon ®, Viton ®)
Respiratory protection:
Respirator (EN 140 / EN 136) with filter (EN 14387/A1 – Type ABEK) when risk of inhalation.
Self-contained breathing apparatus (EN 137 / EN 14593 / EN 14594) in case of important risk or prolonged exposure, for example in case of fire fighting.

Stability and reactivity

Reactivity: No data available.

Chemical Stability: The substance is stable at room temperature and under normal storage and handling conditions

Possibility of hazardous reactions: No dangerous reaction has been identified.

Conditions to avoid: Avoid wet conditions.

Incompatible materials: Reacts with water, acids, basis, alcohols, cetones and aldehydes.

Hazardous decomposition products:
In case of fire: toxic fumes of carbon oxide (CO), carbon dioxide (CO2), hydrochloric acid gas (HCl) and hydrofluoric acid gas (HF).
Decomposition in water: formation of hydrochloric acid gas (HCl).

Disposal considerations

Waste treatment methods:
Product residues: Do not reject in natural environment. Burn in an adequate incinerator (for halogenated products).
Contaminated packaging: Empty containers/drums should be handled with the same precautions than the full ones. Contaminated packaging have to be disposed in a site
approved for chemical and hazardous waste or burned in a specialised burning centre.